Abstract:
A melt consolidated, multiaxially oriented liquid crystal polymer ("LCP") sheet or other article formed from LCP particles. One embodiment includes a multi-component LCP sheet in which particles of a higher melting LCP are imbedded in a matrix of a lower melting LCP. These LCP components are formed into sheet at a temperature between the melting point of the lower melting matrix LCP and the higher melting reinforcing LCP, so that the imbedded LCP particles may maintain their shape, orientation, and mechanical characteristics while the matrix LCP component flows around the particles and forms a solid sheet. In another embodiment, LCP particles are melt consolidated to form a single article in which a significant amount of LCP orientation is retained. A sheet of this invention may be formed by a variety of processes, and may be made from recycled scrap LCP.
Abstract:
A process for treating a liquid crystal polymer film which includes the steps of: heating a film obtained by extrusion molding of a liquid crystal polymer, while contacting at least one surface of the film with a supporting body, to melt the polymer; cooling the melted polymer to form a solidified polymer layer; and separating the solidified polymer layer from the supporting body. The process readily provides liquid crystal polymer films having excellent resistance to intra-layer delamination and high tensile strength and elongation, as well as excellent resistance to abrasion, dimensional stability when heated, and resistance to folding.
Abstract:
This invention discloses laminates comprising dyed liquid crystalline polymer based polarizers in the middle with a non-peelable, non-liquid crystalline polymeric cover layers, prepared by a process of coextrusion. The laminates are suitable to prepare liquid crystal display devices therefrom. An illustrative laminate comprises a dyed liquid crystal polymer as the polarizing film with polyethylene terephthalate as the cover layers.
Abstract:
Multilayer laminates including films, sheets, preforms, containers and other articles having at least one wholly aromatic, amorphous, stretchable liquid crystalline polymer layer with at least one non-polyester thermoplastic polymer layer are provided as well as methods for producing and stretching the multilayer articles. The laminates are suitable for thermoforming and stretch blow molding applications and may be stretched at temperatures lower than the molten state of the liquid crystal polymer and at high total draw ratios without fractures or tears. Containers suitable for food or beverage products may be produced from the laminates.
Abstract:
The surface of an aromatic liquid crystalline polyester film is modified to have improved adhesion by: (a) applying an adhesion-promoting coating to the film; (b) subsequently heating the film to a temperature above the melting point of the polyester; and, (c) applying pressure to the heated film. Preferably, the film is placed between two portions of a release film (e.g. a polyimide) prior to applying pressure.
Abstract:
The present invention relates to a stretchable blend comprising a stretchable liquid crystal polymer and a thermoplastic. These stretchable blends can be stretched at the same temperature range as many conventional thermoplastics. During a post orientation process, such as fiber or film stretching, the stretchable liquid crystal polymer can stretch and deform along with the thermoplastic matrix maintaining adhesion between the liquid crystal polymer domains and the thermoplastic matrix thereby improving the physical properties of the oriented article.
Abstract:
A film having a roughened surface. The film is made of an LCP and has surface recessions covering at least about 25% of the area of the surface. The film is made by pressing an embossing means against the film surface at a temperature about 15.degree.-75.degree. C. below the melting point of the polymer. The embossed film has improved resistance to abrasion.
Abstract:
This invention discloses laminates comprising a liquid crystal polymer film inside and non-adherent, non-liquid crystalline polymer film on the outside, prepared by a process of coextrusion. Delamination of the outside layers yields a liquid crystal polymer film of superior surface quality. The invention is particularly suitable for preparing liquid crystal polymer-based polarizers with improved surface quality.
Abstract:
The invention provides a multilayer microelectronic circuit board including a laminate of a plurality of circuit layers containing conductive vias within the layers or a combination of conductive vias and conductive wiring patterns on a surface of the layers, the layers comprising a first liquid crystal polymer and, interposed between said circuit layers, a layer of second liquid crystal polymer having a melting point of at least about 10.degree. C. lower than the melting point of the first liquid crystal polymer. The boards are produced by stacking a plurality of circuit layer sheets in appropriate electrical alignment such that they are separated by an interposed layer of the second liquid crystal polymer of lower melting point, and heating the stacked polymer sheets under pressure sufficient to bond the sheets or layers into a microelectronic printed circuit board, the temperature of the heating being sufficient to melt the lower melting second polymer but insufficient to melt the polymer present in the circuit layers. The second polymer layer may be interposed as a separate sheet during assembly or may be present as one or two separate surface layers in contact with the higher melting point polymer of the circuit layers.