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公开(公告)号：US09154058B2
公开(公告)日：2015-10-06
申请号：US13125993
申请日：2009-08-17
申请人： Ray H. Baughman , Ali E. Aliev , Jiyoung Oh , Mikhail Kozlov , Shaoli Fang , Raquel Ovalle-Robles , Anvar A. Zakhidov
发明人： Ray H. Baughman , Ali E. Aliev , Jiyoung Oh , Mikhail Kozlov , Shaoli Fang , Raquel Ovalle-Robles , Anvar A. Zakhidov
CPC分类号： H02N11/006 , H02N1/006
摘要： Nanofiber actuators and strain amplifiers having a material that generates a force or generates a displacement when directly or indirectly electrically driven. This material is an aerogel or a related low density or high density network comprising conducting fibers that are electrically interconnected and can substantially actuate without the required presence of either a liquid or solid electrolyte. Reversible or permanently frozen actuation is used to modify the properties of the actuator material for applications.
摘要翻译： 纳米纤维致动器和应变放大器具有在直接或间接电驱动时产生力或产生位移的材料。 该材料是气凝胶或相关的低密度或高密度网络，其包括导电纤维，其电互连并且可基本上致动而不需要液体或固体电解质的存在。 使用可逆或永久冷冻致动来修改用于应用的致动器材料的特性。
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公开(公告)号：US20120000293A1
公开(公告)日：2012-01-05
申请号：US13125993
申请日：2009-08-17
申请人： Ray H. Baughman , Ali E. Aliev , Jiyoung Oh , Mikhail Kozlov , Shaoli Fang , Raquel Ovalle-Robles , Anvar A. Zakhidov
发明人： Ray H. Baughman , Ali E. Aliev , Jiyoung Oh , Mikhail Kozlov , Shaoli Fang , Raquel Ovalle-Robles , Anvar A. Zakhidov
IPC分类号： G01F1/56 , H01Q1/08 , H01J1/02 , G02B5/18 , G02B5/30 , H04R1/00 , H01L41/04 , H01J35/00 , B82Y15/00
CPC分类号： H02N11/006 , H02N1/006
摘要： Nanofiber actuators and strain amplifiers having a material that generates a force or generates a displacement when directly or indirectly electrically driven. This material is an aerogel or a related low density or high density network comprising conducting fibers that are electrically interconnected and can substantially actuate without the required presence of either a liquid or solid electrolyte. Reversible or permanently frozen actuation is used to modify the properties of the actuator material for applications.
摘要翻译： 纳米纤维致动器和应变放大器具有在直接或间接电驱动时产生力或产生位移的材料。 该材料是气凝胶或相关的低密度或高密度网络，其包括导电纤维，其电互连并且可基本上致动而不需要液体或固体电解质的存在。 使用可逆或永久冷冻致动来修改用于应用的致动器材料的特性。
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公开(公告)号：US08968756B2
公开(公告)日：2015-03-03
申请号：US13322880
申请日：2010-05-27
申请人： Shaoli Fang , Marcio Dias Lima , Xavier N. Lepro-Chavez , Javier Carretero-Gonzalez , Elizabeth Castillo-Martinez , Raquel Ovalle-Robles , Carter Sebastian Haines , David Michael Novitski , Mohammad H. Haque , Chihye Lewis-Azad , Mikhail Kozlov , Anvar A. Zakhidov , Ray H. Baughman
发明人： Shaoli Fang , Marcio Dias Lima , Xavier N. Lepro-Chavez , Javier Carretero-Gonzalez , Elizabeth Castillo-Martinez , Raquel Ovalle-Robles , Carter Sebastian Haines , David Michael Novitski , Mohammad H. Haque , Chihye Lewis-Azad , Mikhail Kozlov , Anvar A. Zakhidov , Ray H. Baughman
IPC分类号： A01N25/34 , H01M4/133 , D01F9/12 , H01M4/131 , H01M4/1391 , H01M4/1393 , H01M4/58 , H01M4/587 , H01M4/96 , D02G3/16 , A61L15/18 , A61L17/04 , H01M8/00 , H01M10/0525
CPC分类号： H01M4/04 , A61K9/7007 , A61L15/18 , A61L17/04 , A61L31/024 , A61L31/16 , A61L2300/108 , A61L2300/414 , A61L2300/418 , A61L2400/12 , B01J21/063 , B01J21/18 , B01J21/185 , B01J23/42 , B01J35/0006 , B01J35/004 , B01J35/06 , B01J37/0215 , B01J37/0238 , B05D3/12 , B05D5/00 , C23C14/04 , C23C14/58 , C23C16/04 , C23C16/56 , D01F9/12 , D02G3/16 , D10B2101/122 , H01B12/06 , H01G11/86 , H01M4/0402 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/5825 , H01M4/587 , H01M4/96 , H01M8/00 , H01M10/0525 , Y02E60/122 , Y02E60/50 , Y10T428/2918 , Y10T428/2929
摘要： Fabrication of yarns or other shaped articles from materials in powder form (or nanoparticles or nanofibers) using carbon nanotube/nanofiber sheet as a platform (template). This includes methods for fabricating biscrolled yarns using carbon nanotube/nanofiber sheets and biscrolled fibers fabricated thereby.
摘要翻译： 使用碳纳米管/纳米纤维片作为平台（模板）从粉末形式的材料（或纳米颗粒或纳米纤维）制造纱线或其他成型制品。 这包括使用碳纳米管/纳米纤维片材制造双曲线纱线的方法和由此制造的双曲线纤维。
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公开(公告)号：US20120100203A1
公开(公告)日：2012-04-26
申请号：US13322880
申请日：2010-05-27
申请人： Shaoli Fang , Marcio Dias Lima , Xavier N. Lepro-Chavez , Javier Carretero-Gonzalez , Elizabeth Castillo-Martinez , Raquel Ovalle-Robles , Carter Sebastian Haines , David Michael Novitski , Mohammad H. Haque , Chihye Lewis-Azad , Mikhail Kozlov , Anvar A. Zakhidov , Ray H. Baughman
发明人： Shaoli Fang , Marcio Dias Lima , Xavier N. Lepro-Chavez , Javier Carretero-Gonzalez , Elizabeth Castillo-Martinez , Raquel Ovalle-Robles , Carter Sebastian Haines , David Michael Novitski , Mohammad H. Haque , Chihye Lewis-Azad , Mikhail Kozlov , Anvar A. Zakhidov , Ray H. Baughman
IPC分类号： A61K9/70 , B01J37/02 , B01J21/06 , B01J35/06 , H01B1/00 , B05D5/12 , H01L39/24 , H01L39/02 , D02G3/00 , C12N5/07 , C01B13/02 , B82Y40/00 , B82Y5/00
CPC分类号： H01M4/04 , A61K9/7007 , A61L15/18 , A61L17/04 , A61L31/024 , A61L31/16 , A61L2300/108 , A61L2300/414 , A61L2300/418 , A61L2400/12 , B01J21/063 , B01J21/18 , B01J21/185 , B01J23/42 , B01J35/0006 , B01J35/004 , B01J35/06 , B01J37/0215 , B01J37/0238 , B05D3/12 , B05D5/00 , C23C14/04 , C23C14/58 , C23C16/04 , C23C16/56 , D01F9/12 , D02G3/16 , D10B2101/122 , H01B12/06 , H01G11/86 , H01M4/0402 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/5825 , H01M4/587 , H01M4/96 , H01M8/00 , H01M10/0525 , Y02E60/122 , Y02E60/50 , Y10T428/2918 , Y10T428/2929
摘要： Fabrication of yarns or other shaped articles from materials in powder form (or nanoparticles or nanofibers) using carbon nanotube/nanofiber sheet as a platform (template). This includes methods for fabricating biscrolled yarns using carbon nanotube/nanofiber sheets and biscrolled fibers fabricated thereby.
摘要翻译： 使用碳纳米管/纳米纤维片作为平台（模板）从粉末形式的材料（或纳米颗粒或纳米纤维）制造纱线或其他成形制品。 这包括使用碳纳米管/纳米纤维片材制造双向卷线纱的方法和由此制造的双曲线纤维。
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5.发明申请FABRICATION AND APPLICATION OF NANOFIBER RIBBONS AND SHEETS AND TWISTED AND NON-TWISTED NANOFIBER YARNS 有权纳米纤维和薄片的织造和应用以及双向和非捻合的纳米纤维纱公开(公告)号：US20150308018A1
公开(公告)日：2015-10-29
申请号：US14332632
申请日：2014-07-16
申请人： Mei Zhang , Shaoli Fang , Ray H. Baughman , Anvar A. Zakhidov , Kenneth Ross Atkinson , Ali E. Aliev , Sergey Li , Chris Williams
发明人： Mei Zhang , Shaoli Fang , Ray H. Baughman , Anvar A. Zakhidov , Kenneth Ross Atkinson , Ali E. Aliev , Sergey Li , Chris Williams
CPC分类号： C01B32/158 , B01L3/502707 , B29C47/0059 , B32B5/02 , B32B5/12 , B32B18/00 , B32B37/12 , B32B2262/106 , B32B2307/202 , B32B2310/00 , B32B2313/04 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/154 , C01B32/16 , C01B32/164 , C01B32/168 , C01B32/17 , C01B32/18 , C01B32/36 , C01B2202/06 , C01B2202/08 , C04B35/62231 , C04B35/62272 , C04B35/62281 , C04B35/62855 , C04B35/62892 , C04B35/62897 , C04B35/80 , C04B2235/422 , C04B2235/5248 , C04B2235/526 , C04B2235/5264 , C04B2235/616 , C23C16/44 , C23C16/50 , D01F9/08 , D01F9/12 , D01F9/127 , D01F9/1273 , D01F9/1275 , D02G3/16 , D02G3/28 , D02G3/44 , D04H3/002 , D06B15/00 , D06M15/256 , D06M15/333 , D10B2101/122 , G01L1/2287 , G02F1/133308 , G02F2001/133334 , G02F2001/1515 , H01B1/24 , H01B5/08 , H01G11/36 , H01L51/0048 , H01L51/444 , H01L51/5206 , H01L51/5234 , H01L51/5296 , H01M4/8605 , H01M4/926 , H01M10/0565 , H05K9/0081 , Y02E10/549 , Y02E60/13 , Y02P70/521 , Y10S977/742 , Y10S977/745 , Y10S977/746 , Y10S977/752 , Y10S977/843 , Y10S977/844 , Y10S977/847 , Y10S977/848 , Y10S977/932 , Y10S977/948 , Y10S977/961 , Y10T428/30
摘要： The present invention is directed to nanofiber yarns, ribbons, and sheets; to methods of making said yarns, ribbons, and sheets; and to applications of said yarns, ribbons, and sheets. In some embodiments, the nanotube yarns, ribbons, and sheets comprise carbon nanotubes. Particularly, such carbon nanotube yarns of the present invention provide unique properties and property combinations such as extreme toughness, resistance to failure at knots, high electrical and thermal conductivities, high absorption of energy that occurs reversibly, up to 13% strain-to-failure compared with the few percent strain-to-failure of other fibers with similar toughness, very high resistance to creep, retention of strength even when heated in air at 450° C. for one hour, and very high radiation and IJV resistance, even when irradiated in air. Furthermore these nanotube yarns can be spun as one micron diameter yarns and plied at will to make two-fold, four-fold, and higher fold yarns. Additional embodiments provide for the spinning of nanofiber sheets having arbitrarily large widths. In still additional embodiments, the present invention is directed to applications and devices that utilize and/or comprise the nanofiber yarns, ribbons, and sheets of the present invention.
摘要翻译： 本发明涉及纳米纤维纱线，丝带和片材; 制造所述纱线，丝带和片材的方法; 以及所述纱线，丝带和片材的应用。 在一些实施方案中，纳米管纱线，带状物和片材包含碳纳米管。 特别地，本发明的这种碳纳米管纱线提供独特的性能和性能组合，例如极韧性，耐击穿能力差，电导率和导热性高，可逆地发生高达13％的应变 - 失效的能量的高吸收 与具有相似韧性的其他纤维的几个百分比应变破坏相比，非常高的抗蠕变性，即使在450℃下在空气中加热一小时也能保持强度，并且具有非常高的辐射和IJV电阻，即使 在空气中照射 此外，这些纳米管纱线可以作为一微米直径的纱线纺丝并且随意地分层以制备两倍，四倍和更高的折叠纱线。 另外的实施例提供了具有任意大宽度的纳米纤维片材的纺丝。 在另外的实施例中，本发明涉及利用和/或包含本发明的纳米纤维纱线，带状物和片材的应用和装置。
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6.发明申请Fabrication and Application of Nanofiber Ribbons and Sheets and Twisted and Non-Twisted Nanofiber Yarns 有权纳米纤维丝束和扭曲和非扭曲纳米纤维纱的制备和应用公开(公告)号：US20080170982A1
公开(公告)日：2008-07-17
申请号：US11718954
申请日：2005-11-09
申请人： Mei Zhang , Shaoli Fang , Ray H. Baughman , Anvar A. Zakhidov , Kenneth Ross Atkinson , Ali E. Aliev , Sergey Li , Chris Williams
发明人： Mei Zhang , Shaoli Fang , Ray H. Baughman , Anvar A. Zakhidov , Kenneth Ross Atkinson , Ali E. Aliev , Sergey Li , Chris Williams
IPC分类号： C01B31/02
CPC分类号： C01B32/158 , B01L3/502707 , B29C47/0059 , B32B5/02 , B32B5/12 , B32B18/00 , B32B37/12 , B32B2262/106 , B32B2307/202 , B32B2310/00 , B32B2313/04 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/154 , C01B32/16 , C01B32/164 , C01B32/168 , C01B32/17 , C01B32/18 , C01B32/36 , C01B2202/06 , C01B2202/08 , C04B35/62231 , C04B35/62272 , C04B35/62281 , C04B35/62855 , C04B35/62892 , C04B35/62897 , C04B35/80 , C04B2235/422 , C04B2235/5248 , C04B2235/526 , C04B2235/5264 , C04B2235/616 , C23C16/44 , C23C16/50 , D01F9/08 , D01F9/12 , D01F9/127 , D01F9/1273 , D01F9/1275 , D02G3/16 , D02G3/28 , D02G3/44 , D04H3/002 , D06B15/00 , D06M15/256 , D06M15/333 , D10B2101/122 , G01L1/2287 , G02F1/133308 , G02F2001/133334 , G02F2001/1515 , H01B1/24 , H01B5/08 , H01G11/36 , H01L51/0048 , H01L51/444 , H01L51/5206 , H01L51/5234 , H01L51/5296 , H01M4/8605 , H01M4/926 , H01M10/0565 , H05K9/0081 , Y02E10/549 , Y02E60/13 , Y02P70/521 , Y10S977/742 , Y10S977/745 , Y10S977/746 , Y10S977/752 , Y10S977/843 , Y10S977/844 , Y10S977/847 , Y10S977/848 , Y10S977/932 , Y10S977/948 , Y10S977/961 , Y10T428/30
摘要： The present invention is directed to methods of making nanofiber yarns. In some embodiments, the nanotube yarns comprise carbon nanotubes. Particularly, such carbon nanotube yarns of the present invention provide unique properties and property combinations such as extreme toughness, resistance to failure at knots, high electrical and thermal conductivities, high absorption of energy that occurs reversibly, up to 13% strain-to-failure compared with the few percent strain-to-failure of other fibers with similar toughness, very high resistance to creep, retention of strength even when heated in air at 450° C. for one hour, and very high radiation and UV resistance, even when irradiated in air.
摘要翻译： 本发明涉及制造纳米纤维纱线的方法。 在一些实施例中，纳米管纱线包括碳纳米管。 特别地，本发明的这种碳纳米管纱线提供独特的性能和性能组合，例如极韧性，耐击穿能力差，电导率和导热性高，可逆地发生高达13％的应变 - 失效的能量的高吸收 与具有相似韧性的其他纤维的几个百分比应变破坏相比，非常高的抗蠕变性，即使在450℃的空气中加热一个小时也能保持强度，并且具有非常高的辐射和抗紫外线性，即使 在空气中照射
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7.发明授权Spinning, processing, and applications of carbon nanotube filaments, ribbons, and yarns 失效纺丝，加工和应用碳纳米管长丝，丝带和纱线公开(公告)号：US07247290B2
公开(公告)日：2007-07-24
申请号：US10700387
申请日：2003-11-04
申请人： Alex Lobovsky , Jim Matrunich , Mikhail Kozlov , Robert C. Morris , Ray H. Baughman , Anvar A. Zakhidov
发明人： Alex Lobovsky , Jim Matrunich , Mikhail Kozlov , Robert C. Morris , Ray H. Baughman , Anvar A. Zakhidov
CPC分类号： D01D5/06 , B82Y30/00 , D01F9/1278 , D10B2101/122 , Y10S977/742 , Y10S977/75 , Y10S977/762 , Y10S977/842 , Y10S977/888
摘要： Coagulation spinning produces structures such as fibers, ribbons, and yarns of carbon nanotubes. Stabilization, orientation, and shaping of spun materials are achieved by post-spinning processes. Advantages include the elimination of core-sheath effects due to carbonaceous contaminants, increasing mechanical properties, and eliminating dimensional instabilities in liquid electrolytes that previously prohibited the application of these spun materials in electrochemical devices. These advances enable the application of coagulation-spun carbon nanotube fibers, ribbons, and yarns in actuators, supercapacitors, and in devices for electrical energy harvesting.
摘要翻译： 凝结纺丝产生诸如纤维，带状物和碳纳米管的结构。 纺丝材料的稳定化，取向和成型通过后纺丝方法实现。 优点包括消除由碳质污染物引起的芯鞘效应，增加机械性能，消除以前禁止在电化学装置中应用这些纺丝材料的液体电解质的尺寸不稳定性。 这些进展使得能够在致动器，超级电容器和用于电能收集的装置中应用凝结纺丝的碳纳米管纤维，带和纱线。
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8.发明授权Spinning, processing, and applications of carbon nanotube filaments, ribbons, and yarns 失效纺丝，加工和应用碳纳米管长丝，丝带和纱线公开(公告)号：US06682677B2
公开(公告)日：2004-01-27
申请号：US09946432
申请日：2001-09-04
申请人： Alex Lobovsky , Jim Matrunich , Mikhail Kozlov , Robert C. Morris , Ray H. Baughman , Anvar A. Zakhidov
发明人： Alex Lobovsky , Jim Matrunich , Mikhail Kozlov , Robert C. Morris , Ray H. Baughman , Anvar A. Zakhidov
IPC分类号： D01D528
CPC分类号： D01D5/06 , B82Y30/00 , D01F9/1278 , D10B2101/122 , Y10S977/742 , Y10S977/75 , Y10S977/762 , Y10S977/842 , Y10S977/888
摘要： Coagulation spinning produces structures such as fibers, ribbons, and yarns of carbon nanotubes. Stabilization, orientation, and shaping of spun materials are achieved by post-spinning processes. Advantages include the elimination of core-sheath effects due to carbonaceous contaminants, increasing mechanical properties, and eliminating dimensional instabilities in liquid electrolytes that previously prohibited the application of these spun materials in electrochemical devices. These advances enable the application of coagulation-spun carbon nanotube fibers, ribbons, and yarns in actuators, supercapacitors, and in devices for electrical energy harvesting.
摘要翻译： 凝结纺丝产生诸如纤维，带状物和碳纳米管的结构。 纺丝材料的稳定化，取向和成型通过后纺丝方法实现。 优点包括消除由碳质污染物引起的芯鞘效应，增加机械性能，消除以前禁止在电化学装置中应用这些纺丝材料的液体电解质的尺寸不稳定性。 这些进展使得能够在致动器，超级电容器和用于电能收集的装置中应用凝结纺丝的碳纳米管纤维，带和纱线。
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公开(公告)号：US06991847B2
公开(公告)日：2006-01-31
申请号：US10068273
申请日：2002-02-07
CPC分类号： B82Y20/00 , C30B5/00 , C30B29/60 , G02B6/1225 , Y10T428/249953 , Y10T428/249974 , Y10T428/249979 , Y10T428/249981 , Y10T428/24999 , Y10T428/8305
摘要： The invention relates to processes for the synthesis of 2-D and 3-D periodic porous silicon structures and composites with improved properties having the advantages of porous silicon and photonic bandgap materials. Photonic crystals comprise a two dimensionally periodic or three dimensionally periodic microporous structural matrix of interconnecting, crystallographically oriented, monodispersed members having voids between adjacent members, and said members additionally having randomly nanoporous surface porosity. The silicon nanofoam material shows enhanced and spectrally controlled/tunable photoluminescence and electroluminesce and finds use as transparent electrodes, high-lumonosity light emitting diodes (LEDs), wavelength division multiplexors, high-active-area catalyst supports, photonic bandgap lasers, silicon-based UV detectors, displays, gas sensors, and the like.
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10.发明授权公开(公告)号：US07718230B2
公开(公告)日：2010-05-18
申请号：US11271571
申请日：2005-11-11
申请人： Anvar A. Zakhidov , Rashmi Nanjundaswamy , Sergey Li , Alexander Zakhidov , Mei Zhang , Ray H. Baughman
发明人： Anvar A. Zakhidov , Rashmi Nanjundaswamy , Sergey Li , Alexander Zakhidov , Mei Zhang , Ray H. Baughman
CPC分类号： B81C1/00111 , H01J9/025 , Y10S977/89 , Y10T428/30
摘要： The present invention provides a method and apparatus for transferring an array of oriented carbon nanotubes from a first surface to a second surface by providing the array of oriented carbon nanotubes on the first surface within a vacuum chamber, providing the second surface within the vacuum chamber separate from the first surface, and applying an electric potential between the first surface and the second surface such that the array of oriented carbon nanotubes are sublimed from the first surface and re-deposited on the second surface.
摘要翻译： 本发明提供了一种通过在真空室内的第一表面上提供定向碳纳米管阵列将定向碳纳米管阵列从第一表面转移到第二表面的方法和装置，提供真空室内的第二表面分开 并且在所述第一表面和所述第二表面之间施加电位使得所述定向碳纳米管阵列从所述第一表面升华并且重新沉积在所述第二表面上。
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