Integrate chemical processes for industrial utilization of seed oils
    2.
    发明授权
    Integrate chemical processes for industrial utilization of seed oils 有权
    整合化学工业用于种子油的工业利用

    公开(公告)号:US07576227B2

    公开(公告)日:2009-08-18

    申请号:US10508805

    申请日:2003-04-17

    IPC分类号: C07C57/00 C07C53/00

    摘要: Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ωpolyester polyamine.

    摘要翻译: 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法,其基本上不含复分解催化剂毒物,特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃,优选还原链的α-烯烃和还原链不饱和酸或酯,优选还原链的α,ω-不饱和酸 或酯。 还原链不饱和酸或酯可以(反式)酯化以形成聚酯聚烯烃,其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α,ω-羟基酸或α,ω-羟基酯,其可以与多元醇反应形成α,ω-聚酯多元醇。 或者,还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α,ω-氨基酸或α,ω-氨基酯,其可以(反式)酯化形成α,ω-聚酯多胺。

    Process for cleaning fouled heat exchangers
    10.
    发明授权
    Process for cleaning fouled heat exchangers 失效
    清洗污水热交换器的工艺

    公开(公告)号:US4099984A

    公开(公告)日:1978-07-11

    申请号:US793328

    申请日:1977-05-03

    IPC分类号: C23G5/00 F28G9/00 B08B3/08

    CPC分类号: C23G5/00 F28G9/00

    摘要: Heat exchangers which become fouled during cooling of CuAlCl.sub.4 .multidot.solvent (such as toluene) solutions employed in extracting carbon monoxide from acetylene is cleaned by circulating through the fouled exchanger a solvent solution of CuAlCl.sub.4 .multidot.solvent containing aluminum trichloride.

    摘要翻译: 在用于从乙炔中提取一氧化碳的CuAlCl4溶剂(例如甲苯)溶液冷却期间被弄脏的热交换器通过污垢交换器循环通过含有三氯化铝的CuAlCl4溶剂的溶剂来清洗。