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    Spatially-Controlled Synthesis of Palladium-Rhodium Hetero-Nanostructures
    9.
    发明申请
    Spatially-Controlled Synthesis of Palladium-Rhodium Hetero-Nanostructures 有权
    钯 - 铑杂 - 纳米结构的空间控制合成

    公开(公告)号：US20150069015A1

    公开(公告)日：2015-03-12

    申请号：US14481256

    申请日：2014-09-09

    申请人： Younan Xia ,  Shuifen Xie

    发明人： Younan Xia ,  Shuifen Xie

    IPC分类号： C30B29/60 ,  C30B29/52 ,  C30B19/12

    CPC分类号： C30B29/607 ,  C30B7/00 ,  C30B7/005 ,  C30B7/14 ,  C30B19/12 ,  C30B29/02 ,  C30B29/52 ,  C30B29/60

    摘要： In a method of generating a nanocrystal with a core-frame structure, a seed crystal, including a first substance, is exposed to a capping agent. The seed nanocrystal has a plurality of first portions that each has a first characteristic and a plurality of second portions that each has a second characteristic, different from the first characteristic. The capping agent has a tendency to adsorb to portions having the first characteristic and has a tendency not to adsorb to portions having the second characteristic. As a result, a selectively capped seed nanocrystal is generated. The selectively capped seed nanocrystal is exposed to a second substance that has a tendency to nucleate on the plurality of second portions and that does not have a tendency to nucleate on portions that have adsorbed the capping agent, thereby generating a frame structure from the plurality of second portions of the seed nanocrystal.

    摘要翻译： 在制造具有芯框架结构的纳米晶体的方法中，将包含第一物质的晶种暴露于封端剂。 种子纳米晶体具有多个第一部分，每个第一部分具有第一特征和多个第二部分，每个第二部分具有与第一特征不同的第二特征。 封端剂具有吸附到具有第一特性的部分的倾向，并且具有不吸附到具有第二特性的部分的倾向。 结果，产生选择性封盖的种子纳米晶体。 选择性封盖的种子纳米晶体暴露于在多个第二部分上具有成核趋势的第二物质，并且在具有吸附封端剂的部分上不具有成核的倾向，从而从多个第二部分生成框架结构 种子纳米晶体的第二部分。