公开(公告)号：US20240279494A1

公开(公告)日：2024-08-22

申请号：US18560366

申请日：2022-03-28

Applicant: STELLA CHEMIFA CORPORATION

Inventor： Hiroya YAMAMOTO ,  Rui HASEBE ,  Megumi TOMISAKI ,  Masanori URAYA ,  Tetsuo NISHIDA ,  Keiichi NII ,  Keigo FUJIWARA

IPC: C09D7/61 ,  C09D5/00 ,  C09D5/02 ,  C09D7/20 ,  C09D7/40 ,  C09D7/45 ,  G02B1/11

CPC classification number: C09D7/61 ,  C09D5/006 ,  C09D5/027 ,  C09D7/20 ,  C09D7/45 ,  C09D7/67 ,  G02B1/11

Abstract: Provided are a liquid dispersion of fluoride particles having a refractive index lower than that of, for example, magnesium fluoride, the liquid dispersion being excellent in dispersibility and suitable for production of an optical film such as an antireflection film; a composition for forming an optical film; and an optical film. A liquid dispersion of fluoride particles according to the present invention contains: fluoride particles; an anionic surfactant as a dispersant for the fluoride particles; and an organic solvent, wherein the fluoride particles contain at least aluminum, an alkali metal, and an alkaline earth metal as an optional element in a composition of the fluoride particles, and the fluoride particles are dispersed in the organic solvent.

公开(公告)号：US09376323B2

公开(公告)日：2016-06-28

申请号：US13377795

申请日：2009-06-19

Applicant: Masahide Waki ,  Kazuhiro Miyamoto ,  Kazutaka Hirano

Inventor： Masahide Waki ,  Kazuhiro Miyamoto ,  Kazutaka Hirano

IPC: C01B35/06 ,  H01M10/0525 ,  H01M10/0568

CPC classification number: C01B35/063 ,  C01B35/066 ,  H01M10/0525 ,  H01M10/0568 ,  Y02E60/122 ,  Y02P70/54

Abstract: An object of the invention is to provide a tetrafluoroborate producing method that allows high-yield, high-efficiency production of a tetrafluoroborate by a continuous process, a tetrafluoroborate-containing electrolyte, and an electrical storage device including such an electrolyte. The invention provides a method for producing a tetrafluoroborate, which includes: a first step including dissolving boron trifluoride gas in an organic solvent; a second step including adding, to the organic solvent, a fluoride (MFn, wherein M represents a metal or NH4, and 1≦n≦3) in an amount stoichiometrically equivalent to or less than the amount of the boron trifluoride so that a tetrafluoroborate solution is produced; and a third step including circulating the tetrafluoroborate solution through the first step so that the boron trifluoride gas is dissolved in the tetrafluoroborate solution instead of the organic solvent.

Abstract translation: 本发明的目的是提供一种四氟硼酸盐的制造方法，其能够通过连续工艺，含有四氟硼酸盐的电解质和包含这种电解质的蓄电装置高产率，高效率地生产四氟硼酸盐。 本发明提供一种四氟硼酸盐的制造方法，其特征在于，包括：将三氟化硼气体溶解在有机溶剂中的第一工序; 第二步，包括以化学计量等于或少于三氟化硼的量向有机溶剂中加入氟化物（MFn，其中M表示金属或NH4，以及1＆amp; NlE; n＆amp; NlE; 3），使得四氟硼酸盐 生产溶液; 以及第三步骤，包括使第一步骤中的四氟硼酸溶液循环，使得三氟化硼气体溶解在四氟硼酸盐溶液中而不是有机溶剂。

公开(公告)号：US20160075557A1

公开(公告)日：2016-03-17

申请号：US14419181

申请日：2014-06-06

Applicant: STELLA CHEMIFA CORPORATION

Inventor： Naoki Yahata ,  Tetsuo Nishida

IPC: C01B25/455

CPC classification number: C01B25/455 ,  B01J31/0288 ,  C01P2006/80 ,  H01M10/0525 ,  H01M10/0567 ,  H01M2300/0025

Abstract: Provided is a method for purifying a difluorophosphate, in which a difluorophosphate is purified to a high purity. The method includes a method for purifying a difluorophosphate, comprising bringing hydrogen fluoride into contact with a difluorophosphate containing an impurity and subsequently heating and drying the difluorophosphate, or bringing the hydrogen fluoride into contact with the difluorophosphate containing the impurity while heating and drying the difluorophosphate containing the impurity, thereby removing the impurity.

Abstract translation: 提供了一种纯化二氟磷酸盐以纯化至高纯度的二氟磷酸盐的方法。 该方法包括一种纯化二氟磷酸盐的方法，包括使氟化氢与含有杂质的二氟磷酸盐接触，随后加热和干燥二氟磷酸盐，或使氟化氢与含有杂质的二氟磷酸盐接触，同时加热和干燥含二氟磷酸盐 杂质，从而除去杂质。

公开(公告)号：US09028786B2

公开(公告)日：2015-05-12

申请号：US13113541

申请日：2011-05-23

Applicant: Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

Inventor： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC: C01B25/10 ,  H01M10/02 ,  H01M10/052 ,  C01B25/455 ,  H01M10/0569 ,  H01M10/0567

CPC classification number: H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

Abstract: To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

公开(公告)号：US08366956B2

公开(公告)日：2013-02-05

申请号：US12926313

申请日：2010-11-09

Applicant: Tetsuo Nishida ,  Yasutaka Tashiro ,  Megumi Tomisaki ,  Masashi Yamamoto ,  Kazutaka Hirano ,  Akihiro Nabeshima ,  Hiroaki Tokuda ,  Kenji Sato ,  Takashi Higono

Inventor： Tetsuo Nishida ,  Yasutaka Tashiro ,  Megumi Tomisaki ,  Masashi Yamamoto ,  Kazutaka Hirano ,  Akihiro Nabeshima ,  Hiroaki Tokuda ,  Kenji Sato ,  Takashi Higono

IPC: C07D207/06 ,  H01L31/04

CPC classification number: C07D207/08 ,  H01G9/038 ,  H01G11/60 ,  H01G11/62 ,  H01M6/164 ,  H01M6/166 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

Abstract: A quaternary ammonium salt of the formula (1), a composition containing the quaternary ammonium salt and an organic solvent, and an electrochemical device using the salt wherein R1 and R2 are both methyl and X− is BF4− or N(CF3SO2)2−.

Abstract translation: 式（1）的季铵盐，含有季铵盐和有机溶剂的组合物和使用盐的电化学装置，其中R 1和R 2都是甲基，X-是BF 4 - 或N（CF 3 SO 2）2 - 。

公开(公告)号：US08293411B2

公开(公告)日：2012-10-23

申请号：US13002090

申请日：2009-12-01

Applicant: Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

Inventor： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC: C01B25/10

CPC classification number: H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

Abstract: To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

Abstract translation: 提供一种简单且容易地生产高纯度二氟磷酸盐的技术，并提供使用所得二氟磷酸盐，电解液和二次电池的电解液的生产方法。 一种制备二氟磷酸盐的方法，包括以下步骤（1）或（2）：（1）使（A）选自含氧酸，含氧酸酐和磷卤氧化物中的至少一种与（B）六氟磷酸盐 在氟化氢存在下，或（2）在六氟磷酸盐存在下使选自碱金属卤化物，碱土金属卤化物，卤化铝和卤化铪中的至少一种卤化物与二氟磷酸反应。 另外，含有所得二氟磷酸盐的非水电解液和含有非水电解液的非水电解二次电池。

公开(公告)号：US20120172210A1

公开(公告)日：2012-07-05

申请号：US13177260

申请日：2011-07-06

Applicant: Masayoshi ISHIDA ,  Shinji HASHIGUCHI ,  Yasutaka TASHIRO

Inventor： Masayoshi ISHIDA ,  Shinji HASHIGUCHI ,  Yasutaka TASHIRO

IPC: B01J27/13 ,  C01G55/00 ,  B82Y30/00

CPC classification number: H01M4/8663 ,  B01J23/42 ,  B01J37/26 ,  H01M4/8605 ,  H01M4/92 ,  H01M4/926

Abstract: The invention aims at providing a platinum black material, without using an expensive and rare material, which is excellent in CO poisoning inhibiting effect, H2S poisoning inhibiting effect, SO4 poisoning inhibiting effect and HCHO poisoning inhibiting effect, and a method for fluorinating platinum black. The platinum black material is characterized by fluorine adsorbed on its surface. The method for fluorinating platinum black is characterized by allowing platinum black to stand in a mixed gas atmosphere of n inert gas and fluorine in a low-pressure chamber to make fluorine adsorbed on the surface of the platinum black.

Abstract translation: 本发明的目的在于提供一种铂黑材料，而不使用具有优良的CO中毒抑制效果，H2S中毒抑制作用，SO4中毒抑制作用和HCHO中毒抑制作用的昂贵稀有材料，以及氟化铂黑的方法。 铂黑材料的特征在于其表面吸附有氟。 氟化铂黑的方法的特征在于，使铂黑在低压室中的惰性气体和氟气的混合气体气氛中放置，以使氟吸附在铂黑的表面上。

公开(公告)号：US20120065116A1

公开(公告)日：2012-03-15

申请号：US13321450

申请日：2009-05-21

Applicant: Masayuki Miyashita ,  Takanobu Kujime ,  Keiichi Nii ,  Masashi Yamamoto

Inventor： Masayuki Miyashita ,  Takanobu Kujime ,  Keiichi Nii ,  Masashi Yamamoto

IPC: C11D7/08

CPC classification number: C11D3/042 ,  C11D7/08 ,  C11D11/0047 ,  H01L21/02065

Abstract: Disclosed is a cleaning liquid which is capable of cleaning an object to be cleaned, to the surface of which cerium oxide adheres, by dissolving and removing cerium oxide in the form of cerium ions. A cleaning method using the cleaning liquid is also disclosed. The cleaning liquid for removing cerium oxide is characterized by containing hydrogen fluoride, at least one acid selected from the group consisting of hydrochloric acid, nitric acid, sulfuric acid, acetic acid, phosphoric acid, iodic acid and hydrobromic acid, and water. The cleaning liquid is also characterized by dissolving and removing cerium oxide in the form of cerium ions.

Abstract translation: 公开了一种能够通过溶解和除去铈离子形式的氧化铈，能够将被清洁物体清洁到氧化铈表面的清洗液。 还公开了使用清洗液的清洗方法。 用于除去氧化铈的清洗液的特征在于含有氟化氢，至少一种选自盐酸，硝酸，硫酸，乙酸，磷酸，碘酸和氢溴酸的酸和水。 清洗液的特征还在于以铈离子的形式溶解和去除氧化铈。

公开(公告)号：US08029689B2

公开(公告)日：2011-10-04

申请号：US12311067

申请日：2007-09-18

Applicant: Tetsuo Nishida ,  Kazutaka Hirano ,  Akinori Oka ,  Yoshinobu Abe ,  Akihiro Nabeshima

Inventor： Tetsuo Nishida ,  Kazutaka Hirano ,  Akinori Oka ,  Yoshinobu Abe ,  Akihiro Nabeshima

IPC: H01G9/02 ,  C07C209/00

CPC classification number: H01G9/038 ,  C07C213/10 ,  C07D207/06 ,  C07D233/58 ,  H01B1/122 ,  H01G9/022 ,  H01G9/035 ,  H01G11/62 ,  Y02E60/13 ,  C07C217/08

Abstract: A process for preparing a high-purity quaternary ammonium salt comprising: (1) adding an oxide or hydroxide of a Group 1, 2, 12 or 13 metal to a quaternary ammonium salt containing a protonic acid salt of a tertiary amine as an impurity and thereby neutralizing the tertiary amine protonic acid salt with the metal oxide or hydroxide to convert the acid salt to a tertiary amine and water and to convert the metal oxide or hydroxide to a metal salt at the same time, and (2) removing the tertiary amine, water and metal salt produced from the system.

Abstract translation: 一种制备高纯度季铵盐的方法，包括：（1）将第1,2,12或13族金属的氧化物或氢氧化物加入到含有作为杂质的叔胺的质子酸盐的季铵盐中，以及 与金属氧化物或氢氧化物中和叔胺质子酸盐，将酸盐转化为叔胺和水，同时将金属氧化物或氢氧化物转化为金属盐，（2）除去叔胺 ，从系统产生的水和金属盐。

公开(公告)号：US20110000423A1

公开(公告)日：2011-01-06

申请号：US12805786

申请日：2010-08-19

Applicant: Tsuguo Fukuda ,  Hirohisa Kikuyama ,  Tomohiko Satonaga

Inventor： Tsuguo Fukuda ,  Hirohisa Kikuyama ,  Tomohiko Satonaga

IPC: C30B15/08

CPC classification number: C30B15/08 ,  C01B9/08 ,  C30B29/12 ,  Y10T117/10

Abstract: Provided is an apparatus capable of producing a fluoride crystal in a very short period of time, and a method suitable for producing a fluoride crystal using the apparatus. The apparatus comprises a chamber, a window material, and the like, and is modified such that it can evacuate air from the chamber to provide a high degree vacuum there. The apparatus further includes a crucible, which has a perforation at its bottom. The capillary portion of the perforation is adjusted to facilitate the contact of a seed crystal with a melt. By using the apparatus it is possible to stably produce high quality single crystals of fluorides in a short period of time.

Abstract translation: 提供了能够在非常短的时间内产生氟化物晶体的装置，以及适用于使用该装置生产氟化物晶体的方法。 该设备包括一个室，一个窗户材料等，并且被改造成使得它可以从室中排出空气以在那里提供高度的真空度。 该装置还包括坩埚，其底部具有穿孔。 调整穿孔的毛细管部分以促进晶种与熔体的接触。 通过使用该装置，可以在短时间内稳定地生产高质量的氟化物单晶。