FILM-FORMING METHOD AND FILM-FORMING SYSTEM

    公开(公告)号:US20230090881A1

    公开(公告)日:2023-03-23

    申请号:US17932341

    申请日:2022-09-15

    IPC分类号: C23C16/16 C23C16/56

    摘要: A film-forming method of embedding ruthenium in a substrate having a recess includes: (a) providing the substrate in a processing container; (b) supplying a gas containing a ruthenium raw material gas into the processing container to form a ruthenium layer; (c) annealing the ruthenium layer; and (d) supplying a gas containing an ozone gas into the processing container to etch the ruthenium layer, wherein (b), (c), and (d) are repeatedly executed in this order.

    Selective cobalt deposition on copper surfaces

    公开(公告)号:US11384429B2

    公开(公告)日:2022-07-12

    申请号:US15598687

    申请日:2017-05-18

    摘要: Embodiments of the invention provide processes to selectively form a cobalt layer on a copper surface over exposed dielectric surfaces. In one embodiment, a method for capping a copper surface on a substrate is provided which includes positioning a substrate within a processing chamber, wherein the substrate contains a contaminated copper surface and a dielectric surface, exposing the contaminated copper surface to a reducing agent while forming a copper surface during a pre-treatment process, exposing the substrate to a cobalt precursor gas to selectively form a cobalt capping layer over the copper surface while leaving exposed the dielectric surface during a vapor deposition process, and depositing a dielectric barrier layer over the cobalt capping layer and the dielectric surface. In another embodiment, a deposition-treatment cycle includes performing the vapor deposition process and subsequently a post-treatment process, which deposition-treatment cycle may be repeated to form multiple cobalt capping layers.

    High-purity tungsten hexacarbonyl for solid source delivery

    公开(公告)号:US10526697B2

    公开(公告)日:2020-01-07

    申请号:US15556102

    申请日:2016-02-28

    申请人: ENTEGRIS, INC.

    IPC分类号: C01G41/00 C23C16/16

    摘要: A solid source material is described for forming a tungsten-containing film. The solid source material is tungsten hexacarbonyl, wherein content of molybdenum is less than 1000 ppm. Such solid source material may be formed by a process including provision of particulate tungsten hexacarbonyl raw material of particles of size less than 5 mm, wherein particles of size greater than 1.4 mm are less than 15% of the particles, and wherein content of molybdenum is less than 1000 ppm, and sintering the particulate tungsten hexacarbonyl raw material at temperature below 100° C. to produce the solid source material as a sintered solid.

    APPARATUS FOR DEPOSITING A COBALT LAYER USING A CAROUSEL BATCH DEPOSITION REACTOR

    公开(公告)号:US20180135180A1

    公开(公告)日:2018-05-17

    申请号:US15871683

    申请日:2018-01-15

    发明人: MAYUR TRIVEDI

    摘要: Methods and apparatus for depositing a cobalt layer in features formed on a substrate are provided herein. In some embodiments, a substrate processing chamber includes: a chamber body having a processing volume; a rotatable substrate support disposed within the chamber body, wherein the substrate support is configured to rotate one or more substrates arranged in a planar array between a first processing position and a second processing position, wherein the first processing position and the second processing position are independently thermally controlled; a showerhead disposed opposite the rotatable substrate support configured to expose the one or more substrates at the first processing position to a cobalt containing precursor; and a heat source disposed within the substrate support configured to heat the one or more substrates at the second processing position.