Manufacture of structures comprising silicon dioxide on a surface
    92.
    发明授权
    Manufacture of structures comprising silicon dioxide on a surface 有权
    在表面上制造包含二氧化硅的结构

    公开(公告)号:US09193599B2

    公开(公告)日:2015-11-24

    申请号:US13825472

    申请日:2011-09-21

    摘要: A substrate surface comprises at least partially at least one elongated structure, wherein each elongated structure comprises a plurality of channels, said channels extending in the direction of the longitudinal axis of the elongated structure, wherein said at least one elongated structure comprises silicon dioxide. The structures are manufactured by: a) providing a reaction solution comprising a silicate, a micelle forming agent, an alkane, a salt, and at least 1.5 M HCl, having a pH of 2 or lower, b) stirring not more than 10 minutes, c) bringing the reaction solution into contact with a substrate surface and d) treating the obtained material with one method selected from a) heat treating the material above 300° C., b) treating the material with at least one selected from H2O2, and H2SO4, c) treating the material with microwaves to digest the micelle forming agent.

    摘要翻译: 衬底表面至少部分地包括至少一个细长结构,其中每个细长结构包括多个通道,所述通道沿细长结构的纵向轴线的方向延伸,其中所述至少一个细长结构包括二氧化硅。 该结构通过以下方法制造:a)提供包含硅酸盐,胶束形成剂,烷烃,盐和至少1.5M HCl,PH为2或更低的反应溶液,b)搅拌不超过10分钟 c)使反应溶液与基材表面接触,和d)用选自以下的一种方法处理所得材料:a)将材料热处理于300℃以上,b)用至少一种选自H 2 O 2, 和H2SO4,c)用微波处理材料以消化胶束形成剂。

    Zeolite DDR nanoparticles
    94.
    发明授权
    Zeolite DDR nanoparticles 有权
    沸石DDR纳米粒子

    公开(公告)号:US08821616B2

    公开(公告)日:2014-09-02

    申请号:US13396411

    申请日:2012-02-14

    摘要: DDR nanocrystals were synthesized using hydrothermal secondary growth. The morphology of the nanoparticles can be manipulated by changing the ratio of silica to water, the synthesis temperature, and the mineralizing agents. Specifically, nanocrystals with morphology of hexagonal plates, octahedral, and diamond-like plates are disclosed. These nanoparticles can be used as seed coatings for DDR membrane growth on substrates, and for the fabrication of mixed matrix membranes, and for any other use where uniform, small DDR zeolite crystals are beneficial.

    摘要翻译: 使用水热二次生长合成DDR纳米晶体。 可以通过改变二氧化硅与水的比例,合成温度和矿化剂来操纵纳米颗粒的形态。 具体地,公开了具有六角形板,八面体和类金刚石板的形态的纳米晶体。 这些纳米颗粒可用作底物上DDR膜生长的种子涂层,以及用于混合基质膜的制造以及均匀的小型DDR沸石晶体有益的任何其它用途。

    Zeolite nano-crystal suspension, zeolite nano-crystal production method, zeolite nano-crystal suspension production method, and zeolite thin film
    95.
    发明授权
    Zeolite nano-crystal suspension, zeolite nano-crystal production method, zeolite nano-crystal suspension production method, and zeolite thin film 失效
    沸石纳米晶体悬浮液,沸石纳米晶体制备方法,沸石纳米晶体悬浮液制备方法和沸石薄膜

    公开(公告)号:US07384622B2

    公开(公告)日:2008-06-10

    申请号:US11212844

    申请日:2005-08-29

    IPC分类号: C01B39/36 C01B37/02

    CPC分类号: C01B37/02 C01B39/365

    摘要: A zeolite suspension contains MEL-type zeolite nanocrystals as a principal component. A method for the production of MEL-type zeolite nanocrystals includes the steps of aging a synthesized solution comprising TEOS, TBAOH, water and alcohol and subjecting the aged solution to hydrothermal crystallization treatment at a predetermined temperature. A method for the production of a zeolite suspension includes the steps of aging a synthesized solution comprising TEOS, TBAOH, water and alcohol, subjecting the aged solution to hydrothermal crystallization treatment to produce MEL-type zeolite nanocrystals and mixing a composition having a surfactant dissolved in at least one organic solvent or a mixed solvent of alcohol-based organic solvents, amide-based organic solvents and ketone-based organic solvents with a zeolite nano-crystal suspension containing the MEL-type zeolite nanocrystals to produce a zeolite suspension.

    摘要翻译: 沸石悬浮液含有MEL型沸石纳米晶体作为主要成分。 制造MEL型沸石纳米晶体的方法包括使包含TEOS,TBAOH,水和醇的合成溶液老化并使老化溶液在预定温度下进行水热结晶处理的步骤。 制备沸石悬浮液的方法包括将包含TEOS,TBAOH,水和醇的合成溶液老化的步骤,将老化溶液进行水热结晶处理以产生MEL型沸石纳米晶体,并将具有表面活性剂溶解的组合物 至少一种有机溶剂或醇基有机溶剂,酰胺类有机溶剂和酮基有机溶剂的混合溶剂与含有MEL型沸石纳米晶体的沸石纳米晶体悬浮液,以产生沸石悬浮液。

    Mesoporous silica, process for the preparation of the same, and use thereof
    96.
    发明授权
    Mesoporous silica, process for the preparation of the same, and use thereof 失效
    介孔二氧化硅,其制备方法及其用途

    公开(公告)号:US07018596B2

    公开(公告)日:2006-03-28

    申请号:US09555073

    申请日:1998-11-19

    IPC分类号: C01B37/02 B41M5/00

    CPC分类号: B41M5/5218 C01B37/02

    摘要: Accordingly, the invention provides: (1) mesoporous silica characterized by having an average pore diameter in the mesopore region of from 1.5 to 10 nm, a nitrogen adsorption specific surface area determined by the BET method of from 500 to 1400 m2/g, and a monolayer adsorption of water at 25° C. of 1.7 H2O molecules/nm2 specific surface area or more; (2) a process for synthesizing the mesoporous silica characterized by mixing and reacting active silica with a neutral template and removing the neutral template from the thus formed complex; (3) ink absorbents characterized by containing mesoporous silica; (4) ink absorbent slurries composed of the above-described ink absorbent and a solvent; and (5) recording sheets characterized by containing the above-described ink absorbent.

    摘要翻译: 因此,本发明提供:(1)中孔二氧化硅,其特征在于,在中孔区域的平均孔径为1.5〜10nm,BET法测定的氮吸附比表面积为500〜1400m 2 25℃下的单层吸附为1.7 H 2 O 2 / O 2比表面积以上; (2)一种用于合成介孔二氧化硅的方法,其特征在于将活性二氧化硅与中性模板混合和反应,并从由此形成的络合物中除去中性模板; (3)以介孔二氧化硅为特征的油墨吸收剂; (4)由上述吸墨剂和溶剂构成的吸墨浆料; 和(5)记录片材,其特征在于含有上述吸墨剂。

    Nanochannel structure containing functional molecule and thin film thereof
    99.
    发明申请
    Nanochannel structure containing functional molecule and thin film thereof 审中-公开
    含有功能性分子的纳米通道结构及其薄膜

    公开(公告)号:US20050205844A1

    公开(公告)日:2005-09-22

    申请号:US10526394

    申请日:2003-09-05

    IPC分类号: B01J19/00 C01B37/02 C09K11/06

    摘要: A nanochannel structure with an oxide layer containing a surfactant micelle contains a functional molecule in a nanochannel. There is provided a new application as a functional material to a substance having a nanometer-sized pore by the technique on a hydrophobic site which is brought by the presence of the surfactant that is used during the production of the substance.

    摘要翻译: 具有含有表面活性剂胶束的氧化物层的纳米通道结构在纳米通道中含有功能性分子。 通过在制造物质时所用的表面活性剂的存在引起的疏水部位上的技术,提供了具有纳米尺寸孔的物质的功能材料的新用途。

    Microporous crystalline zeolite material (zeolite ITQ-22), synthesis method thereof and use of same as a catalyst
    100.
    发明申请
    Microporous crystalline zeolite material (zeolite ITQ-22), synthesis method thereof and use of same as a catalyst 有权
    微孔结晶沸石材料(沸石ITQ-22),其合成方法及其用作催化剂

    公开(公告)号:US20050182278A1

    公开(公告)日:2005-08-18

    申请号:US10996182

    申请日:2004-11-23

    摘要: The present invention refers to a microporous crystalline material of zeolitic nature (ITQ-22) which, in the calcined state, has the empirical formula wherein M is H+ or at least one inorganic cation of charge +n; X is at least one chemical element of oxidation state +3, preferably selected from the group consisting of Al, Ga, B, Fe and Cr; Y is at least one chemical element with oxidation state +4 other than Si and Ge, preferably selected from the group consisting of Ti, Sn and V; x has a value less than 0.2, preferably less than 0.1 and can take the value zero, y has a value less than 0.1, preferably less than 0.05 and can take the value zero, z has a value less than 0.8, preferably between 0.005 and 0.5 and can take the value zero, with a characteristic X-ray diffraction pattern, to the method of preparation and to the use of the material in separation and transformation processes of organic compounds.

    摘要翻译: 本发明涉及沸石性质的微孔结晶材料(ITQ-22),其在煅烧状态下具有经验式,其中M为H +或至少一种电荷无机阳离子+ n; X是氧化态+3的至少一种化学元素,优选选自Al,Ga,B,Fe和Cr; Y是至少一种氧化态除了Si和Ge以外的化合物,优选选自Ti,Sn和V; x的值小于0.2,优选小于0.1,并且可以取零值,y的值小于0.1,优选小于0.05,并且可以取零值,z的值小于0.8,优选为0.005和 0.5,并且可以使用特征X射线衍射图,将零值作为制备方法和在有机化合物的分离和转化过程中使用该材料。