公开(公告)号：US10947200B2

公开(公告)日：2021-03-16

申请号：US15739239

申请日：2016-06-21

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Manuel Alcarazo ,  Javier Peña Gonzalez ,  Garazi Talavera Urquijo

IPC: C07D233/42

Abstract: The present invention refers to substituted imidazolium sulfuranes, the use thereof for the transfer of a —CN group or an alkyne group.

公开(公告)号：US10947186B2

公开(公告)日：2021-03-16

申请号：US16613822

申请日：2018-05-08

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Tobias Ritter ,  Fei Ye

IPC: C07C253/12 ,  B01J31/24 ,  C07C255/31 ,  C07C255/34 ,  C07D213/64 ,  C07D333/24

Abstract: The present invention refers to a process for a Rh-catalyzed Anti-Markovnikov hydrocyanation of terminal alkynes which process discloses, for the first time, the highly stereo- and regio-selective hydrocyanation of terminal alkynes to furnish E-configured alkenyl nitriles and the catalyst used in the present process.

公开(公告)号：US20200369583A1

公开(公告)日：2020-11-26

申请号：US16635266

申请日：2018-07-10

Applicant: STUDIENGESELLSCHAFT KOHLE MBH ,  PRESIDENT AND FELLOWS OF HARVARD COLLEGE

Inventor： Tobias RITTER ,  Constanze NEUMANN ,  Mohammad Hassan BEYZAVI ,  Martin Georg STREBL-BANTILLO ,  Debashis MANDAL

IPC: C07C17/16 ,  C07C231/12 ,  C07B59/00 ,  C07D451/02

Abstract: The present invention refers to a process for transition-metal-assisted 18F-deoxyfluorination of phenols. The transformation benefits from readily available phenols as starting materials, tolerance of moisture and ambient atmosphere, large substrate scope, and translatability to generate doses appropriate for positron emission tomography (PET) imaging.

公开(公告)号：US20200181068A1

公开(公告)日：2020-06-11

申请号：US16613822

申请日：2018-05-08

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Tobias RITTER ,  Fei YE

IPC: C07C253/12 ,  B01J31/24

Abstract: The present invention refers to a process for a Rh-catalyzed Anti-Markovnikov hydrocyanation of terminal alkynes which process discloses, for the first time, the highly stereo- and regio-selective hydrocyanation of terminal alkynes to furnish E-configured alkenyl nitriles and the catalyst used in the present process.

公开(公告)号：US20190099748A1

公开(公告)日：2019-04-04

申请号：US16083160

申请日：2017-03-09

Applicant: President and Fellows of Harvard College ,  Studiengesellschaft Kohle mbH

Inventor： Tobias Ritter ,  Jeffrey Garber ,  Kumiko Yamamoto

IPC: B01J31/30 ,  B01J31/18 ,  C07C23/10 ,  C07C17/12

Abstract: Provided herein are palladium complexes comprising a ligand of Formula (A′) and a ligand of Formula (B), wherein R1-R18 are as defined herein. The palladium complexes are useful in methods of fluorinating aryl and heteroaryl substrates. Further provided are compositions and kits comprising the palladium complexes.

公开(公告)号：US20180339999A1

公开(公告)日：2018-11-29

申请号：US15756136

申请日：2016-08-31

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Benjamin LIST ,  Philip Stephan Joseph KAIB ,  Lucas SCHREYER ,  Sunggi LEE ,  Roberta PROPERZI ,  Luping LIU

IPC: C07F9/22 ,  C07F9/6584

Abstract: The present invention relates to chiral phosphoramidimidates, their salts and metal complexes as well as derivatives thereof and their use as catalysts.

公开(公告)号：US20180086983A1

公开(公告)日：2018-03-29

申请号：US15560595

申请日：2016-03-22

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Roberto RINALDI ,  Marco KENNEMA

IPC: C10G1/08 ,  C09K17/14

CPC classification number: C10G1/086 ,  C09K17/14 ,  C10G1/083 ,  C10G2300/44 ,  C10L1/02

Abstract: The present invention refers to a process for catalytic fractionation of peat, coir, peat-like materials or mosses into a non-pyrolytic bio-oil and a sterile solid fraction with similar volume and structural function to the starting material. The inventive process is useful for a variety of interesting applications, starting from raw peat with a water content of up to 80% resulting in a an oil, rich in polyols and aliphatic molecules.

公开(公告)号：US09783561B2

公开(公告)日：2017-10-10

申请号：US14371238

申请日：2013-01-08

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Benjamin List ,  Ilija Coric ,  Sreekumar Vellalath

IPC: C07F9/6574 ,  B01J31/02 ,  C07F9/6571 ,  C07D493/10 ,  C07D319/08 ,  C07D327/06 ,  C07D339/08 ,  C07D239/90 ,  C07C231/06 ,  C07D209/08 ,  C07D209/12 ,  C07D307/10 ,  C07D307/20

CPC classification number: C07F9/65746 ,  B01J31/0264 ,  B01J31/0271 ,  B01J2231/52 ,  B01J2231/70 ,  C07C231/06 ,  C07D209/08 ,  C07D209/12 ,  C07D239/90 ,  C07D307/10 ,  C07D307/20 ,  C07D319/08 ,  C07D327/06 ,  C07D339/08 ,  C07D493/10 ,  C07F9/657154 ,  C07F9/65744 ,  C07C233/05

Abstract: The invention relates to chiral imidodiphosphates and derivatives thereof having the general formula I, The compounds are suitable as chiral Brønsted acid catalysts, phase-transfer catalysts, chiral anions for organic salts, metal salts or metal complexes for catalysis.

公开(公告)号：US09758731B2

公开(公告)日：2017-09-12

申请号：US14651033

申请日：2013-12-10

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Roberto Rinaldi ,  Xingyu Wang

IPC: C07C1/20 ,  C10G3/00 ,  C10G45/02 ,  C10G45/28 ,  C10G45/30 ,  C10G49/20

CPC classification number: C10G3/52 ,  C10G3/45 ,  C10G3/47 ,  C10G3/50 ,  C10G45/02 ,  C10G45/28 ,  C10G45/30 ,  C10G49/20 ,  C10G2300/42 ,  C10G2400/30 ,  Y02P30/20

Abstract: The present invention discloses a process for the conversion of phenolics into aromatic hydrocarbons. In more detail, the present invention refers to a process for the selective hydrodeoxygenation of phenolic feeds into aromatic hydrocarbons, such as benzene, toluene, alkylbenzenes and others. The selective catalytic hydrodeoxygenation is performed in absence of external supply of molecular hydrogen.

公开(公告)号：US09755247B2

公开(公告)日：2017-09-05

申请号：US14375501

申请日：2013-02-08

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Ferdi Schüth ,  Diana Carolina Galeano Nunez ,  Hans-Josef Bongard ,  Karl Mayrhofer ,  Josef C. Meier ,  Claudio Baldizzone ,  Stefano Mezzavilla

IPC: H01M4/133 ,  H01M4/92 ,  B01J37/08 ,  B01J37/18 ,  B01J21/18 ,  B01J23/40 ,  B01J23/42 ,  B01J23/745 ,  B01J35/10 ,  B01J37/02 ,  B01J37/34 ,  B01J23/06 ,  B01J23/08 ,  B01J23/14 ,  B01J23/16 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/52 ,  B01J23/62 ,  B01J23/652 ,  B01J23/656 ,  B01J23/70 ,  B01J23/89 ,  B01J35/08 ,  C01B31/04 ,  H01M4/90 ,  H01M12/04 ,  H01M12/08 ,  H01M4/86 ,  H01M4/88 ,  B01J35/00 ,  B01J29/03 ,  H01M8/1018

CPC classification number: H01M4/926 ,  B01J21/18 ,  B01J23/06 ,  B01J23/08 ,  B01J23/14 ,  B01J23/16 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/52 ,  B01J23/626 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/70 ,  B01J23/745 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/8926 ,  B01J23/8966 ,  B01J29/0325 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/0046 ,  B01J35/006 ,  B01J35/008 ,  B01J35/0086 ,  B01J35/08 ,  B01J35/1028 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/0244 ,  B01J37/084 ,  B01J37/18 ,  B01J37/343 ,  C01B32/20 ,  C01P2004/32 ,  C01P2006/12 ,  H01M4/8605 ,  H01M4/8842 ,  H01M4/8882 ,  H01M4/9041 ,  H01M4/9083 ,  H01M8/1018 ,  H01M12/04 ,  H01M12/08 ,  H01M2008/1095 ,  H01M2300/0082

Abstract: The present invention refers to highly sinter-stable metal nanoparticles supported on mesoporous graphitic spheres, the so obtained metal-loaded mesoporous graphitic particles, processes for their preparation and the use thereof as catalysts, in particular for high temperature reactions in reducing atmosphere and cathode side oxygen reduction reaction (ORR) in PEM fuel cells.