公开(公告)号：US09709888B2

公开(公告)日：2017-07-18

申请号：US14375518

申请日：2013-03-22

申请人： TOYOBO CO., LTD.

发明人： Hiroto Yamada ,  Yukimi Yawata ,  Kazuya Yoshimoto

IPC分类号： G03F7/00 ,  G03F7/033 ,  G03F7/027 ,  B41N1/12 ,  G03F7/24

CPC分类号： G03F7/033 ,  B41N1/12 ,  G03F7/027 ,  G03F7/24

摘要： A photosensitive resin composition for CTP flexographic printing original plate containing at least a hydrophobic polymer obtained from water-dispersible latex (A), a hydrophilic polymer (B), a photopolymerizable unsaturated compound (C), a photopolymerization initiator (D), and if necessary, rubber (E), characterized in that, the photopolymerizable unsaturated compound (C) comprises a photopolymerizable oligomer containing no hydroxyl group (C-1), a hydroxyl group-containing photopolymerizable monomer having a pentaerythritol skeleton, a dipentaerythritol skeleton or a glycerol skeleton (C-2) and, optionally, a photopolymerizable monomer containing no hydroxyl group (C-3). The content of the hydroxyl group-containing photopolymerizable monomer (C-2) is 1 to 20% by mass of the photosensitive resin composition. The content of the rubber (E) is preferably 0.5 to 15% by mass of the photosensitive resin composition.

公开(公告)号：US09670311B2

公开(公告)日：2017-06-06

申请号：US14378166

申请日：2013-02-18

申请人： TOYOBO CO., LTD.

发明人： Hideki Tanaka ,  Naoko Oda

IPC分类号： A01N25/10 ,  C08G63/08 ,  C08J3/05 ,  C09D167/04 ,  C09J167/04 ,  B32B27/36 ,  C09D11/00 ,  C08G63/664 ,  C09D11/104 ,  B32B5/02 ,  B32B7/06 ,  B32B7/12 ,  B32B27/10 ,  B32B27/12 ,  C08L101/16

CPC分类号： C08G63/08 ,  A01N25/10 ,  B32B5/022 ,  B32B5/024 ,  B32B7/06 ,  B32B7/12 ,  B32B27/10 ,  B32B27/12 ,  B32B27/36 ,  B32B2307/7163 ,  B32B2307/748 ,  B32B2553/00 ,  C08G63/664 ,  C08J3/05 ,  C08J2367/04 ,  C08L101/16 ,  C09D11/00 ,  C09D11/104 ,  C09D167/04 ,  C09J167/04 ,  Y10T428/3179 ,  Y10T442/20

摘要： A polylactic polyester resin having a chemical structure represented by Formula (1), an acid value of 300 to 2,500 eq/106 g, a number average molecular weight of 2,000 to 50,000, and a lactic acid content percentage of not less than 40 weight %, Z—(O—(CH2CH2O)p—(CO—Y—O)q—X)r  (1) wherein Z is an r-valent organic group, Y is —CH(CH3)—, or a mixture of —CH(CH3)— and C2-10 linear or branched alkylene group, and X is a residue of a polybasic acid having 2 or more carboxyl groups, or hydrogen; each of X, Y, and Z may be one kind or a mixture of a plurality of different kinds; and p, q, and r are 0 or a positive integer, p has an average value of not less than 0.5, q has an average value of not less than 5, and r has an average value of not less than 3 and not more than 15. An aqueous dispersion, an aqueous resin composition, an aqueous adhesive, an aqueous paint, aqueous ink, a laminate made of an aqueous adhesive or aqueous ink, a packaging material, a sustained-release biodegradable coating agent, and a sustained-release biodegradable coated body comprising the sustained-release biodegradable coating agent, which contain the polyester resin.

公开(公告)号：US20170066922A1

公开(公告)日：2017-03-09

申请号：US15122434

申请日：2015-03-03

申请人： TOYOBO CO., LTD.

发明人： Nobuhiro YOSHIMURA

IPC分类号： C08L77/02

CPC分类号： C08L77/02 ,  C08K3/32 ,  C08K3/346 ,  C08K9/04 ,  C08L2205/025

摘要： The present invention provides a polyamide resin composition containing 1 to 10 part (s) by mass of swellable layered silicate and 0.01 to 0.3 part by mass of a phosphorus-containing compound having 3 or less phosphorus oxidation number to 100 parts by mass of polyamide resins, characterized in that, the polyamide resins comprise a polyamide resin A1 having relative viscosity of from 3.0 to 4.0 and a polyamide resin A2 having relative viscosity of from 1.5 to less than 3.0, that their mixing rate A1/A2 (in terms of ratio by mass) is from 98/2 to 5/95, and that tensile elongation at break of the polyamide resin composition is 3.0% or more. The polyamide resin composition has tenacity which has not been achieved in the conventional nano-composite and has excellent strength, rigidity and hot rigidity in spite of small content of inorganic filler and specific gravity.

摘要翻译： 本发明提供一种聚酰胺树脂组合物，其含有1〜10质量份可溶胀层状硅酸盐和0.01〜0.3质量份含磷氧化数为3以下的含磷化合物，相对于100质量份聚酰胺树脂 其特征在于，所述聚酰胺树脂包含相对粘度为3.0〜4.0的聚酰胺树脂A1和相对粘度为1.5〜小于3.0的聚酰胺树脂A2，其混合比A1 / A2（按比例 质量）为98/2〜5/95，聚酰胺树脂组合物的拉伸断裂伸长率为3.0％以上。 聚酰胺树脂组合物在传统的纳米复合材料中具有未达到的韧性，并且尽管无机填料的含量少，比重也具有优异的强度，刚性和热刚性。

公开(公告)号：US20170029575A1

公开(公告)日：2017-02-02

申请号：US15303393

申请日：2015-04-08

申请人： TOYOBO CO., LTD.

发明人： Kunihiro MAEDA ,  Hideto OHASHI ,  Satoru NAKAGAWA

IPC分类号： C08J3/22 ,  C08K3/08 ,  C08J5/18 ,  C08K5/521

CPC分类号： C08J3/22 ,  C08G63/16 ,  C08J5/18 ,  C08J2367/02 ,  C08K3/08 ,  C08K5/521 ,  C08K2003/0825 ,  C08L67/00

摘要： The present invention is a polyester composition for a masterbatch, which comprises a polyester, a magnesium compound, an alkali metal compound and a phosphorus compound, wherein magnesium atoms, alkali metal atoms and phosphorus atoms are contained in amounts of 400 to 2700 ppm by mass, 40 to 270 ppm by mass and 200 to 1700 ppm by mass, respectively, in the polyester composition, the melt resistivity of the polyester composition is 0.005×108 to 0.05×108 Ω·cm, and few contaminant particles are observed in the polyester composition under specified conditions. The polyester composition for a masterbatch has a satisfactorily low melt resistivity, contains few contaminant particles, and has an excellent color hue and excellent thermal stability.

摘要翻译： 本发明是一种母料用聚酯组合物，其包含聚酯，镁化合物，碱金属化合物和磷化合物，其中镁原子，碱金属原子和磷原子的含量为400〜2700质量ppm 在聚酯组合物中分别为40〜270质量ppm，200〜1700质量ppm，聚酯组合物的熔融电阻率为0.005×10 8〜0.05×10 8Ω·cm，在聚酯中观察到少量污染物 组成在规定的条件下。 母料的聚酯组合物具有令人满意的低熔体电阻率，含有很少的污染物颗粒，并且具有优异的色调和优异的热稳定性。

公开(公告)号：US09512301B2

公开(公告)日：2016-12-06

申请号：US14781366

申请日：2014-04-08

申请人： TOYOBO CO., LTD.

发明人： Tomohide Nakagawa ,  Tatsuya Oi ,  Kazunari Tanaka

IPC分类号： C08L77/00 ,  B32B27/30 ,  B60C1/00 ,  C08K7/14 ,  C08L77/02 ,  C08L77/06 ,  C08J5/04

CPC分类号： C08K7/14 ,  C08J5/043 ,  C08J2377/06 ,  C08J2377/10 ,  C08J2477/06 ,  C08J2477/10 ,  C08K3/04 ,  C08L77/02 ,  C08L77/06

摘要： The present invention provides a polyamide resin composition reinforced with glass fiber which can produce a molded product having high anti-vibration property or, in other words, having very high resonance frequency and having, upon necessity, excellent weather-resisting color fastness. A polyamide resin composition reinforced with glass fiber, comprising a polyamide resin (A) constituted from aliphatic polyamide (a1) and aromatic component-containing polyamide (a2), and glass fibers (B) having a cross-sectional area of 1.5 to 5.0×10−6 cm2, wherein ratio by weight of the polyamide resin (A) to the glass fibers (B) [(A):(B)] is from 20:80 to 35:65 and ratio by weight of the aliphatic polyamide (a1) to the aromatic component-containing polyamide (a2) [(a1):(a2)] is from 5:95 to 95:5. The polyamide resin composition reinforced with glass fibers of the present invention can further comprise carbon black (C) in an amount of at most 5% by weight.

摘要翻译： 本发明提供一种用玻璃纤维增​​强的聚酰胺树脂组合物，其可以制造具有高抗振性能的成型产品，或换句话说，具有非常高的共振频率，并且在必要时具有优异的耐候性色牢度。 由玻璃纤维增​​强的聚酰胺树脂组合物，包含由脂肪族聚酰胺（a1）和含芳香族成分的聚酰胺（a2）构成的聚酰胺树脂（A）和横截面积为1.5〜5.0×的玻璃纤维（B） 10-6cm 2，其中聚酰胺树脂（A）与玻璃纤维（B）[（A）：B）]的重量比为20:80至35:65，脂族聚酰胺（ a1）至含芳香族成分的聚酰胺（a2）[（a1）：（a2）]为5:95〜95:5。 用本发明的玻璃纤维增​​强的聚酰胺树脂组合物还可以含有至多5重量％的碳黑（C）。

公开(公告)号：US09506043B2

公开(公告)日：2016-11-29

申请号：US14367822

申请日：2012-12-19

申请人： TOYOBO CO., LTD.

发明人： Sachio Iwai ,  Takahide Kishimoto ,  Seiji Takeshima ,  Shusaku Yanagidani

IPC分类号： C12N9/02 ,  C12N1/20 ,  C12N1/00 ,  C12N15/00 ,  C12N5/02 ,  C07H21/04

CPC分类号： C12N9/0036 ,  C12Y106/99

摘要： A novel diaphorase; a method for producing the diaphorase; and use of the diaphorase are provided. The diaphorase comprises any one of the following polypeptides (a) to (c): (a) a polypeptide having the amino acid sequence of SEQ ID NO: 1, (b) a polypeptide having the amino acid sequence of SEQ ID NO: 1 in which one or several amino acid residues are substituted, deleted, inserted, added, and/or inverted, and having diaphorase activity, and (c) a polypeptide having an amino acid sequence with 80% or more identity to the amino acid sequence of SEQ ID NO: 1, and having diaphorase activity.

摘要翻译： 一种新颖的心电图 一种生产心肌黄酶的方法; 并提供使用心肌黄酶。 心肌黄酶包含以下多肽（a）至（c）中的任一种：（a）具有SEQ ID NO：1的氨基酸序列的多肽，（b）具有SEQ ID NO：1的氨基酸序列的多肽 其中一个或几个氨基酸残基被取代，缺失，插入，添加和/或倒转，并且具有心肌黄酶活性，和（c）具有与氨基酸序列具有80％或更高同一性的氨基酸序列的多肽 SEQ ID NO：1，并具有心肌黄酶活性。

公开(公告)号：US09447575B2

公开(公告)日：2016-09-20

申请号：US13880169

申请日：2011-11-01

申请人： Tomohide Nakagawa ,  Tadamine Ohashi ,  Yasuto Fujii ,  Akio Tange

发明人： Tomohide Nakagawa ,  Tadamine Ohashi ,  Yasuto Fujii ,  Akio Tange

IPC分类号： B29C44/00 ,  E04B1/78 ,  C08L77/00 ,  C08J9/06 ,  F02F7/00

CPC分类号： E04B1/78 ,  B29C44/02 ,  C08J9/06 ,  C08J2377/00 ,  C08K3/013 ,  C08L25/04 ,  C08L77/00 ,  C08L2205/02 ,  F02F7/0085 ,  Y10T428/249977 ,  C08K3/0033

摘要： Provided is a polyamide resin composition which can provide an expanded molding being superior in heat resistance and sufficiently reduced in weight and having high load resistance by a simple molding process. The polyamide resin composition is characterized by comprising a polyamide resin (A), a glycidyl-group-containing styrene copolymer (B) having two or more glycidyl groups per molecule, a weight average molecular weight of 4000 to 25000 and an epoxy value of 400 to 2500 Eq/1×106 g and an inorganic reinforcing material (C) in a proportion such that the content of the glycidyl-group-containing styrene copolymer (B) is 0.2 to 25 parts by mass and the content of the inorganic reinforcing material (C) is 0 to 350 parts by mass relative to 100 parts by mass of the polyamide resin (A).

摘要翻译： 提供一种聚酰胺树脂组合物，其能够提供耐热性优异且重量轻且通过简单的成型工艺具有高耐负载性的发泡成型体。 聚酰胺树脂组合物的特征在于，包含聚酰胺树脂（A），每分子具有两个以上缩水甘油基的含缩水甘油基的苯乙烯共聚物（B），重均分子量为4000〜25000，环氧值为400 至2500当量/ 1×106g的无机增强材料（C），使含缩水甘油基的苯乙烯共聚物（B）的含量为0.2〜25质量份，无机增强材料 （C）相对于100质量份聚酰胺树脂（A）为0〜350质量份。

公开(公告)号：US09296868B2

公开(公告)日：2016-03-29

申请号：US14418273

申请日：2013-09-25

申请人： TOYOBO CO., LTD.

发明人： Mahiro Nakano ,  Tadashi Nakaya ,  Toshiyuki Shimizu ,  Yoshitomo Ikehata

IPC分类号： C08J9/00 ,  C08J5/18 ,  B29C55/14 ,  C08J11/04 ,  B29K67/00 ,  B29K105/26

CPC分类号： C08J5/18 ,  B29C55/14 ,  B29K2067/003 ,  B29K2105/26 ,  C08J2367/02 ,  C08J2367/03

摘要： It is provided that a polyester film containing a polyester resin obtained by recycling PET bottles and having high lamination strength and slight unevenness in thickness. A biaxially stretched polyester film comprising 50 wt. % or more and 95 wt. % or less of a polyester resin obtained by recycling PET bottles, wherein the content of an isophthalic acid component in all dicarboxylic acid components in the entire polyester resin composing the polyester film is 0.5 mol % or more and 5.0 mol % or less, and the polyester satisfy the specific intrinsic viscosity, the specific thermal shrinkage rate, the specific refractive index in the thickness direction, and the specific unevenness in thickness.

摘要翻译： 提供了含有通过回收PET瓶而获得的具有高层压强度和轻微的厚度不均匀性的聚酯树脂的聚酯膜。 一种双轴拉伸的聚酯薄膜，包括50wt。 ％以上95重量％ 通过回收PET瓶而获得的聚酯树脂的％以下为0.5重量％以上且5.0摩尔％以下，其中，构成聚酯膜的整个聚酯树脂中的所有二羧酸成分中的间苯二甲酸成分的含量为 聚酯满足特定的特性粘度，比热收缩率，厚度方向的比折射率以及厚度的特定不均匀性。

公开(公告)号：US09200110B2

公开(公告)日：2015-12-01

申请号：US14391225

申请日：2013-04-05

申请人： TOYOBO CO., LTD.

发明人： Keiichiro Togawa ,  Hiroshi Shibano

IPC分类号： C08G63/02 ,  C08G63/183 ,  C08G63/85 ,  B29C49/00 ,  C08G64/00 ,  B29K67/00 ,  B29L31/00

CPC分类号： C08G63/183 ,  B29C49/0005 ,  B29K2067/003 ,  B29L2031/7158 ,  C08G63/85

摘要： The present invention is directed to a heat-resistant polyester blow-molded article made of a polyester resin composition containing 0.035 to 1.75 equivalent/ton of a hindered phenol structural unit and containing at least one selected from the group consisting of antimony compounds as a polymerization catalyst, the cyclic trimer content thereof being less than or equal to 0.5% by mass, the acetaldehyde content thereof being less than or equal to 50 ppm and the intrinsic viscosity thereof being 0.68 to 0.90 dL/g. The present invention enables efficient production of a molded article excellent in transparency and heat-resistant dimensional stability, in particular a heat-resistant blow-molded article. Moreover, according to the present invention, there are provided a polyester resin composition which is excellent in long-term continuous moldability and hardly stains a mold and a molded article prepared therewith, and a method for molding a polyester blow-molded article using the polyester resin composition.

摘要翻译： 本发明涉及由含有0.035〜1.75当量/位受阻酚结构单元并含有选自锑化合物作为聚合物的至少一种的聚酯树脂组合物制成的耐热聚酯吹塑制品 催化剂，其环状三聚物含量小于或等于0.5质量％，其乙醛含量小于或等于50ppm，其特性粘度为0.68至0.90dL / g。 本发明能够有效地制造透明性和耐热尺寸稳定性优异的成型体，特别是耐热吹塑制品。 此外，根据本发明，提供了一种长期连续成型性优异且难以染色的模具及其制备的成型体的聚酯树脂组合物，以及使用聚酯的聚酯吹塑成型体的成型方法 树脂组合物。

公开(公告)号：US20150314245A1

公开(公告)日：2015-11-05

申请号：US14647266

申请日：2013-12-11

申请人： TOYOBO CO., LTD.

发明人： Takahito Nakao ,  Takashi Ohkame ,  Ryouhei Yamane ,  Seiji Watanuki ,  Tooru Kitagawa

IPC分类号： B01D71/76 ,  B01D71/68 ,  B01D71/58 ,  B01D69/12

CPC分类号： B01D71/76 ,  B01D61/027 ,  B01D69/02 ,  B01D69/087 ,  B01D69/10 ,  B01D69/12 ,  B01D71/52 ,  B01D71/58 ,  B01D71/68 ,  B01D2323/46 ,  B01D2325/14 ,  B01D2325/20 ,  B01D2325/30

摘要： The present invention provides a composite separation membrane having a separation layer formed of sulfonated polyarylene ether (SPAE) copolymer on a surface of a porous support membrane wherein both high separation property and high water permeation property are achieved. A composite separation membrane wherein a surface of a porous support membrane containing polyphenylene ether is coated with a thin film of a sulfonated polyarylene ether copolymer constituted from a repeating structure of a hydrophobic segment and a hydrophilic segment, characterized in that when proton nuclear magnetic resonance spectrum is measured at −10° C., chemical shift of a spectral peak top derived from water contained in the membrane satisfies from 4.15 ppm to less than 5.00 ppm.

摘要翻译： 本发明提供一种复合分离膜，其在多孔支撑膜的表面上具有由磺化聚亚芳基醚（SPAE）共聚物形成的分离层，其中实现了高分离性和高水渗透性。 一种复合分离膜，其中含有聚苯醚的多孔载体膜的表面涂覆有由疏水链段和亲水链段的重复结构构成的磺化聚亚芳基醚共聚物的薄膜，其特征在于当质子核磁共振谱 在-10℃下测量，衍生自膜中所含水的光谱峰顶的化学位移满足4.15ppm至小于5.00ppm。