Aluminum nitride powder and thermally conductive grease composition
using the same
    162.
    发明授权
    Aluminum nitride powder and thermally conductive grease composition using the same 有权
    氮化铝粉末和使用其的导热油脂组合物

    公开(公告)号:US6136758A

    公开(公告)日:2000-10-24

    申请号:US209455

    申请日:1998-12-11

    Abstract: An aluminum nitride powder having the surface treated with an organosilane represented by formula, R.sup.I.sub.a R.sup.II.sub.b SiY.sub.4-1-b, and/or a partial hydrolysis condensate thereof to acquire excellent moisture-proof, wherein R.sup.I represents a 6-20C alkyl group or a group formed by substituting halogen atom or atoms for part or all of the hydrogen atoms attached to carbon atoms of the 6-20C alkyl group, R.sup.II represents a 1-20C hydrocarbon group or a group formed by substituting halogen atom or atoms for part or all of the hydrogen atoms attached to carbon atoms of the 1-20C hydrocarbon group, Y represents a hydrolyzable group, a is an integer of 1 to 3 and b is an integer of 0 to 2, provided that a+b is an integer of 1 to 3; and a thermally conductive grease composition comprising (A) 50-95 weight % of the aforementioned surface-treated aluminum nitride powder and (B) 5 to 50 weight % of at least one base oil selected from the group consisting of liquid silicones, liquid hydrocarbons and fluorohydrocarbon oils, and further, if desired, (C) 0-30 weight % of a thicknener selected from the group consisting of zinc oxide, alumina, boron nitride and silicon carbide powders.

    Abstract translation: 具有用式表示的有机硅烷表面处理的氮化铝粉末,RIaRIIbSiY4-1-b和/或其部分水解缩合物,以获得优异的防湿性,其中RI表示6-20C烷基或由 用卤原子或原子取代与6-20C烷基的碳原子连接的部分或全部氢原子,RII表示1-20C的烃基或通过用卤原子或原子取代部分或全部氢 附着于1-20C烃基的碳原子的原子,Y表示可水解基团,a表示1〜3的整数,b表示0〜2的整数,条件是a + b为1〜3的整数。 和导热性润滑脂组合物,其包含(A)50-95重量%的上述表面处理的氮化铝粉末和(B)5至50重量%的至少一种基础油,其选自液体硅酮,液体烃 和氟代烃油,并且如果需要,(C)0-30重量%的选自氧化锌,氧化铝,氮化硼和碳化硅粉末的增稠剂。

    Thermoset polymer/solid lubricant coating system
    165.
    发明授权
    Thermoset polymer/solid lubricant coating system 失效
    热固性聚合物/固体润滑剂涂料体系

    公开(公告)号:US5363821A

    公开(公告)日:1994-11-15

    申请号:US88686

    申请日:1993-07-06

    Abstract: A solid film lubricant system for protecting metal wear interfaces subject to high temperatures and wet lubrications, comprising an oil-attracting solid lubricant mixture with at least two elements selected from the group of graphite, MoS.sub.2 and BN; a support (i.e., hard lands or hard sublayer) for the mixture to loads of at least 10 psi at temperatures of 600.degree.-800.degree. F. while being thermally stable; a thermally stable thermoset polymer matrix adhering the mixture to the support or the wear surface, the polymer having inherent hydrocarbon chemical attraction to form a tenacious oil film of the lubricating oil on the wearing surface. A method of making anti-friction coated surfaces comprising providing a light metal based cylinder surface (i.e., metal base or alloys of aluminum, titanium, or magnesium); exposing nonoxidized metal of the surface; applying a high elastic modulus load-supporting metal layer onto at least portions of the light metal cylinder surface; and simultaneously distributing a solvent-based solid film lubricant mixture and thermoset polymer onto at least portions of the layer at about room temperature to form a coating of desired thickness. An engine block with one or more anti-friction coated cylinder bore surfaces, comprising a hard, load-supporting face on the bore surface; and a coating on the face comprised of an oil-attracting solid lubricant mixture and a thermoset polymer that supports loads of at least 10 psi at temperatures of 600.degree.-800.degree. F. and is stable at such temperatures.

    Abstract translation: 一种用于保护经受高温和湿润润滑的金属磨损界面的固体膜润滑剂系统,包括具有选自石墨MoS 2和BN中的至少两种元素的吸油固体润滑剂混合物; 用于混合物的载体(即硬土或硬亚层)在600-800°F的温度下的载荷至少为10psi,同时热稳定; 将该混合物粘附到载体或耐磨表面上的热稳定的热固性聚合物基体,该聚合物具有固有的碳氢化合物化学吸引力,以在磨损表面上形成润滑油的坚固的油膜。 一种制造抗摩擦涂层表面的方法,包括提供基于轻金属的圆柱体表面(即,金属基体或铝,钛或镁的合金); 暴露表面的非氧化金属; 在轻金属圆筒表面的至少一部分上施加高弹性模量负载金属层; 并且在大约室温下同时将溶剂基固体膜润滑剂混合物和热固性聚合物分布到该层的至少部分上以形成所需厚度的涂层。 具有一个或多个抗摩擦涂覆的气缸孔表面的发动机缸体,包括孔表面上的硬的负载支撑面; 以及由吸油固体润滑剂混合物和热固性聚合物组成的涂层,其在600-800°F的温度下支持至少10psi的载荷,并且在这样的温度下是稳定的。

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