公开(公告)号：US5032461A

公开(公告)日：1991-07-16

申请号：US597112

申请日：1990-10-12

Applicant: David G. Shaw ,  Angelo Yializis ,  Donald S. Strycker ,  Mooyoung Ham

Inventor： David G. Shaw ,  Angelo Yializis ,  Donald S. Strycker ,  Mooyoung Ham

IPC: B05D3/06 ,  B05D3/14 ,  B05D7/00 ,  B05D7/24 ,  H01G4/14 ,  H01G4/30 ,  H01G13/00

CPC classification number: B05D7/56 ,  B05D1/60 ,  B05D3/068 ,  B05D7/24 ,  H01G13/00 ,  H01G4/145 ,  H01G4/306 ,  B05D3/148 ,  Y10T428/31692 ,  Y10T428/31909

Abstract: A high speed process for forming a multi layered thin film structure in a vacuum wherein each film is less than about four microns thick and the total layers can reach upwards to 4,000 or more. The polymeric layers are formed of a cross linked component selected from the group consisting of polyfunctional acrylates and mixtures of polyfunctional acrylates and monocrylates with the component having a preferable molecular weight of between 200 and 300 and a vapor pressure preferably in excess of 1.times.10.sup.-2 Torr. The polymeric layers may be interleaved with metal layers.

Abstract translation: 用于在真空中形成多层薄膜结构的高速工艺，其中每个薄膜的厚度小于约4微米，总层可达到4000以上。 聚合物层由选自多官能丙烯酸酯和多官能丙烯酸酯和单烯酸酯的混合物的交联组分形成，组分优选分子量为200-300，蒸气压优选超过1×10 -2乇 。 聚合物层可以与金属层交错。

公开(公告)号：US20120270020A1

公开(公告)日：2012-10-25

申请号：US13091635

申请日：2011-04-21

Applicant: ANGELO YIALIZIS ,  Gordon Goodyear

Inventor： ANGELO YIALIZIS ,  Gordon Goodyear

IPC: B32B7/02 ,  B05D3/02 ,  B05D3/06 ,  B29D11/00 ,  B05D5/06

CPC classification number: B29D11/0074 ,  Y10T428/24942

Abstract: A polymer-based optically-variable device for security applications has a high degree of color uniformity over the device area. The uniformity of thickness of the structure used in such devices is optimized by controlling previously neglected process parameters such as the temperature distribution of the deposition nozzle, the substrate and the deposition drum, their emissivities, the micro-roughness of the substrate, and the rate of monomer re-evaporation. Re-evaporation is minimized by initiating radiation-curing within two seconds of monomer deposition. The equipment is carefully monitored to eliminate all sources of emissivity non-homogeneities, such as surface blemishes in the surface areas exposed to the substrate. Substrates with haziness less than 5% and gloss greater than 90% are preferred. As a result, a maximum thickness variation of less than 5% over the transmissive layer of the optically variable device is found to ensure that no appreciable color-shift variation is visible to the naked eye.

Abstract translation: 用于安全应用的基于聚合物的光学可变装置在装置区域上具有高度的颜色均匀性。 通过控制先前忽略的工艺参数（例如沉积喷嘴，衬底和沉积鼓的温度分布，它们的发射率，衬底的微粗糙度以及速率）来优化在这些器件中使用的结构的厚度的均匀性 的单体再蒸发。 通过在单体沉积的两秒钟内启动辐射固化，使再蒸发最小化。 仔细监测设备以消除所有发射率不均匀性的来源，例如暴露于基底的表面区域中的表面瑕疵。 雾度小于5％，光泽大于90％的基材是优选的。 结果发现，在光学可变装置的透射层上的最大厚度变化小于5％，以确保没有肉眼可见的明显的色移变化。

公开(公告)号：US20070093076A1

公开(公告)日：2007-04-26

申请号：US11633995

申请日：2006-12-05

Applicant: Michael Mikhael ,  Richard Ellwanger ,  Angelo Yializis

Inventor： Michael Mikhael ,  Richard Ellwanger ,  Angelo Yializis

IPC: H01L21/47

CPC classification number: B05D1/62 ,  B05D1/60 ,  B05D3/0254 ,  B05D3/0263 ,  B05D3/06 ,  B05D3/067 ,  B05D3/068 ,  B05D3/142 ,  B05D3/147 ,  B05D5/083 ,  B05D7/04 ,  B05D2252/02 ,  C23C16/30 ,  C23C16/509 ,  D06M10/025 ,  D06M10/08 ,  D06M10/10 ,  D06M14/18 ,  D21H21/16 ,  D21H23/50 ,  H01J37/32009 ,  H01J37/32018 ,  H01J37/3244 ,  H01J37/32449 ,  H01J37/32532 ,  H01J37/32724 ,  H01J37/32825 ,  H01L21/312 ,  H05H1/2406 ,  H05H2001/2412

Abstract: A plasma is produced in a treatment space (58) by diffusing a plasma gas at atmospheric pressure and subjecting it to an electric field created by two metallic electrodes (54,56) separated by a dielectric material (64), and a precursor material is introduced into the treatment space to coat a substrate film or web (14) by vapor deposition or atomized spraying at atmospheric pressure. The deposited precursor exposed to an electromagnetic field (AC, DC, or plasma) and then it is cured by electron-beam, infrared-light, visible-light, or ultraviolet-light radiation, as most appropriate for the particular material being deposited. Additional plasma post-treatment may be used to enhance the properties of the resulting coated products.

Abstract translation: 在处理空间（58）中产生等离子体，通过在大气压下扩散等离子体气体并使其受到由电介质材料（64）分开的两个金属电极（54,56）产生的电场，前体材料是 通过在大气压下气相沉积或雾化喷雾而引入处理空间以涂覆基底膜或网（14）。 暴露于电磁场（AC，DC或等离子体）中的沉积的前驱物，然后通过电子束，红外光，可见光或紫外光辐射固化，最适合于沉积的特定材料。 可以使用额外的等离子体后处理来增强所得涂覆产品的性能。

公开(公告)号：US07157117B2

公开(公告)日：2007-01-02

申请号：US10830608

申请日：2004-04-23

Applicant: Michael G. Mikhael ,  Angelo Yializis

Inventor： Michael G. Mikhael ,  Angelo Yializis

IPC: C23C16/00

CPC classification number: B01D71/022 ,  B01D39/1623 ,  B01D39/18 ,  B01D39/2017 ,  B01D39/2065 ,  B01D67/0072 ,  B01D67/0088 ,  B01D67/009 ,  B01D71/02 ,  B01D2239/0241 ,  B01D2239/0414 ,  B01D2239/0421 ,  B01D2239/0428 ,  B01D2239/045 ,  B01D2239/0457 ,  B01D2239/0478 ,  B01D2239/0492 ,  B01D2239/065 ,  B01D2239/10 ,  B01D2239/1291 ,  B01D2325/04 ,  B01D2325/26 ,  B01D2325/30 ,  B01D2325/36 ,  B01D2325/38 ,  B05D1/60 ,  B05D3/142 ,  B05D3/144 ,  C23C8/02 ,  C23C8/20 ,  C23C8/80 ,  C23C28/00 ,  C23C30/00 ,  D04H1/42 ,  D06M10/025 ,  D06M10/08 ,  D06M14/18 ,  Y10T428/249953 ,  Y10T428/249956 ,  Y10T428/249987 ,  Y10T428/24999

Abstract: A porous substrate is pretreated in a plasma field and a functionalizing monomer is immediately flash-evaporated, deposited and cured over the porous substrate in a vacuum vapor-deposition chamber. By judiciously controlling the process so that the resulting polymer coating adheres to the surface of individual fibers in ultra-thin layers (approximately 0.02–3.0 μm) that do not extend across the pores in the material, the porosity of the porous substrate is essentially unaffected while the fibers and the final product acquire the desired functionality. The resulting polymer layer is also used to improve the adherence and durability of metallic and ceramic coatings.

公开(公告)号：US20060257642A9

公开(公告)日：2006-11-16

申请号：US10830608

申请日：2004-04-23

Applicant: Michael Mikhael ,  Angelo Yializis

Inventor： Michael Mikhael ,  Angelo Yializis

IPC: B05D1/08 ,  B32B3/26 ,  B32B9/00

CPC classification number: B01D71/022 ,  B01D39/1623 ,  B01D39/18 ,  B01D39/2017 ,  B01D39/2065 ,  B01D67/0072 ,  B01D67/0088 ,  B01D67/009 ,  B01D71/02 ,  B01D2239/0241 ,  B01D2239/0414 ,  B01D2239/0421 ,  B01D2239/0428 ,  B01D2239/045 ,  B01D2239/0457 ,  B01D2239/0478 ,  B01D2239/0492 ,  B01D2239/065 ,  B01D2239/10 ,  B01D2239/1291 ,  B01D2325/04 ,  B01D2325/26 ,  B01D2325/30 ,  B01D2325/36 ,  B01D2325/38 ,  B05D1/60 ,  B05D3/142 ,  B05D3/144 ,  C23C8/02 ,  C23C8/20 ,  C23C8/80 ,  C23C28/00 ,  C23C30/00 ,  D04H1/42 ,  D06M10/025 ,  D06M10/08 ,  D06M14/18 ,  Y10T428/249953 ,  Y10T428/249956 ,  Y10T428/249987 ,  Y10T428/24999

Abstract: A porous substrate is pretreated in a plasma field and a functionalizing monomer is immediately flash-evaporated, deposited and cured over the porous substrate in a vacuum vapor-deposition chamber. By judiciously controlling the process so that the resulting polymer coating adheres to the surface of individual fibers in ultra-thin layers (approximately 0.02-3.0 μm) that do not extend across the pores in the material, the porosity of the porous substrate is essentially unaffected while the fibers and the final product acquire the desired functionality. The resulting polymer layer is also used to improve the adherence and durability of metallic and ceramic coatings.

Abstract translation: 多孔基材在等离子体场中进行预处理，并且在真空气相沉积室中立即将功能化单体快速蒸发，沉积并固化在多孔基材上。 通过明智地控制该方法，使得所得到的聚合物涂层附着在不延伸穿过材料孔隙的超薄层（大约0.02-3.0μm）中的单个纤维的表面上，多孔基材的孔隙率基本上不受影响 而纤维和最终产品获得所需的功能。 所得聚合物层也用于改善金属和陶瓷涂层的粘附性和耐久性。

公开(公告)号：US20060240648A1

公开(公告)日：2006-10-26

申请号：US11448966

申请日：2006-06-07

Applicant: Michael Mikhael ,  Angelo Yializis ,  Richard Ellwanger

Inventor： Michael Mikhael ,  Angelo Yializis ,  Richard Ellwanger

IPC: H01L21/20

CPC classification number: H01L21/02118 ,  B05D1/60 ,  B05D1/62 ,  B05D3/0254 ,  B05D3/0263 ,  B05D3/06 ,  B05D3/067 ,  B05D3/068 ,  B05D3/142 ,  B05D3/147 ,  B05D5/083 ,  B05D7/04 ,  B05D2252/02 ,  C23C16/30 ,  C23C16/509 ,  D06M10/025 ,  D06M10/08 ,  D06M10/10 ,  D06M14/18 ,  D21H21/16 ,  D21H23/50 ,  H01J37/32009 ,  H01J37/32018 ,  H01J37/3244 ,  H01J37/32449 ,  H01J37/32532 ,  H01J37/32724 ,  H01J37/32825 ,  H01L21/02274 ,  H01L21/0234 ,  H01L21/02345 ,  H01L21/02348 ,  H01L21/02351 ,  H01L21/312 ,  H05H1/2406 ,  H05H2001/2412

Abstract: A plasma is produced in a treatment space (58) by diffusing a plasma gas at atmospheric pressure and subjecting it to an electric field created by two metallic electrodes (54,56) separated by a dielectric material (64), a precursor material is introduced into the treatment space to coat a substrate film or web (14) by vapor deposition or atomized spraying at atmospheric pressure. The deposited precursor is cured by electron-beam, infrared-light, visible-light, or ultraviolet-light radiation, as most appropriate for the particular material being deposited. Additional plasma post-treatment may be used to enhance the properties of the resulting coated products.

Abstract translation: 在处理空间（58）中产生等离子体，通过在大气压下扩散等离子体气体并使其受到由介电材料（64）分开的两个金属电极（54,56）产生的电场，引入前体材料 进入处理空间以通过气相沉积或在大气压下的雾化喷涂来涂覆基底膜或网（14）。 沉积的前体通过电子束，红外光，可见光或紫外光辐射固化，最适合于沉积的特定材料。 可以使用额外的等离子体后处理来增强所得涂覆产品的性能。

公开(公告)号：US07005161B2

公开(公告)日：2006-02-28

申请号：US10475923

申请日：2001-06-22

Applicant: Michael G. Mikhael ,  Angelo Yializis

Inventor： Michael G. Mikhael ,  Angelo Yializis

IPC: C23C14/24

CPC classification number: C23C14/24 ,  C23C14/0005 ,  C23C14/12

Abstract: A monomer is selected to produce a polymeric film having desirable characteristics for a particular application. The monomer is ppolymerized under controlled conditions to produce a solid oligomer having those characteristics at a molecular weight suitable for evaporation under vacuum at a temperature lower than its thermal decomposition temperature. The process of polymerization to produce the oligomer is carried out under conditions that yield a finite molecular-chain length with no residual reactive groups. The solid oligomer so produced is extruded as a film onto a revolving drum (38) in the evaporation section (40) of a vapor deposition chamber, and then cryocondensed on a cold substrate (44) to form a solid film having the same characteristic selected in the solid oligomer constituting the starting material. As a result of the initial complete reaction to produce the oligomer, the thin-film product does not contain unreacted groups and all attendant disadvantages are avoided.

Abstract translation: 选择单体以产生对于特定应用具有期望特性的聚合物膜。 在受控条件下共聚单体以产生具有适于在真空下在低于其热分解温度的温度下蒸发的分子量的那些特性的固体低聚物。 制备低聚物的聚合方法在产生无残余反应性基团的有限分子链长度的条件下进行。 将如此制造的固体低聚物作为膜挤出到蒸镀室的蒸发部（40）中的转鼓（38）上，然后在冷的基板（44）上冷冻冷冻以形成具有相同特性的固体膜 在构成原料的固体低聚物中。 作为产生低聚物的初始完全反应的结果，薄膜产物不含未反应的基团，并且避免了所有伴随的缺点。

公开(公告)号：US06838183B2

公开(公告)日：2005-01-04

申请号：US09792197

申请日：2001-02-21

Applicant: Angelo Yializis

Inventor： Angelo Yializis

IPC: C08J7/18 ,  B05D3/14 ,  B05D7/24 ,  B32B9/00 ,  B32B15/08 ,  B32B15/082 ,  B32B27/00 ,  C08F2/46 ,  C08J7/04 ,  C23C14/20 ,  H01G4/20

CPC classification number: B05D1/60 ,  B05D3/144 ,  B05D3/147 ,  B32B27/00 ,  C23C14/20 ,  H01G4/20 ,  Y10T428/12569 ,  Y10T428/12576 ,  Y10T428/1462 ,  Y10T428/31515 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699 ,  Y10T428/31855 ,  Y10T428/31935

Abstract: A hybrid film, comprising a first polymer film having a plasma-treated surface and a second polymer film having first and second surfaces, with the first surface of the second polymer film being disposed along the first plasma-treated surface of the first polymer film, has superior thermal and mechanical properties that improve performance in a number of applications, including food packaging, thin film metallized and foil capacitors, metal evaporated magnetic tapes, flexible electrical cables, and decorative and optically variable films. One or more metal layers may be deposited on either the plasma-treated surface of the substrate and/or the radiation-cured acrylate polymer. A ceramic layer may be deposited on the radiation-cured acrylate polymer to provide an oxygen and moisture barrier film. The hybrid film is produced using a high speed, vacuum polymer deposition process that is capable of forming thin, uniform, high temperature, cross-linked acrylate polymers on specific thermoplastic or thermoset films. Radiation curing is employed to cross-link the acrylate monomer. The hybrid film can be produced in-line with the metallization or ceramic coating process, in the same vacuum chamber and with minimal additional cost.

Abstract translation: 一种混合膜，包括具有等离子体处理表面的第一聚合物膜和具有第一和第二表面的第二聚合物膜，第二聚合物膜的第一表面沿着第一聚合物膜的第一等离子体处理表面设置， 具有优异的热和机械性能，可在许多应用中提高性能，包括食品包装，薄膜金属化和箔电容器，金属蒸发磁带，柔性电缆以及装饰和光学可变膜。 一个或多个金属层可以沉积在基板的等离子体处理的表面和/或辐射固化的丙烯酸酯聚合物上。 可以将陶瓷层沉积在辐射固化的丙烯酸酯聚合物上以提供氧气和湿气阻挡膜。 使用能够在特定热塑性或热固性膜上形成薄的，均匀的，高温的交联的丙烯酸酯聚合物的高速真空聚合物沉积工艺来制备混合膜。 辐射固化用于交联丙烯酸酯单体。 可以在相同的真空室中以与金属化或陶瓷涂覆方法一致的方式生产混合膜并以最小的附加成本。

公开(公告)号：US06270841B1

公开(公告)日：2001-08-07

申请号：US09346877

申请日：1999-07-02

Applicant: Michael G. Mikhael ,  Angelo Yializis

Inventor： Michael G. Mikhael ,  Angelo Yializis

IPC: C23C1424

CPC classification number: C23C14/24 ,  C23C14/0005 ,  C23C14/12

Abstract: A monomer is selected to produce a polymeric film having desirable characteristics for a particular application. The monomer is polymerized under controlled conditions to produce a solid oligomer having those characteristics at a molecular weight suitable for evaporation under vacuum at a temperature lower than its thermal decomposition temperature. The process of polymerization to produce the oligomer is carried out under conditions that yield a finite molecular-chain length with no residual reactive groups. The solid oligomer so produced is liquefied and extruded as a film onto a revolving drum in the evaporation section of a conventional vapor deposition chamber, and it is then cryocondensed on a cold substrate to form a solid thin film having the same desirable characteristic selected in the solid oligomer constituting the starting material. As a result of the initial complete reaction to produce the oligomer, the thin-film product does not contain unreacted groups and all attendant disadvantages are avoided.

Abstract translation: 选择单体以产生对于特定应用具有期望特性的聚合物膜。 单体在受控条件下聚合以产生具有适于在真空下在低于其热分解温度的温度下蒸发的分子量的那些特性的固体低聚物。 制备低聚物的聚合方法在产生无残余反应性基团的有限分子链长度的条件下进行。 将如此制造的固体低聚物液化并以薄膜的形式挤压到常规蒸镀室的蒸发部分的转鼓上，然后在冷的基材上冷冻冷冻以形成具有在 构成原料的固体低聚物。 作为产生低聚物的初始完全反应的结果，薄膜产物不含未反应的基团，并且避免了所有伴随的缺点。

公开(公告)号：US6083628A

公开(公告)日：2000-07-04

申请号：US628570

申请日：1996-04-04

Applicant: Angelo Yializis

Inventor： Angelo Yializis

IPC: C08J7/18 ,  B05D3/14 ,  B05D7/24 ,  B32B9/00 ,  B32B15/08 ,  B32B15/082 ,  B32B27/00 ,  C08F2/46 ,  C08J7/04 ,  C23C14/20 ,  H01G4/20

CPC classification number: B05D1/60 ,  B32B27/00 ,  C23C14/20 ,  H01G4/20 ,  B05D3/144 ,  B05D3/147 ,  Y10T428/12569 ,  Y10T428/12576 ,  Y10T428/1462 ,  Y10T428/31515 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699 ,  Y10T428/31855 ,  Y10T428/31935

Abstract: A hybrid film, comprising a first polymer film having a plasma-treated surface and a second polymer film having first and second surfaces, with the first surface of the second polymer film being disposed along the first plasma-treated surface of the first polymer film, has superior thermal and mechanical properties that improve performance in a number of applications, including food packaging, thin film metallized and foil capacitors, metal evaporated magnetic tapes, flexible electrical cables, and decorative and optically variable films. One or more metal layers may be deposited on either the plasma-treated surface of the substrate and/or the radiation-cured acrylate polymer. A ceramic layer may be deposited on the radiation-cured acrylate polymer to provide an oxygen and moisture barrier film. The hybrid film is produced using a high speed, vacuum polymer deposition process that is capable of forming thin, uniform, high temperature, cross-linked acrylate polymers on specific thermoplastic or thermoset films. Radiation curing is employed to cross-link the acrylate monomer. The hybrid film can be produced in-line with the metallization or ceramic coating process, in the same vacuum chamber and with minimal additional cost.

Abstract translation: 一种混合膜，包括具有等离子体处理表面的第一聚合物膜和具有第一和第二表面的第二聚合物膜，第二聚合物膜的第一表面沿着第一聚合物膜的第一等离子体处理表面设置， 具有优异的热和机械性能，可在许多应用中提高性能，包括食品包装，薄膜金属化和箔电容器，金属蒸发磁带，柔性电缆以及装饰和光学可变膜。 一个或多个金属层可以沉积在基板的等离子体处理的表面和/或辐射固化的丙烯酸酯聚合物上。 可以将陶瓷层沉积在辐射固化的丙烯酸酯聚合物上以提供氧气和湿气阻挡膜。 使用能够在特定热塑性或热固性膜上形成薄的，均匀的，高温的交联的丙烯酸酯聚合物的高速真空聚合物沉积工艺来制备混合膜。 辐射固化用于交联丙烯酸酯单体。 可以在相同的真空室中以与金属化或陶瓷涂覆方法一致的方式生产混合膜并以最小的额外成本。