Surface treatment method of copper foil with silane coupling agent
    12.
    发明授权
    Surface treatment method of copper foil with silane coupling agent 失效
    铜箔与硅烷偶联剂的表面处理方法

    公开(公告)号:US06878261B2

    公开(公告)日:2005-04-12

    申请号:US10278644

    申请日:2002-10-23

    Abstract: A surface treatment method for increasing adhesion of a surface of copper foil to an insulating epoxy-impregnated substrate used in printed circuit boards is provided. The method includes nodularizing a surface of an electrolytic copper foil, surface-treating the surface of the nodularized electrolytic copper foil by Zn—As alloy electrodeposition to form a Zn—As composite layer thereon, and coating the surface of the surface-treated electrolytic copper foil with a silane coupling agent mixture, whose compounding ratio of 3-aminopropyltriethoxysilane with respect to vinyltriethoxysilane is between 6:4 and 9:1. This method is very effective to prevent discoloration of copper foil caused by oxidation and the like.

    Abstract translation: 提供了一种用于增加铜箔表面对印刷电路板中使用的绝缘环氧树脂浸渍基材的粘附性的表面处理方法。 该方法包括使电解铜箔的表面结节化,通过Zn-As合金电沉积对结节状电解铜箔的表面进行表面处理,在其上形成Zn-As复合层,并将表面处理的电解铜 用硅烷偶联剂混合物,其3-氨基丙基三乙氧基硅烷相对于乙烯基三乙氧基硅烷的配混比为6:4至9:1。 该方法对于防止由氧化等引起的铜箔的变色是非常有效的。

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