公开(公告)号：US07482389B2

公开(公告)日：2009-01-27

申请号：US11111055

申请日：2005-04-20

申请人： Jennifer Nam Cha ,  Geraud Jean-Michel Dubois ,  James Lupton Hedrick ,  Ho-Cheol Kim ,  Victor Yee-Way Lee ,  Teddie Peregrino Magbitang ,  Robert Dennis Miller ,  Willi Volksen

发明人： Jennifer Nam Cha ,  Geraud Jean-Michel Dubois ,  James Lupton Hedrick ,  Ho-Cheol Kim ,  Victor Yee-Way Lee ,  Teddie Peregrino Magbitang ,  Robert Dennis Miller ,  Willi Volksen

IPC分类号： B32B3/26

CPC分类号： H01L21/3121 ,  G03F7/0002 ,  H01L21/02118 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02216 ,  H01L21/02282 ,  H01L21/312 ,  H01L21/31695 ,  Y10T428/249953 ,  Y10T428/31663

摘要： A nanoporous material exhibiting a lamellar structure is disclosed. The material comprises three or more substantially parallel sheets of an organosilicate material, separated by highly porous spacer regions. The distance between the centers of the sheets lies between 1 nm and 50 nm. The highly porous spacer regions may be substantially free of condensed material. For the manufacture of such materials, a process is disclosed in which matrix non-amphiphilic polymeric material and templating polymeric material are dispersed in a solvent, where the templating polymeric material includes a polymeric amphiphilic material. The solvent with the polymeric materials is distributed onto a substrate. Organization is induced in the templating polymeric material. The solvent is removed, leaving the polymeric materials in place. The matrix polymeric material is cured, forming a lamellar structure.

摘要翻译： 公开了具有层状结构的纳米多孔材料。 该材料包括由高度多孔的间隔区隔开的三个或更多个基本平行的有机硅酸盐材料片。 片材中心之间的距离介于1nm和50nm之间。 高度多孔的间隔区域可以基本上不含冷凝材料。 为了制造这种材料，公开了一种方法，其中将基质非两亲性聚合物材料和模板聚合物材料分散在溶剂中，其中模板聚合材料包括聚合物两亲性材料。 具有聚合物材料的溶剂分布在基材上。 组织在模板聚合材料中被诱导。 除去溶剂，留下聚合物材料就位。 基体聚合材料固化，形成层状结构。

公开(公告)号：US07459572B2

公开(公告)日：2008-12-02

申请号：US11660491

申请日：2004-08-19

申请人： Seong-Jin Kim ,  Ho-Seong Lee ,  Jin-Won Yun ,  Ho-Cheol Kim

发明人： Seong-Jin Kim ,  Ho-Seong Lee ,  Jin-Won Yun ,  Ho-Cheol Kim

IPC分类号： C07D301/26

CPC分类号： C07D303/16

摘要： There is provided a process for preparing a glycidyl derivative from 3-chloro-1,2-propanediol, comprising i) adding a phosphate salt to a solution into which 3-chloro-1,2-propanediol is dissolved into a solvent to produce glycidol, and ii) adding to the solution of step i) a base capable of releasing a glycidyl group from the glycidol and a substrate susceptible to nucleophilic attack to produce the desired glycidyl derivative by nucleophilic attack of the glycidyl group to the substrate.

摘要翻译： 提供了由3-氯-1,2-丙二醇制备缩水甘油基衍生物的方法，其包括：i）将磷酸盐加入溶于溶剂中的3-氯-1,2-丙二醇溶液中以产生缩水甘油 ，和ii）向步骤i）的溶液中加入能够从缩水甘油中释放缩水甘油基的碱和易受亲核攻击的底物，以通过缩水甘油基的亲核攻击产生所需的缩水甘油基衍生物。

公开(公告)号：US20080233343A1

公开(公告)日：2008-09-25

申请号：US12061777

申请日：2008-04-03

申请人： Joy Cheng ,  Ho-Cheol Kim ,  Robert D. Miller

发明人： Joy Cheng ,  Ho-Cheol Kim ,  Robert D. Miller

IPC分类号： B32B5/12 ,  B05D3/00

CPC分类号： B29D22/00 ,  B33Y10/00 ,  B33Y80/00 ,  B81C1/00031 ,  B81C2201/0149 ,  B82Y30/00 ,  C08L53/00 ,  G03F7/0002 ,  Y10S977/70 ,  Y10S977/701 ,  Y10S977/712 ,  Y10S977/788 ,  Y10S977/932 ,  Y10T428/1393 ,  Y10T428/24132 ,  Y10T428/249921 ,  C08L2666/02 ,  C08L2666/24

摘要： Methods and a structure. A first film of a first block copolymer is formed inside a trough integrally disposed on an energetically neutral surface layer of a substrate. Line-forming microdomains are assembled of the first block copolymer, and form first self-assembled structures within the first film normal to the sidewalls and parallel to the surface layer. At least one microdomain is removed from the first film such that oriented structures remain in the trough oriented normal to the sidewalls and parallel to the surface layer. A second film of a second block copolymer is formed inside the trough. Line-forming microdomains are assembled of the second block copolymer, and form second self-assembled structures within the second film oriented normal to the oriented structures and parallel to the sidewalls. A second method and a structure are also provided.

摘要翻译： 方法和结构。 第一嵌段共聚物的第一膜形成在整体设置在基材的能量中性表面层上的槽内。 线形成微区域由第一嵌段共聚物组装，并且在垂直于侧壁并平行于表面层的第一膜内形成第一自组装结构。 至少一个微区域从第一膜移除，使得定向结构保持在垂直于侧壁并平行于表面层的槽中。 在槽内形成第二嵌段共聚物的第二膜。 线形成微区域由第二嵌段共聚物组装，并且在第二膜中形成第二自组装结构，其定向垂直于取向结构并平行于侧壁。 还提供了第二种方法和结构。

公开(公告)号：US20080171136A1

公开(公告)日：2008-07-17

申请号：US12053721

申请日：2008-03-24

申请人： Geraud Jean-Michel Dubois ,  James Lupton Hedrick ,  Ho-Cheol Kim ,  Victor Yee-Way Lee ,  Teddie Peregrino Magbitang ,  Robert Dennis Miller ,  Muthumanickam Sankarapandian ,  Linda Karin Sundberg ,  Willi Volksen

发明人： Geraud Jean-Michel Dubois ,  James Lupton Hedrick ,  Ho-Cheol Kim ,  Victor Yee-Way Lee ,  Teddie Peregrino Magbitang ,  Robert Dennis Miller ,  Muthumanickam Sankarapandian ,  Linda Karin Sundberg ,  Willi Volksen

IPC分类号： H01B3/20 ,  B05D5/12

CPC分类号： C08L101/12 ,  H01L21/02118 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02216 ,  H01L21/02282 ,  H01L21/31695 ,  H01L21/76807 ,  H01L21/7682 ,  H01L2221/1047

摘要： A composition of matter and a structure fabricated using the composition. The composition comprising: a resin; polymeric nano-particles dispersed in the resin, each of the polymeric nano-particle comprising a multi-arm core polymer and pendent polymers attached to the multi-arm core polymer, the multi-arm core polymer immiscible with the resin and the pendent polymers miscible with the resin; and a solvent, the solvent volatile at a first temperature, the resin cross-linkable at a second temperature, the polymeric nano-particle decomposable at a third temperature, the third temperature higher than the second temperature, the second temperature higher than the first temperature, wherein a thickness of a layer of the composition shrinks by less than about 3.5% between heating the layer from the second temperature to the third temperature.

摘要翻译： 使用该组合物制造的物质组成和结构。 所述组合物包含：树脂; 分散在树脂中的聚合物纳米颗粒，每个聚合纳米颗粒包含多臂芯聚合物和连接到多臂芯聚合物的悬置聚合物，与树脂不混溶的多臂芯聚合物和可混溶的侧链聚合物 与树脂; 和溶剂，所述溶剂在第一温度下挥发，所述树脂在第二温度下可交联，所述聚合物纳米颗粒在第三温度下可分解，所述第三温度高于所述第二温度，所述第二温度高于所述第一温度 ，其中在从第二温度到第三温度的层之间加热组合物的层的厚度收缩小于约3.5％。

公开(公告)号：US20080103256A1

公开(公告)日：2008-05-01

申请号：US11554079

申请日：2006-10-30

申请人： Ho-Cheol Kim ,  Charles Thomas Rettner

发明人： Ho-Cheol Kim ,  Charles Thomas Rettner

IPC分类号： C08L53/00

CPC分类号： C08L53/00 ,  C08L2666/02

摘要： A method and associated structure. A substrate is provided. The substrate has an energetically neutral corrugated surface layer. A film is formed on the corrugated surface layer. The film includes a combination of a di-block copolymer and a stiffening compound. The di-block copolymer includes lamellar microdomains of a first polymer block and lamellar microdomains of a second polymer block. The stiffening compound is dissolved within the first polymer block. At least one lamellar microdomain is removed from the film such that an oriented structure remains on the surface layer.

摘要翻译： 一种方法和相关结构。 提供基板。 衬底具有能量中性的波纹表面层。 在波纹表面层上形成膜。 该膜包括二嵌段共聚物和硬化化合物的组合。 二嵌段共聚物包括第一聚合物嵌段的层状微区和第二聚合物嵌段的层状微区。 硬化化合物溶解在第一聚合物嵌段内。 从薄膜中去除至少一个层状微畴，使得取向结构保留在表面层上。

公开(公告)号：US20070197817A1

公开(公告)日：2007-08-23

申请号：US10592223

申请日：2004-03-13

申请人： Seong-Jin Kim ,  Jeong-Ho Song ,  Jin-Won Yun ,  Ho-Seong Lee ,  Ho-Cheol Kim

发明人： Seong-Jin Kim ,  Jeong-Ho Song ,  Jin-Won Yun ,  Ho-Seong Lee ,  Ho-Cheol Kim

IPC分类号： C07C253/16

CPC分类号： C07C253/16 ,  C07C253/00 ,  C07C255/12 ,  C07C255/13 ,  C07C255/15 ,  C07C255/20 ,  C07C255/31 ,  C07C255/36

摘要： The present invention relates to a method for the preparation of 3-substituted-3′-hydroxypropionitrile, more particularly, to a method for the preparation of 3-substituted-3′-hydroxypropionitrile which comprises performing ring opening of 1-substituted-ethylene oxide using sodium cyanide and citric acid in a range of pH 7.8˜8.3 to provide 3-substituted-3′-hydroxypropionitrile in high optical purity and with high yield.

摘要翻译： 本发明涉及3-取代-3'-羟基丙腈的制备方法，更具体地说涉及制备3-取代-3'-羟基丙腈的方法，该方法包括进行1-取代环氧乙烷的开环 使用氰化钠和柠檬酸在pH 7.8〜8.3的范围内，以高光学纯度和高产率提供3-取代-3'-羟基丙腈。

公开(公告)号：US07229934B2

公开(公告)日：2007-06-12

申请号：US11031418

申请日：2005-01-07

申请人： Geraud Dubois ,  James Hedrick ,  Ho-Cheol Kim ,  Victor Lee ,  Teddie Magbitang ,  Robert Miller ,  Eva Simonyi ,  Willi Volksen

发明人： Geraud Dubois ,  James Hedrick ,  Ho-Cheol Kim ,  Victor Lee ,  Teddie Magbitang ,  Robert Miller ,  Eva Simonyi ,  Willi Volksen

IPC分类号： H01L21/31 ,  H01L21/469

CPC分类号： H01L21/7682 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02214 ,  H01L21/02282 ,  H01L21/02343 ,  H01L21/31633 ,  H01L21/31695 ,  H01L2221/1047

摘要： Oxycarbosilane materials make excellent matrix materials for the formation of porous low-k materials using incorporated pore generators(porogens). The elastic modulus numbers measured for porous samples prepared in this fashion are 3–6 times higher than porous organosilicates prepared using the sacrificial porogen route. The oxycarbosilane materials are used to produce integrated circuits for use in electronics devices.

摘要翻译： 氧碳硅烷材料制成优良的基质材料，用于形成使用并入的孔隙发生器（致孔剂）的多孔低k材料。 以这种方式制备的多孔样品测量的弹性模量数是使用牺牲致孔剂途径制备的多孔有机硅酸盐的3-6倍。 氧碳硅烷材料用于生产用于电子设备的集成电路。

公开(公告)号：US20060205875A1

公开(公告)日：2006-09-14

申请号：US11077804

申请日：2005-03-11

申请人： Jennifer Cha ,  James Hedrick ,  Ho-Cheol Kim ,  Robert Miller ,  Willi Volksen

发明人： Jennifer Cha ,  James Hedrick ,  Ho-Cheol Kim ,  Robert Miller ,  Willi Volksen

IPC分类号： C08L53/00

CPC分类号： C08L101/12 ,  C08L53/00 ,  G03F7/0002 ,  Y10T428/24 ,  Y10T428/2495 ,  Y10T428/24975 ,  Y10T428/249921 ,  Y10T428/249953 ,  Y10T428/249958 ,  Y10T428/249975 ,  Y10T428/249978 ,  Y10T428/249979 ,  Y10T428/24998 ,  Y10T428/25 ,  Y10T428/26 ,  Y10T428/31504 ,  Y10T428/31511 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

摘要： A material and an associated method of formation. A self-assembling block copolymer that includes a first block species and a second block species respectively characterized by a volume fraction of F1 and F2 with respect to the self-assembling block copolymer is provided. At least one crosslinkable polymer that is miscible with the second block species is provided. The self-assembling block copolymer and the at least one crosslinkable polymer are combined to form a mixture. The mixture having a volume fraction, F3, of the crosslinkable polymer, a volume fraction, F1A, of the first block species, and a volume fraction, F2A, of the second block species is formed. A material having a predefined morphology where the sum of F2A and F3 were preselected is formed.

摘要翻译： 一种材料和相关的形成方法。 一种自组装嵌段共聚物，其包括分别以相对于自组装的F 1和F 2的体积分数表征的第一嵌段物质和第二嵌段物质 嵌段共聚物。 提供了与第二嵌段物质混溶的至少一种可交联聚合物。 自组装嵌段共聚物和至少一种可交联聚合物组合形成混合物。 具有第一嵌段物质的可交联聚合物的体积分数F 3 N 3，体积分数F 1 A 1，以及体积分数F _{2A 。 预先选择具有预定形态的材料，其中预先选择F 2 A 2和F 3 3之和。}

公开(公告)号：US08481164B2

公开(公告)日：2013-07-09

申请号：US12061283

申请日：2008-04-02

申请人： Jennifer Nam Cha ,  James Lupton Hedrick ,  Ho-Cheol Kim ,  Robert Dennis Miller ,  Willi Volksen

发明人： Jennifer Nam Cha ,  James Lupton Hedrick ,  Ho-Cheol Kim ,  Robert Dennis Miller ,  Willi Volksen

IPC分类号： C08L53/00 ,  B32B5/22 ,  B32B27/28

CPC分类号： C08L101/12 ,  C08L53/00 ,  G03F7/0002 ,  Y10T428/24 ,  Y10T428/2495 ,  Y10T428/24975 ,  Y10T428/249921 ,  Y10T428/249953 ,  Y10T428/249958 ,  Y10T428/249975 ,  Y10T428/249978 ,  Y10T428/249979 ,  Y10T428/24998 ,  Y10T428/25 ,  Y10T428/26 ,  Y10T428/31504 ,  Y10T428/31511 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

摘要： A material and an associated method of formation. A self-assembling block copolymer that includes a first block species and a second block species respectively characterized by a volume fraction of F1 and F2 with respect to the self-assembling block copolymer is provided. At least one crosslinkable polymer that is miscible with the second block species is provided. The self-assembling block copolymer and the at least one crosslinkable polymer are combined to form a mixture. The mixture having a volume fraction, F3, of the crosslinkable polymer, a volume fraction, F1A, of the first block species, and a volume fraction, F2A, of the second block species is formed. A material having a predefined morphology where the sum of F2A and F3 were preselected is formed.

摘要翻译： 一种材料和相关的形成方法。 提供了一种自组装嵌段共聚物，其包括分别以相对于自组装嵌段共聚物的F1和F2的体积分数表征的第一嵌段和第二嵌段。 提供了与第二嵌段物质混溶的至少一种可交联聚合物。 自组装嵌段共聚物和至少一种可交联聚合物组合形成混合物。 形成具有可交联聚合物的体积分数F3，第一嵌段物质的体积分数F1A和第二嵌段物质的体积分数F2A的混合物。 形成具有预定形态的材料，其中预先选择F2A和F3的总和。

公开(公告)号：US08349203B2

公开(公告)日：2013-01-08

申请号：US12554175

申请日：2009-09-04

申请人： Ho-Cheol Kim ,  Sang-min Park ,  Charles T. Rettner

发明人： Ho-Cheol Kim ,  Sang-min Park ,  Charles T. Rettner

IPC分类号： C03C15/00

CPC分类号： H01L29/0657 ,  B81C1/00031 ,  B81C2201/0149 ,  G03F7/0002 ,  Y10T428/24479 ,  Y10T428/24521 ,  Y10T428/2457 ,  Y10T428/24612 ,  Y10T428/24802

摘要： A method of forming a block copolymer pattern comprises providing a substrate comprising a topographic pre-pattern comprising a ridge surface separated by a height, h, greater than 0 nanometers from a trench surface; disposing a block copolymer comprising two or more block components on the topographic pre-pattern to form a layer having a thickness of more than 0 nanometers over the ridge surface and the trench surface; and annealing the layer to form a block copolymer pattern having a periodicity of the topographic pre-pattern, the block copolymer pattern comprising microdomains of self-assembled block copolymer disposed on the ridge surface and the trench surface, wherein the microdomains disposed on the ridge surface have a different orientation compared to the microdomains disposed on the trench surface.

摘要翻译： 形成嵌段共聚物图案的方法包括提供包括地形预图案的基材，所述地貌预图案包括从沟槽表面分开高度h，大于0纳米的脊表面; 在所述地形预图案上设置包含两个或更多个嵌段组分的嵌段共聚物，以在所述脊表面和所述沟槽表面上形成厚度大于0纳米的层; 并退火所述层以形成具有所述地形预图案的周期性的嵌段共聚物图案，所述嵌段共聚物图案包括设置在所述脊表面上的自组装嵌段共聚物的微区域和所述沟槽表面，其中所述微区域设置在所述脊表面上 与设置在沟槽表面上的微区域相比具有不同的取向。