公开(公告)号：US20220169846A1

公开(公告)日：2022-06-02

申请号：US17434914

申请日：2020-03-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ning Zhou ,  Diane North ,  Matthew A. Jast

IPC: C08L67/04 ,  C08J5/18 ,  C08J7/04 ,  C08J5/12 ,  B32B7/12 ,  B32B27/36 ,  B32B7/02 ,  B32B27/08 ,  B32B27/20 ,  B32B27/22

Abstract: An article is described comprising a first film layer comprising polylactic acid polymer (semicrystalline polylactic acid polymer; amorphous polylactic acid polymer; or a mixture thereof); a second (e.g. polyvinyl acetate) polymer having a Tg of at least 25° C.; plasticizer. In some embodiment, the film layer further comprises inorganic pigment and/or hydrolysis stabilizer. In other embodiments, the film has a net melting endotherm, ΔHnm1, of less than 10 J/g. Also described are methods of making a graphic film.

公开(公告)号：US11110689B2

公开(公告)日：2021-09-07

申请号：US15320551

申请日：2015-06-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David B. Olson ,  Patricia M. Savu ,  Diane North ,  Jordan C. DuCharme

IPC: B32B27/06 ,  C09J133/08 ,  H01L31/048 ,  C09J133/06 ,  C09J133/14 ,  C09J7/38 ,  B32B27/00 ,  B32B27/30 ,  C08F220/18 ,  B32B27/08 ,  B32B7/12 ,  C09J4/00 ,  C09J7/22 ,  B32B27/38 ,  B32B27/28 ,  B32B27/36 ,  B32B27/18 ,  B32B27/32 ,  B32B27/34 ,  B32B27/42 ,  B32B27/40 ,  B32B27/16

Abstract: A composition that includes a blend of a pressure sensitive adhesive and an ultraviolet light-absorbing oligomer. The oligomer has a first divalent unit having a pendent ultraviolet absorbing group and a second divalent unit represented by formula in which R1 is hydrogen or methyl, and R2 is alkyl having from 4 to 20 carbon atom. Articles including the composition are disclosed. For example, an assembly including a barrier film and the composition is also disclosed.

公开(公告)号：US09998070B2

公开(公告)日：2018-06-12

申请号：US15391945

申请日：2016-12-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Mark B. O'Neill ,  Andrew J. Henderson ,  Timothy J. Hebrink ,  Rajesh K. Katare ,  Naiyong Jing ,  Diane North ,  Eric M. Peterson

IPC: H02S40/22 ,  G02B5/08

CPC classification number: H02S40/22 ,  B32B33/00 ,  B32B37/153 ,  B32B2037/246 ,  B32B2038/0028 ,  B32B2038/0092 ,  B32B2307/40 ,  F24S23/70 ,  G02B1/10 ,  G02B1/105 ,  G02B1/14 ,  G02B5/0808 ,  G02B5/0875 ,  Y02E10/40 ,  Y02E10/52

Abstract: The present disclosure generally relates to durable solar mirror films, methods of making durable solar mirror films, and constructions including durable solar mirror films. In one embodiment, the present disclosure relates to a solar mirror film comprising: a multilayer optical film layer including having a coefficient of hygroscopic expansion of less than about 30 ppm per percent relative humidity; and a reflective layer having a coefficient of hygroscopic expansion.

公开(公告)号：US20240294748A1

公开(公告)日：2024-09-05

申请号：US18629011

申请日：2024-04-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ning Zhou ,  Diane North ,  Matthew A. Jast

IPC: C08L67/04 ,  B32B7/02 ,  B32B7/12 ,  B32B27/08 ,  B32B27/20 ,  B32B27/22 ,  B32B27/36 ,  C08J5/12 ,  C08J5/18 ,  C08J7/04

CPC classification number: C08L67/04 ,  B32B7/02 ,  B32B7/12 ,  B32B27/08 ,  B32B27/20 ,  B32B27/22 ,  B32B27/36 ,  C08J5/128 ,  C08J5/18 ,  C08J7/0427 ,  B32B2250/02 ,  B32B2255/10 ,  B32B2264/10 ,  B32B2307/4026 ,  B32B2307/54 ,  B32B2307/702 ,  B32B2307/704 ,  C08J2367/04 ,  C08J2431/04 ,  C08J2467/04 ,  C08L2201/08 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/06

Abstract: An article is described comprising a first film layer comprising polylactic acid polymer (semicrystalline polylactic acid polymer; amorphous polylactic acid polymer; or a mixture thereof); a second (e.g. polyvinyl acetate) polymer having a Tg of at least 25° C.; plasticizer. In some embodiment, the film layer further comprises inorganic pigment and/or hydrolysis stabilizer. In other embodiments, the film has a net melting endotherm, ΔHnm1, of less than 10 J/g. Also described are methods of making a graphic film.

公开(公告)号：US10125251B2

公开(公告)日：2018-11-13

申请号：US15320544

申请日：2015-06-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David B. Olson ,  Patricia M. Savu ,  Diane North

IPC: C08L23/16 ,  C08L27/16 ,  C08J5/18

Abstract: A composition that includes a blend of a fluoropolymer and an ultraviolet light-absorbing oligomer. The oligomer has a first divalent unit having a pendent ultraviolet absorbing group and a second divalent unit represented by formula (I): At least one of the following limitations is also met: the ultraviolet light-absorbing oligomer further comprises a third divalent unit comprising a pendent 2,2,6,6-tetramethylpiperidinyl group, or the composition further comprises a second oligomer comprising a third divalent unit comprising a pendent 2,2,6,6-tetramethylpiperidinyl group at least one of the second divalent units. Articles including the composition are disclosed. The composition can be an extruded film. A method of making such an extruded film is also disclosed.

公开(公告)号：US20170192130A1

公开(公告)日：2017-07-06

申请号：US15461916

申请日：2017-03-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yufeng Liu ,  Timothy J. Hebrink ,  Stephen A. Johnson ,  Diane North

IPC: G02B1/04 ,  G02B5/08 ,  G02B5/02 ,  B42D25/36 ,  B42D25/29 ,  B42D25/23 ,  B42D25/351 ,  B42D25/425 ,  B42D25/455 ,  B29C47/00 ,  B29C47/06 ,  B29C55/12 ,  B29C55/00 ,  B29C35/02 ,  B29D11/00 ,  G02B5/30

CPC classification number: G02B1/10 ,  B29C35/02 ,  B29C48/0018 ,  B29C48/022 ,  B29C48/08 ,  B29C48/185 ,  B29C48/21 ,  B29C55/005 ,  B29C55/12 ,  B29D11/00788 ,  B29K2067/00 ,  B32B7/12 ,  B32B27/08 ,  B32B27/30 ,  B32B27/36 ,  B42D25/00 ,  B42D25/23 ,  B42D25/29 ,  B42D25/351 ,  B42D25/36 ,  B42D25/425 ,  B42D25/445 ,  B42D25/455 ,  G02B1/04 ,  G02B5/0268 ,  G02B5/0284 ,  G02B5/0841 ,  G02B5/3016 ,  G02B5/3041 ,  Y10T428/31786

Abstract: A multilayer optical film includes alternating layers of first and second optical layers; the first optical layer comprising a first polyester, wherein the first polyester comprises first dicarboxylate monomers and first diol monomers, and from about 0.25 to less than 10 mol % of the first dicarboxylate monomers have pendant ionic groups; the second optical layer comprising a second polyester; and wherein the first and second optical layers have refractive indices along at least one axis that differ by at least 0.04. The multilayer optical film may be a polarizer film, a reflective polarizer film, a diffuse blend reflective polarizer film, a diffuser film, a brightness enhancing film, a turning film, a mirror film, or a combination thereof. The multilayer optical film may also be a transaction card such as a financial transaction card, an identification card, a key card, or a ticket card. A method of making the multilayer film is also disclosed.

公开(公告)号：US09568653B2

公开(公告)日：2017-02-14

申请号：US14398485

申请日：2013-04-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Mark B. O'Neill ,  Andrew J. Henderson ,  Timothy J. Hebrink ,  Rajesh K. Katare ,  Naiyong Jing ,  Diane North ,  Eric M. Peterson

IPC: G02B5/00 ,  G02B5/08 ,  F24J2/10 ,  B32B33/00 ,  G02B1/10 ,  G02B1/14 ,  B32B37/15 ,  B32B37/24 ,  B32B38/00

CPC classification number: H02S40/22 ,  B32B33/00 ,  B32B37/153 ,  B32B2037/246 ,  B32B2038/0028 ,  B32B2038/0092 ,  B32B2307/40 ,  F24S23/70 ,  G02B1/10 ,  G02B1/105 ,  G02B1/14 ,  G02B5/0808 ,  G02B5/0875 ,  Y02E10/40 ,  Y02E10/52

Abstract: The present disclosure generally relates to durable solar mirror films, methods of making durable solar mirror films, and constructions including durable solar mirror films. In one embodiment, the present disclosure relates to a solar mirror film comprising: a multilayer optical film layer including having a coefficient of hygroscopic expansion of less than about 30 ppm per percent relative humidity; and a reflective layer having a coefficient of hygroscopic expansion.

Abstract translation: 本公开总体上涉及耐久的太阳镜镜片，制造耐用的太阳镜膜的方法以及包括耐用的太阳镜膜的结构。 在一个实施方案中，本公开涉及一种太阳能镜膜，其包括：多层光学膜层，其包含相对湿度小于约30ppm的吸湿膨胀系数; 以及具有吸湿膨胀系数的反射层。

公开(公告)号：US20130088783A1

公开(公告)日：2013-04-11

申请号：US13687327

申请日：2012-11-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yufeng Liu ,  Timothy J. Hebrink ,  Stephen A. Johnson ,  Diane North

IPC: G02B1/10

CPC classification number: G02B1/10 ,  B29C35/02 ,  B29C48/0018 ,  B29C48/022 ,  B29C48/08 ,  B29C48/185 ,  B29C48/21 ,  B29C55/005 ,  B29C55/12 ,  B29D11/00788 ,  B29K2067/00 ,  B32B7/12 ,  B32B27/08 ,  B32B27/30 ,  B32B27/36 ,  B42D25/00 ,  B42D25/23 ,  B42D25/29 ,  B42D25/351 ,  B42D25/36 ,  B42D25/425 ,  B42D25/445 ,  B42D25/455 ,  G02B1/04 ,  G02B5/0268 ,  G02B5/0284 ,  G02B5/0841 ,  G02B5/3016 ,  G02B5/3041 ,  Y10T428/31786

Abstract: A multilayer optical film includes alternating layers of first and second optical layers; the first optical layer comprising a first polyester, wherein the first polyester comprises first dicarboxylate monomers and first diol monomers, and from about 0.25 to less than 10 mol % of the first dicarboxylate monomers have pendant ionic groups; the second optical layer comprising a second polyester; and wherein the first and second optical layers have refractive indices along at least one axis that differ by at least 0.04. The multilayer optical film may be a polarizer film, a reflective polarizer film, a diffuse blend reflective polarizer film, a diffuser film, a brightness enhancing film, a turning film, a mirror film, or a combination thereof. The multilayer optical film may also be a transaction card such as a financial transaction card, an identification card, a key card, or a ticket card. A method of making the multilayer film is also disclosed.

Abstract translation: 多层光学膜包括第一和第二光学层的交替层; 所述第一光学层包括第一聚酯，其中所述第一聚酯包含第一二羧酸酯单体和第一二醇单体，并且约0.25至小于10mol％的所述第一二羧酸酯单体具有侧基离子基团; 所述第二光学层包含第二聚酯; 并且其中所述第一和第二光学层沿着至少一个不同于0.04的轴的折射率。 多层光学膜可以是偏光膜，反射偏振膜，漫反射偏振膜，漫射膜，亮度增强膜，转膜，镜面膜或其组合。 多层光学膜也可以是诸如金融交易卡，身份证，密钥卡或票卡之类的交易卡。 还公开了制备多层膜的方法。