公开(公告)号：US20160138167A1

公开(公告)日：2016-05-19

申请号：US14900820

申请日：2014-07-04

Applicant: ARCELORMITTAL INVESTIGACION Y DESARROLLO SL

Inventor： Daniel Chaleix ,  Christian Allely ,  Maxime Monnoyer ,  Pascale Feltin

IPC: C23C22/53 ,  C23C22/68

CPC classification number: C23C22/53 ,  C23C2/06 ,  C23C2/26 ,  C23C14/16 ,  C23C14/5846 ,  C23C22/68 ,  C23C28/321 ,  C23C28/34 ,  C25D3/565 ,  C25D5/48 ,  C25D7/0614 ,  C25D11/34

Abstract: The present invention provides a metal sheet including a steel substrate coated on at least one face with a coating including from 0.1 to 20% by weight of magnesium, optionally from 0.1 to 20% by weight of aluminum, the balance being zinc, potential impurities linked to the method and optionally one or more additional elements selected from among Si, Sb, Pb, Ti, Ca, Mn, Sn, La, Ce, Cr, Ni, Zr and Bi, the content by weight of each additional element being less than 0.3%. The coating itself is covered by a layer, based on zinc hydroxychloride, having a chlorine coating weight of at least 1 mg/m2. The layer does not include hydrozincite or mixed hydroxycarbonates of zinc and aluminum or water-soluble compounds of sodium or potassium. The present invention also provides a method to obtain the metal sheet.

Abstract translation: 本发明提供了一种金属板，其包括涂覆在至少一个表面上的钢基材，涂层包括0.1至20重量％的镁，任选0.1至20重量％的铝，余量为锌，可能的杂质连接 所述方法和任选的一种或多种选自Si，Sb，Pb，Ti，Ca，Mn，Sn，La，Ce，Cr，Ni，Zr和Bi中的另外的元素，每个附加元素的重量含量小于 0.3％。 涂层本身被基于羟基氯化锌的层覆盖，氯层重量至少为1mg / m 2。 该层不包括锌和铝的氢化锌或混合羟基碳酸盐或钠或钾的水溶性化合物。 本发明还提供一种获得金属片的方法。

公开(公告)号：US20150368778A1

公开(公告)日：2015-12-24

申请号：US14766344

申请日：2013-07-08

Applicant: ARCELORMITTAL INVESTIGACION Y DESARROLLO, S.L.

Inventor： Christian Allely ,  Luc Diez ,  Tiago Machado Amorim ,  Jean-Michel Mataigne

IPC: C23C2/26 ,  C23C2/06

CPC classification number: C23C2/26 ,  C22C18/04 ,  C23C2/00 ,  C23C2/04 ,  C23C2/06 ,  C23C2/12 ,  C23C2/28 ,  C23C2/40 ,  C23C28/00 ,  C23C28/021 ,  C23C28/025 ,  C23C30/00 ,  C23C30/005 ,  Y10T428/12556 ,  Y10T428/12792 ,  Y10T428/12799 ,  Y10T428/12972 ,  Y10T428/12979 ,  Y10T428/12993

Abstract: A metal sheet including a substrate having at least one face coated by a metallic coating is provided. The metallic coating has an aluminium content by weight tAl of between 3.6 and 3.8% a magnesium content by weight tMg of between 2.7 and 3.3%. The coating has a microstructure comprising a lamellar matrix of eutectic ternary Zn/Al/MgZn2 and possibly: dendrites of Zn with an accumulated surface content exceeding 5.0%, flowers of binary eutectic of Zn/MgZn2 with an accumulated surface content less than or equal to 15.0%, dendrites of binary eutectic Zn/Al surface with an accumulated surface content of less than 1.0% islets of MgZn2 with an accumulated surface content below 1.0%.

Abstract translation: 提供了包括具有被金属涂层涂覆的至少一个面的基板的金属片。 该金属涂层的铝含量按重量计tAl为3.6至3.8％，镁含量按重量计tMg为2.7至3.3％。 该涂层具有包含共晶三元Zn / Al / MgZn2的层状基体的微观结构，并且可能：积累的表面含量超过5.0％的Zn的枝晶，积累的表面含量小于或等于的Zn / MgZn2的二元共晶花 15.0％，二元共晶Zn / Al表面的枝晶，积累的表面含量小于1.0％的MgZn2胰岛，积累的表面含量低于1.0％。

公开(公告)号：US12012655B2

公开(公告)日：2024-06-18

申请号：US17834335

申请日：2022-06-07

Applicant: ArcelorMittal

Inventor： Christian Allely ,  Tiago Machado Amorim ,  Joost De Strycker ,  Krista Godelieve Oscar Van Den Bergh

IPC: C22C38/00 ,  B32B15/01 ,  B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  C21D8/00 ,  C22C21/00 ,  C22C21/02 ,  C22C21/04 ,  C22C21/06 ,  C22C21/08 ,  C22C21/10 ,  C22C21/14 ,  C22C21/16 ,  C22C21/18 ,  C23C2/00 ,  C23C2/02 ,  C23C2/04 ,  C23C2/06 ,  C23C2/12 ,  C23C2/26 ,  C23C2/28 ,  C23C2/34 ,  C23C2/40 ,  C23C28/02 ,  C23C30/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/22 ,  C22C38/28 ,  C22C38/32 ,  C22C38/42 ,  C22C38/44 ,  C22C38/48 ,  C22C38/50 ,  C22C38/54 ,  C22C38/58

CPC classification number: C23C2/12 ,  B32B15/01 ,  B32B15/012 ,  B32B15/013 ,  B32B15/04 ,  B32B15/043 ,  B32B15/18 ,  B32B15/20 ,  C21D8/005 ,  C22C21/00 ,  C22C21/02 ,  C22C21/04 ,  C22C21/06 ,  C22C21/08 ,  C22C21/10 ,  C22C21/14 ,  C22C21/16 ,  C22C21/18 ,  C22C38/00 ,  C23C2/02 ,  C23C2/024 ,  C23C2/026 ,  C23C2/04 ,  C23C2/06 ,  C23C2/26 ,  C23C2/28 ,  C23C2/29 ,  C23C2/34 ,  C23C2/40 ,  C23C28/02 ,  C23C28/021 ,  C23C28/023 ,  C23C30/00 ,  C23C30/005 ,  C21D2211/002 ,  C21D2211/005 ,  C21D2211/008 ,  C22C38/001 ,  C22C38/002 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/22 ,  C22C38/28 ,  C22C38/32 ,  C22C38/42 ,  C22C38/44 ,  C22C38/48 ,  C22C38/50 ,  C22C38/54 ,  C22C38/58 ,  Y10T428/12438 ,  Y10T428/12736 ,  Y10T428/1275 ,  Y10T428/12757 ,  Y10T428/12764 ,  Y10T428/12951 ,  Y10T428/12972 ,  Y10T428/12979 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/263 ,  Y10T428/264 ,  Y10T428/265

Abstract: A steel sheet with a metallic coating is provided. A composition of the metallic coating includes from 2.0 to 24.0% by weight of zinc, from 7.1 to 12.0% by weight of silicon, optionally from 1.1 to 8.0% by weight of magnesium, and optionally additional elements chosen from Pb, Ni, Zr, or Hf. The content by weight of each additional element is less than 0.3%. A balance of the composition is aluminum, unavoidable impurities and residual elements. A ratio Al/Zn is from 4.0 to 6.0.

公开(公告)号：US11976342B2

公开(公告)日：2024-05-07

申请号：US17943561

申请日：2022-09-13

Applicant: ArcelorMittal

Inventor： Sebastian Cobo ,  Christian Allely ,  Martin Beauvais ,  Anis Aouafi ,  Emmanuel Lucas

IPC: C21D9/48 ,  B32B15/01 ,  C21D1/673 ,  C21D6/00 ,  C21D8/02 ,  C22C38/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/44 ,  C22C38/48 ,  C22C38/50 ,  C22C38/54 ,  C23C2/02 ,  C23C2/06 ,  C23C2/12 ,  C23C2/28 ,  C23C2/40

CPC classification number: C21D9/48 ,  B32B15/012 ,  B32B15/013 ,  C21D1/673 ,  C21D6/004 ,  C21D6/005 ,  C21D6/008 ,  C21D8/0205 ,  C21D8/0226 ,  C21D8/0236 ,  C21D8/0263 ,  C22C38/001 ,  C22C38/004 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/44 ,  C22C38/48 ,  C22C38/50 ,  C22C38/54 ,  C23C2/02 ,  C23C2/022 ,  C23C2/024 ,  C23C2/06 ,  C23C2/12 ,  C23C2/28 ,  C23C2/40 ,  C21D2211/002 ,  C21D2211/008

Abstract: A rolled steel sheet, for press hardening is provided, having a chemical composition where Ti/N>3.42, and the carbon, manganese, chromium and silicon contents satisfy:






2.6

C

+

Mn
5.3

+

Cr
13

+

Si
15


≥

1.1

%
.






The sheet has a nickel content Nisurf at any point of the steel in the vicinity of the surface over a depth Δ, such that: Nisurf>Ninom, Ninom denoting the nominal nickel content of the steel, and such that, Nimax denoting the maximum nickel content within Δ:









(


Ni
max

+

Ni
nom


)

2

×

(
Δ
)


≥
0.6

,




and such that:







(


Ni
max

-

Ni
nom


)

Δ

≥
0.01




and the surface density of all of the particles Di, and the surface density of the particles D(>2 μm) larger than 2 micrometers satisfy, at least to a depth of 100 micrometers in the vicinity of the surface of said sheet:

Di+6.75D(>2 μm) 2 μm) being expressed as number of particles per square millimeter, and said particles denoting all the oxides, sulfides, and nitrides, either pure or combined such as oxysulfides and carbonitrides, present in the steel matrix.

公开(公告)号：US11654653B2

公开(公告)日：2023-05-23

申请号：US16605473

申请日：2018-04-25

Applicant: ArcelorMittal

Inventor： Christian Allely ,  Pascal Bertho ,  Anirban Chakraborty ,  Hassan Ghassemi-Armaki

IPC: C25D5/12 ,  B23K11/11 ,  C22C38/02 ,  C22C38/04 ,  C25D5/50 ,  C21D8/02 ,  C23C10/28 ,  C25D3/12 ,  C21D9/46 ,  C25D3/22 ,  C22C38/06 ,  B32B15/01

CPC classification number: B32B15/011 ,  B23K11/11 ,  C21D8/0273 ,  C21D9/46 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C23C10/28 ,  C25D3/12 ,  C25D3/22 ,  C25D5/12 ,  C25D5/50

Abstract: The present invention relates to a method for the manufacture of a galvannealed steel sheet including the steps of A.) coating of the steel sheet with a first coating consisting of nickel and having a thickness between 150 nm and 650 nm, the steel sheet having the following composition in weight percentage 0.10

公开(公告)号：US11566310B2

公开(公告)日：2023-01-31

申请号：US16759253

申请日：2018-11-15

Applicant: ARCELORMITTAL

Inventor： Anirban Chakraborty ,  Hassan Ghassemi-Armaki ,  Pascal Bertho ,  Christian Allely

IPC: C22C38/58 ,  C21D1/76 ,  C21D9/46 ,  C21D9/56 ,  C22C38/02 ,  C22C38/06 ,  C22C38/44 ,  C22C38/48 ,  C22C38/50 ,  C22C38/54 ,  C23C2/06 ,  B23K103/04 ,  B23K11/11 ,  B23K35/02 ,  B23K35/28 ,  B23K35/30

Abstract: The present invention relates to a method for the manufacture of a coated steel sheet comprising the following successive steps: A. the coating of the steel sheet with a first coating consisting of nickel and having a thickness between 600 nm and 1400 nm, the steel sheet having the following composition in weight: 0.10

公开(公告)号：US11473166B2

公开(公告)日：2022-10-18

申请号：US16617903

申请日：2018-05-30

Applicant: ArcelorMittal

Inventor： Sebastian Cobo ,  Christian Allely ,  Martin Beauvais ,  Anis Aouafi ,  Emmanuel Lucas

IPC: C21D9/48 ,  B32B15/01 ,  C21D1/673 ,  C21D6/00 ,  C21D8/02 ,  C22C38/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/44 ,  C22C38/48 ,  C22C38/50 ,  C22C38/54 ,  C23C2/02 ,  C23C2/06 ,  C23C2/12 ,  C23C2/28 ,  C23C2/40

Abstract: A rolled steel sheet, for press hardening is provided, having a chemical composition where Ti/N>3.42, and the carbon, manganese, chromium and silicon contents satisfy: 2.6 ⁢ C + Mn 5.3 + Cr 13 + Si 15 ≥ 1.1 ⁢ % . The sheet has a nickel content Nisurf at any point of the steel in the vicinity of the surface over a depth Δ, such that: Nisurf >Ninom, Ninom denoting the nominal nickel content of the steel, and such that, Nimax denoting the maximum nickel content within Δ: ( Ni max + Ni nom ) 2 × ( Δ ) ≥ 0.6 , and such that: ( Ni max - Ni nom ) Δ ≥ 0.01 and the surface density of all of the particles Di and the surface density of the particles D(>2 μm) larger than 2 micrometers satisfy, at least to a depth of 100 micrometers in the vicinity of the surface of said sheet: Di+6.75 D(>2 μm) 2 μm) being expressed as number of particles per square millimeter, and said particles denoting all the oxides, sulfides, and nitrides, either pure or combined such as oxysulfides and carbonitrides, present in the steel matrix.

公开(公告)号：US10006099B2

公开(公告)日：2018-06-26

申请号：US14858276

申请日：2015-09-18

Applicant: ARCELORMITTAL ,  THYSSENKRUPP STEEL EUROPE AG

Inventor： Colin Scott ,  Philippe Cugy ,  Christian Allely

IPC: C22C38/02 ,  C22C38/04 ,  C22C38/08 ,  C22C38/12 ,  C22C38/16 ,  C21D9/46 ,  C23C2/02 ,  C23C2/06 ,  C23C2/28 ,  C23C28/02 ,  C21D1/26 ,  C21D1/42 ,  C21D1/767 ,  C21D6/00 ,  C21D8/02 ,  C22C38/00 ,  C22C38/06 ,  B32B15/01

CPC classification number: C21D9/46 ,  B32B15/013 ,  C21D1/26 ,  C21D1/42 ,  C21D1/767 ,  C21D6/001 ,  C21D6/004 ,  C21D6/005 ,  C21D6/008 ,  C21D8/0205 ,  C21D8/0236 ,  C22C38/001 ,  C22C38/002 ,  C22C38/02 ,  C22C38/04 ,  C22C38/06 ,  C22C38/08 ,  C22C38/12 ,  C22C38/16 ,  C23C2/02 ,  C23C2/06 ,  C23C2/28 ,  C23C28/021 ,  C23C28/023 ,  C23C28/025 ,  C23C28/028 ,  Y02P10/253 ,  Y10T428/12799

Abstract: A process for fabricating a steel sheet is provided. The process includes soaking a steel sheet. The steel has a composition including iron, carbon, manganese, silicon, aluminum, sulfur, phosphorus and nitrogen and at least one metallic element X chosen among vanadium, titanium, niobium, molybdenum, and chromium. A quantity Xp of metallic element under the form of carbides, nitrides or carbonitrides is, by weight: 0.030%≤Vp≤0.40%; 0.030%≤Tip≤0.50%; 0.040%≤Nbp≤0.40%; 0.14%≤Mop≤0.44%; or 0.070%≤Crp≤0.6%. The soaking step occurs under a pure nitrogen or argon atmosphere with a dew point lower than −30° C. at a soaking temperature θ between 250 and 900° C. and with a dynamic circulation of a regenerated atmosphere.

公开(公告)号：US20160010216A1

公开(公告)日：2016-01-14

申请号：US14768350

申请日：2014-02-18

Applicant: ARCELORMITTAL

Inventor： Christian Allely ,  Tiago Machado Amorim ,  Astrid Coffigny

IPC: C23C28/00 ,  C23C2/26 ,  B32B15/01 ,  C23C22/68 ,  C23C22/60 ,  C23C2/06 ,  C23C2/40

CPC classification number: C23C28/321 ,  B32B15/013 ,  C23C2/06 ,  C23C2/26 ,  C23C2/40 ,  C23C22/60 ,  C23C22/68 ,  C23C28/34 ,  C23G1/20

Abstract: A method for the production of metal sheet including a substrate having two faces, at least one of which is coated with a metal coating including between 0.1 and 10% by weight of Mg and optionally between 0.1 and 20% by weight of Al, the remainder of the metal coating being Zn. The method includes at least the steps of providing a steel substrate having two faces, depositing a metal coating on at least one face hot dipping of the substrate, solidifying the metal coating, applying onto the outer surfaces of the metal coating an aqueous solution having a pH of 7 to 13 and including a magnesium ion complexing agent, for which the dissociation constant pKd of the complexing reaction of the agent with the magnesium is greater than or equal to 2, and to the metal sheet obtainable with this method.

Abstract translation: 一种用于生产金属片的方法，其包括具有两个表面的基底，其中至少一个涂覆有包含0.1至10重量％的Mg和任选地0.1至20重量％的Al的金属涂层，其余部分 的金属涂层是Zn。 该方法至少包括以下步骤：提供具有两个面的钢基材，在基材的至少一个表面上浸渍金属涂层，使金属涂层固化，将金属涂层固化，在金属涂层的外表面上施加具有 pH为7〜13，并且包括镁离子络合剂，其中该试剂与镁的络合反应的解离常数pKd大于或等于2，以及可用该方法获得的金属片。

公开(公告)号：US20150191077A1

公开(公告)日：2015-07-09

申请号：US14413965

申请日：2013-05-13

Applicant: ARCELORMITTAL INVESTIGACIÓN Y DESARROLLO, S.L.

Inventor： Christian Allely ,  Astrid Coffigny-Gregoire ,  Laurence Dosdat ,  Stéphane Morel

IPC: B60J5/04 ,  B32B37/12 ,  B32B37/18 ,  C22C18/04

CPC classification number: B60J5/0483 ,  B32B37/12 ,  B32B37/18 ,  B32B2605/00 ,  C22C18/04 ,  C23C2/06 ,  Y10T156/10 ,  Y10T428/12736

Abstract: The present invention provides an assembly of an aluminum-based element and an element made of steel provided on at least one of the surfaces thereof with a metal coating. The metal coating is made of a zinc-aluminum-magnesium alloy including from 2.3% to 3.3% by weight of magnesium and from 3.5% to 3.9% by weight of aluminum. The remainder of the metal coating is zinc, inevitable impurities and possibly one or more additional elements selected from among Si, Sb, Pb, Ti, Ca, Mn, Sn, La, Ce, Cr, Ni or Bi. The coated surface of the steel element is in at least partial contact with the the aluminum-based element. The contact is brought about by a layer of adhesive or sealant having a thickness of less than 5 mm. The present invention also provides a part for a vehicle including at least one assembly and a vehicle.

Abstract translation: 本发明提供一种铝基元件和由至少一个表面上设置有金属涂层的由钢构成的元件的组件。 该金属涂层由包含2.3％至3.3％重量的镁和3.5％至3.9％重量的铝的锌 - 铝 - 镁合金制成。 金属涂层的其余部分是锌，不可避免的杂质以及可能的一种或多种选自Si，Sb，Pb，Ti，Ca，Mn，Sn，La，Ce，Cr，Ni或Bi中的另外的元素。 钢元件的涂覆表面与铝基元件至少部分接触。 接触是由厚度小于5mm的粘合剂或密封剂层引起的。 本发明还提供了一种包括至少一个组件和车辆的车辆的部件。