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公开(公告)号：US20110152596A1
公开(公告)日：2011-06-23
申请号：US13035382
申请日：2011-02-25
申请人： Horst-Werner ZANTHOFF , Dietrich Maschmeyer , Thomas Quandt , Franz Nierlich , Silvia Santiago Fernandez , Stephan Houbrechts , Georg Skillas , Kurt-Alfred Gaudschun
发明人： Horst-Werner ZANTHOFF , Dietrich Maschmeyer , Thomas Quandt , Franz Nierlich , Silvia Santiago Fernandez , Stephan Houbrechts , Georg Skillas , Kurt-Alfred Gaudschun
IPC分类号： C07C1/20
CPC分类号： B01J21/12 , B01D3/009 , B01J19/30 , B01J19/32 , B01J23/02 , B01J29/0308 , B01J29/08 , B01J29/40 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0201 , B01J37/0213 , B01J37/0225 , B01J2219/30408 , B01J2219/30475 , B01J2219/32416 , B01J2219/32466 , B01J2229/18 , C07C1/20 , C07C1/24 , C07C2521/10 , C07C2521/12 , Y02P20/127 , Y02P20/582 , C07C11/09
摘要： A catalyst, useful in the preparation of isoolefins and containing 0.1 to 20% by mass of an alkali metal oxide, an alkaline earth metal oxide and mixtures thereof; 0.1 to 99% by mass of aluminum oxide; and 0.1 to 99% by mass of silicon dioxide, is prepared by a) treating an aluminosilicate with an aqueous alkali metal salt solution, an alkaline earth metal salt solution and mixtures thereof, under acidic conditions, to obtain a treated aluminosilicate; and b) calcining the treated aluminosilicate, to obtain the catalyst.
摘要翻译： 一种可用于制备异烯烃并含有0.1至20质量％的碱金属氧化物，碱土金属氧化物及其混合物的催化剂; 0.1〜99质量％的氧化铝; 和0.1〜99质量％的二氧化硅，通过a）在酸性条件下用碱金属盐水溶液，碱土金属盐溶液及其混合物处理铝硅酸盐，得到处理过的铝硅酸盐; 和b）煅烧经处理的硅铝酸盐，得到催化剂。
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公开(公告)号：US20080058573A1
公开(公告)日：2008-03-06
申请号：US11836905
申请日：2007-08-10
申请人： Horst-Werner Zanthoff , Dietrich Maschmeyer , Thomas Quandt , Franz Nierlich , Silvia Santiago Fernandez , Stephan Houbrechts , Georg Skillas , Kurt-Alfred Gaudschun
发明人： Horst-Werner Zanthoff , Dietrich Maschmeyer , Thomas Quandt , Franz Nierlich , Silvia Santiago Fernandez , Stephan Houbrechts , Georg Skillas , Kurt-Alfred Gaudschun
IPC分类号： C07C4/06
CPC分类号： B01J21/12 , B01D3/009 , B01J19/30 , B01J19/32 , B01J23/02 , B01J29/0308 , B01J29/08 , B01J29/40 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0201 , B01J37/0213 , B01J37/0225 , B01J2219/30408 , B01J2219/30475 , B01J2219/32416 , B01J2219/32466 , B01J2229/18 , C07C1/20 , C07C1/24 , C07C2521/10 , C07C2521/12 , Y02P20/127 , Y02P20/582 , C07C11/09
摘要： A catalyst, useful in the preparation of isoolefins and containing 0.1 to 20% by mass of an alkali metal oxide, an alkaline earth metal oxide and mixtures thereof; 0.1 to 99% by mass of aluminum oxide; and 0.1 to 99% by mass of silicon dioxide, is prepared by a) treating an aluminosilicate with an aqueous alkali metal salt solution, an alkaline earth metal salt solution and mixtures thereof, under acidic conditions, to obtain a treated aluminosilicate; and b) calcining the treated aluminosilicate, to obtain the catalyst.
摘要翻译： 一种可用于制备异烯烃并含有0.1至20质量％的碱金属氧化物，碱土金属氧化物及其混合物的催化剂; 0.1〜99质量％的氧化铝; 和0.1〜99质量％的二氧化硅，通过a）在酸性条件下用碱金属盐水溶液，碱土金属盐溶液及其混合物处理铝硅酸盐，得到处理过的铝硅酸盐; 和b）煅烧经处理的硅铝酸盐，得到催化剂。
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公开(公告)号：US07977523B2
公开(公告)日：2011-07-12
申请号：US11836905
申请日：2007-08-10
申请人： Horst-Werner Zanthoff , Dietrich Maschmeyer , Thomas Quandt , Franz Nierlich , Silvia Santiago Fernandez , Stephan Houbrechts , Georg Skillas , Kurt-Alfred Gaudschun
发明人： Horst-Werner Zanthoff , Dietrich Maschmeyer , Thomas Quandt , Franz Nierlich , Silvia Santiago Fernandez , Stephan Houbrechts , Georg Skillas , Kurt-Alfred Gaudschun
IPC分类号： C07C4/06
CPC分类号： B01J21/12 , B01D3/009 , B01J19/30 , B01J19/32 , B01J23/02 , B01J29/0308 , B01J29/08 , B01J29/40 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0201 , B01J37/0213 , B01J37/0225 , B01J2219/30408 , B01J2219/30475 , B01J2219/32416 , B01J2219/32466 , B01J2229/18 , C07C1/20 , C07C1/24 , C07C2521/10 , C07C2521/12 , Y02P20/127 , Y02P20/582 , C07C11/09
摘要： A catalyst, useful in the preparation of isoolefins and containing 0.1 to 20% by mass of an alkali metal oxide, an alkaline earth metal oxide and mixtures thereof; 0.1 to 99% by mass of aluminum oxide; and 0.1 to 99% by mass of silicon dioxide, is prepared by a) treating an aluminosilicate with an aqueous alkali metal salt solution, an alkaline earth metal salt solution and mixtures thereof, under acidic conditions, to obtain a treated aluminosilicate; and b) calcining the treated aluminosilicate, to obtain the catalyst.
摘要翻译： 一种可用于制备异烯烃并含有0.1至20质量％的碱金属氧化物，碱土金属氧化物及其混合物的催化剂; 0.1〜99质量％的氧化铝; 和0.1〜99质量％的二氧化硅，通过a）在酸性条件下用碱金属盐水溶液，碱土金属盐溶液及其混合物处理铝硅酸盐，得到处理过的铝硅酸盐; 和b）煅烧经处理的硅铝酸盐，得到催化剂。
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14.发明授权Device for carrying out liquid reactions with fine-grained solid catalysts and method for the use thereof 失效用细粒固体催化剂进行液体反应的装置及其使用方法公开(公告)号：US07569196B2
公开(公告)日：2009-08-04
申请号：US10579471
申请日：2004-09-16
CPC分类号： B01J8/006 , B01F7/00641 , B01J8/085 , B01J8/087 , B01J8/10 , B01J8/222 , B01J19/0046 , B01J19/0066 , B01J2208/0007 , B01J2219/00011 , B01J2219/00033 , B01J2219/00038 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , B01J2219/00236 , B01J2219/00283 , B01J2219/00389 , B01J2219/00423 , B01J2219/00477 , B01J2219/00481 , B01J2219/00495 , B01J2219/00585 , B01J2219/00599 , B01J2219/00707 , B01J2219/00736 , B01J2219/00738 , B01J2219/00747
摘要： A reactor for carrying out catalyzed liquid reactions in which the catalyst is present as a dispersion in the reaction zone. The reactor includes at least one inlet and outlet, with all starting materials being fed in via the inlet and all products being discharged via the outlet. The inlet and outlet can be switched so that an exit previously serving as the outlet is utilized as an entrance serving as the inlet and at the same time an entrance previously serving as the inlet is utilized as an exit serving as the outlet. The inlet and outlet each include a filter element that keeps the catalyst in the reactor. The reactor also includes a device that ensures homogeneous distribution of the catalyst and the starting materials in the reactor. This reactor can carry out reactions at a high solids content without the catalyst having to be separated off from a product stream in an extra process step and without regular cleaning and thus shutdown of the process being necessary.
摘要翻译： 用于进行催化液体反应的反应器，其中催化剂作为反应区中的分散体存在。 反应器包括至少一个入口和出口，所有原料通过入口进料，所有的产物通过出口排出。 入口和出口可以被切换，使得先前用作出口的出口被用作入口用作入口，并且同时将先前用作入口的入口用作出口用作出口。 入口和出口各自包括将催化剂保持在反应器中的过滤元件。 反应器还包括确保催化剂和原料在反应器中均匀分布的装置。 该反应器可以以高固体含量进行反应，而不需要在额外的工艺步骤中将催化剂从产物流中分离出来，并且不需要定期清洁，因此关闭所需的方法。
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15.发明申请Device for carrying out liquid reactions with fine-grained solid catalysts and method for the use thereof 失效用细粒固体催化剂进行液体反应的装置及其使用方法公开(公告)号：US20070104627A1
公开(公告)日：2007-05-10
申请号：US10579471
申请日：2004-09-16
IPC分类号： B01J8/10
CPC分类号： B01J8/006 , B01F7/00641 , B01J8/085 , B01J8/087 , B01J8/10 , B01J8/222 , B01J19/0046 , B01J19/0066 , B01J2208/0007 , B01J2219/00011 , B01J2219/00033 , B01J2219/00038 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , B01J2219/00236 , B01J2219/00283 , B01J2219/00389 , B01J2219/00423 , B01J2219/00477 , B01J2219/00481 , B01J2219/00495 , B01J2219/00585 , B01J2219/00599 , B01J2219/00707 , B01J2219/00736 , B01J2219/00738 , B01J2219/00747
摘要： A reactor for carrying out catalyzed liquid reactions in which the catalyst is present as a dispersion in the reaction zone. The reactor includes at least one inlet and outlet, with all starting materials being fed in via the inlet and all products being discharged via the outlet. The inlet and outlet can be switched so that an exit previously serving as the outlet is utilized as an entrance serving as the inlet and at the same time an entrance previously serving as the inlet is utilized as an exit serving as the outlet. The inlet and outlet each include a filter element that keeps the catalyst in the reactor. The reactor also includes a device that ensures homogeneous distribution of the catalyst and the starting materials in the reactor. This reactor can carry out reactions at a high solids content without the catalyst having to be separated off from a product stream in an extra process step and without regular cleaning and thus shutdown of the process being necessary.
摘要翻译： 用于进行催化液体反应的反应器，其中催化剂作为反应区中的分散体存在。 反应器包括至少一个入口和出口，所有原料通过入口进料，所有的产物通过出口排出。 入口和出口可以被切换，使得先前用作出口的出口被用作入口用作入口，并且同时将先前用作入口的入口用作出口用作出口。 入口和出口各自包括将催化剂保持在反应器中的过滤元件。 反应器还包括确保催化剂和原料在反应器中均匀分布的装置。 该反应器可以以高固体含量进行反应，而不需要在额外的工艺步骤中将催化剂从产物流中分离出来，并且不需要定期清洁，因此关闭所需的方法。
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公开(公告)号：US08877667B2
公开(公告)日：2014-11-04
申请号：US13381676
申请日：2010-06-16
摘要： The invention relates to a process for regenerating catalysts containing mixed oxides from the group of alkali metal and/or alkaline earth metal oxides, aluminium oxide and silicon oxide, characterized in that the regeneration comprises the following features: i) treatment of the catalyst in situ, ii) contacting of the catalyst with water, iii) treatment of the catalyst within a temperature range from 100 to 400° C., iv) treatment of the catalyst within a pressure range from 0.1 to 2 MPa, v) treatment of the catalyst over a period of 0.1 to 24 h, vi) treatment of the catalyst with a specific catalyst hourly space velocity of 0.1 to 100 h−1.
摘要翻译： 本发明涉及一种从碱金属和/或碱土金属氧化物，氧化铝和氧化硅组中再生含有混合氧化物的催化剂的方法，其特征在于再生包括以下特征：i）原位处理催化剂 ，ii）催化剂与水的接触，iii）在100-400℃的温度范围内处理催化剂，iv）在0.1-2MPa的压力范围内处理催化剂，v）处理催化剂 在0.1至24小时的时间内，vi）用特定催化剂处理催化剂，小时空速为0.1至100h-1。
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公开(公告)号：US20130030233A1
公开(公告)日：2013-01-31
申请号：US13394827
申请日：2010-08-12
申请人： Christian Boeing , Dietrich Maschmeyer , Markus Winterberg , Stefan Buchholz , Berthold Melcher , Marco Haumann , Peter Wasserscheid
发明人： Christian Boeing , Dietrich Maschmeyer , Markus Winterberg , Stefan Buchholz , Berthold Melcher , Marco Haumann , Peter Wasserscheid
CPC分类号： C10G50/00 , B01J21/04 , B01J21/066 , B01J21/08 , B01J21/10 , B01J21/18 , B01J21/185 , B01J31/0274 , B01J31/0279 , B01J31/0281 , B01J31/0284 , B01J31/0288 , B01J31/0292 , B01J31/143 , B01J31/2234 , B01J31/2404 , B01J31/26 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J2231/20 , B01J2231/323 , B01J2531/847 , B82Y30/00 , C07C2/32 , C07C2/36 , C07C2531/24 , C10G2300/1088 , C10G2300/70 , C10G2400/22 , C07C11/02
摘要： The invention provides a catalyst system composed of: a) a support material selected from at least one of the following materials: silicon dioxide, aluminium oxide, magnesium oxide, zirconium oxide and mixed oxides thereof, carbon nanotubes; b) an ionic liquid; c) a catalytically active composition comprising nickel; d) an activator selected from the group of Lewis acids with alkylating properties. Additionally provided is the use of the catalyst systems of the invention in the oligomerization of unsaturated hydrocarbon mixtures.
摘要翻译： 本发明提供了一种催化剂体系，该催化剂体系包括：a）选自以下材料中的至少一种的二氧化硅，氧化铝，氧化镁，氧化锆及其混合氧化物的载体材料，碳纳米管; b）离子液体; c）包含镍的催化活性组合物; d）选自具有烷基化性质的路易斯酸的活化剂。 另外提供了本发明的催化剂体系在不饱和烃混合物的低聚反应中的用途。
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公开(公告)号：US20140088226A1
公开(公告)日：2014-03-27
申请号：US14119994
申请日：2012-04-26
申请人： Andreas Gevers , Hinnerk Becker , Michael Grass , Markus Winterberg , Dietrich Maschmeyer , Christian Boeing
发明人： Andreas Gevers , Hinnerk Becker , Michael Grass , Markus Winterberg , Dietrich Maschmeyer , Christian Boeing
IPC分类号： C08K5/1535
CPC分类号： C08K5/1535 , C07D493/04 , C08K5/0016 , C08L27/06
摘要： Dianhydrohexitol diesters of 2-ethylheptanoic acid
摘要翻译： 2-乙基庚酸的二氢己糖二酯
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公开(公告)号：US09200216B2
公开(公告)日：2015-12-01
申请号：US13394827
申请日：2010-08-12
申请人： Christian Boeing , Dietrich Maschmeyer , Markus Winterberg , Stefan Buchholz , Berthold Melcher , Marco Haumann , Peter Wasserscheid
发明人： Christian Boeing , Dietrich Maschmeyer , Markus Winterberg , Stefan Buchholz , Berthold Melcher , Marco Haumann , Peter Wasserscheid
IPC分类号： C10G50/00 , B01J31/02 , B01J31/14 , B01J31/22 , B01J31/24 , B01J31/26 , B82Y30/00 , C07C2/32 , C07C2/36 , B01J21/04 , B01J21/06 , B01J21/08 , B01J21/10 , B01J21/18 , B01J35/02 , B01J35/10
CPC分类号： C10G50/00 , B01J21/04 , B01J21/066 , B01J21/08 , B01J21/10 , B01J21/18 , B01J21/185 , B01J31/0274 , B01J31/0279 , B01J31/0281 , B01J31/0284 , B01J31/0288 , B01J31/0292 , B01J31/143 , B01J31/2234 , B01J31/2404 , B01J31/26 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J2231/20 , B01J2231/323 , B01J2531/847 , B82Y30/00 , C07C2/32 , C07C2/36 , C07C2531/24 , C10G2300/1088 , C10G2300/70 , C10G2400/22 , C07C11/02
摘要： The invention provides a catalyst system composed of: a) a support material selected from at least one of the following materials: silicon dioxide, aluminum oxide, magnesium oxide, zirconium oxide and mixed oxides thereof, carbon nanotubes; b) an ionic liquid; c) a catalytically active composition comprising nickel; d) an activator selected from the group of Lewis acids with alkylating properties. Additionally provided is the use of the catalyst systems of the invention in the oligomerization of unsaturated hydrocarbon mixtures.
摘要翻译： 本发明提供了一种催化剂体系，该催化剂体系包括：a）选自以下材料中的至少一种的二氧化硅，氧化铝，氧化镁，氧化锆及其混合氧化物的载体材料，碳纳米管; b）离子液体; c）包含镍的催化活性组合物; d）选自具有烷基化性质的路易斯酸的活化剂。 另外提供了本发明的催化剂体系在不饱和烃混合物的低聚反应中的用途。
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公开(公告)号：US20140194648A1
公开(公告)日：2014-07-10
申请号：US14122041
申请日：2012-05-15
申请人： Christian Boeing , Dietrich Maschmeyer , Markus Winterberg , Michael Grass , Andreas Gevers , Hinnerk Gordon Becker
发明人： Christian Boeing , Dietrich Maschmeyer , Markus Winterberg , Michael Grass , Andreas Gevers , Hinnerk Gordon Becker
CPC分类号： C07C51/09 , B01J21/04 , B01J23/42 , B01J23/44 , B01J23/755 , B01J35/1019 , C07C67/08 , C08K5/0016 , C08K5/10 , C07C53/128
摘要： Process for producing 2-ethylheptanoic acid.
摘要翻译： 2-乙基庚酸的制备方法。
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