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    Oriented Photocatalytic Semiconductor Surfaces
    11.
    发明申请
    Oriented Photocatalytic Semiconductor Surfaces 审中-公开
    定向光催化半导体表面

    公开(公告)号：US20140256532A1

    公开(公告)日：2014-09-11

    申请号：US13788580

    申请日：2013-03-07

    Applicant: Sunpower Technologies LLC

    Inventor： Daniel Landry ,  Travis Jennings

    IPC: B01J35/00

    CPC classification number: B01J35/004 ,  B01J27/04 ,  B01J27/043 ,  B01J27/045 ,  B01J27/0573 ,  B01J27/0576 ,  B01J35/0013 ,  B01J35/0033 ,  B01J35/006 ,  C01B3/042 ,  C01B3/045 ,  C01B13/0207 ,  C10L3/08 ,  Y02E60/364

    Abstract: The present disclosure relates to oriented photocatalytic semiconductor surfaces which may include photocatalytic capped colloidal nanocrystals (PCCNs) positioned all in the same orientation. The photoactive material may be employed in a plurality of photocatalytic energy conversion applications such as the photocatalytic reduction of carbon dioxide and water splitting, among others. The disclosed oriented PCCNs, within the oriented photoactive material, may also exhibit different shapes and sizes, and higher efficiency in a light harvesting process. Having all the PCCNs oriented at the same angle and dipole moment may allow the light to interact with the dipole at an increased efficiency, to predict the polarity of the light or a more efficient interaction with the nanocrystals substrate, and therefore, increasing the harvesting efficiency by controlling different parts of the light spectrum in the same system.

    Abstract translation: 本公开涉及定向光催化半导体表面，其可以包括全部位于相同取向的光催化封端的胶体纳米晶体（PCCN）。 光活性材料可以用于多种光催化能转换应用，例如二氧化碳的光催化还原和水分解等。 所公开的定向光活性材料中的定向PCCN也可以呈现不同的形状和尺寸，并且在光采集过程中效率更高。 使所有PCCN以相同的角度和偶极矩定向可以允许光以更高的效率与偶极相互作用，以预测光的极性或与纳米晶体衬底更有效的相互作用，因此提高收获效率 通过控制同一系统中光谱的不同部分。

    PHOTOCATALYTIC SYSTEM FOR THE REDUCTION OF CARBON DIOXIDE
    12.
    发明申请
    PHOTOCATALYTIC SYSTEM FOR THE REDUCTION OF CARBON DIOXIDE 审中-公开
    用于减少二氧化碳的光化学体系

    公开(公告)号：US20140174906A1

    公开(公告)日：2014-06-26

    申请号：US13722476

    申请日：2012-12-20

    Applicant: SUNPOWER TECHNOLOGIES LLC

    Inventor： DANIEL LANDRY

    IPC: B01J35/00 ,  B01J23/30 ,  B01J23/36 ,  C07C1/22 ,  B01J27/04

    CPC classification number: B01J35/004 ,  B01J27/043 ,  B01J35/0073 ,  B01J35/06 ,  B82Y30/00 ,  C07C1/22 ,  C07C9/04

    Abstract: A system and method employing sunlight energy for the reduction of carbon dioxide into methane and water are disclosed. Methane gas may then be stored for later use as fuel. The system and method may use inorganic capping agents that cap the surface of semiconductor nanocrystals to form photocatalytic capped colloidal nanocrystals, which may be deposited on a substrate and treated to form a photoactive material. The photoactive material may be employed in the system to harvest sunlight and produce energy necessary for carbon dioxide reduction. The system may also include elements necessary to collect and transfer methane, for subsequent transformation into electrical energy.

    Abstract translation: 公开了一种使用太阳能来将二氧化碳还原成甲烷和水的系统和方法。 然后可以将甲烷气体储存以供以后用作燃料。 该系统和方法可以使用覆盖半导体纳米晶体的表面以形成光催化封端的胶体纳米晶体的无机封端剂，其可以沉积在基底上并被处理以形成光活性材料。 光活性材料可用于系统中以收获太阳光并产生二氧化碳还原所需的能量。 该系统还可以包括收集和转移甲烷所需的元素，以便随后转化成电能。

    Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof
    14.
    发明申请
    Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof 审中-公开
    加氢转化多金属催化剂及其制备方法

    公开(公告)号：US20140066295A1

    公开(公告)日：2014-03-06

    申请号：US14019379

    申请日：2013-09-05

    Applicant: Jinyi Han ,  Alexander E. Kuperman ,  Theodorus Ludovicus Michael Maesen ,  Horacio Trevino

    Inventor： Jinyi Han ,  Alexander E. Kuperman ,  Theodorus Ludovicus Michael Maesen ,  Horacio Trevino

    IPC: B01J27/051 ,  B01J27/049

    CPC classification number: B01J27/0515 ,  B01J27/043 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1038 ,  C10G45/08

    Abstract: A self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock is disclosed. The self-supported MMS catalyst is characterized by an HDN reaction rate constant of at least 100 g feed hr−1 g catalyst−1 assuming first order kinetics, and an HDS reaction rate constant of at least 550 g feed hr−1 g catalyst−1 assuming first order kinetics in hydrotreating of a Heavy Coker Gas Oil as a feedstock with properties indicated in Table A and at given process conditions as indicated in Table E. In one embodiment, the catalyst is characterized as having a multi-phased structure comprising five phases: a molybdenum sulfide phase, a tungsten sulfide phase, a molybdenum tungsten sulfide phase, an active nickel phase, and a nickel sulfide phase.

    Abstract translation: 公开了一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂。 自支撑的MMS催化剂的特征在于以假定一级动力学为至少100g进料hr-1g催化剂-1的HDN反应速率常数，以及至少550g进料hr-1g催化剂-1的HDS反应速率常数， 假设在重型Coker Gas Oil作为原料的加氢处理中的一级动力学作为原料，具有表A所示的性质和表E所示的给定工艺条件。在一个实施方案中，催化剂的特征在于具有多相结构，其包含五 相：硫化钼相，硫化钨相，硫化钨相，活性镍相和硫化镍相。

    Hydroprocessing bulk catalyst and methods of making thereof
    15.
    发明授权
    Hydroprocessing bulk catalyst and methods of making thereof 有权
    加氢处理散装催化剂及其制备方法

    公开(公告)号：US08420565B2

    公开(公告)日：2013-04-16

    申请号：US12625394

    申请日：2009-11-24

    Applicant: Oleg Mironov ,  Alexander E. Kuperman

    Inventor： Oleg Mironov ,  Alexander E. Kuperman

    IPC: B01J31/00 ,  B01J21/00 ,  B01J27/049 ,  B01J27/24 ,  B01J37/20

    CPC classification number: B01J35/002 ,  B01J27/04 ,  B01J27/043 ,  B01J27/049 ,  B01J35/006 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/20

    Abstract: A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (Rp)i(Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least at least a “d” block element metal; L is also at least a “d” block element metal, but different from M; t, u, v, w, x, y, z representing the total charge for each of the components (M, L, S, C, H, O and N, respectively); R is optional and in one embodiment, R is a lanthanoid element metal; 0

    Abstract translation: 提供加氢处理体积催化剂。 还提供了制备加氢处理大量催化剂的方法。 加氢处理催化剂具有式（Rp）i（Mt）a（Lu）b（Sv）d（Cw）e（Hx）f（Oy）g（Nz）h，其中M至少至少为块状元素金属 ; L也至少是一个D块元素金属，但不同于M; 表示各组分（M，L，S，C，H，O和N分别）的总电荷的t，u，v，w，x，y，z; R是任选的，在一个实施方案中，R是镧系元素金属; 0 <= i <= 1; pi + ta + ub + vd + we + xf + yg + zh = 0; 0

    Hydroprocessing Bulk Catalyst and Methods of Making Thereof
    17.
    发明申请
    Hydroprocessing Bulk Catalyst and Methods of Making Thereof 有权
    加氢处理散装催化剂及其制备方法

    公开(公告)号：US20110124493A1

    公开(公告)日：2011-05-26

    申请号：US12625368

    申请日：2009-11-24

    Applicant: Alexander E. Kuperman ,  Oleg Mironov ,  Jinyi Han

    Inventor： Alexander E. Kuperman ,  Oleg Mironov ,  Jinyi Han

    IPC: B01J31/02

    CPC classification number: B01J37/20 ,  B01J23/80 ,  B01J27/043 ,  B01J27/049 ,  B01J35/002 ,  B01J35/023 ,  C10G49/02

    Abstract: A hydroprocessing bulk catalyst is provided. A process to prepare hydroprocessing bulk catalysts is also provided. The hydroprocessing catalyst has the formula (RP)i(Mt)a(Lu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least at least a “d” block element metal; L is also at least a “d” block element metal, but different from M; t, u, v, w, x, y, z representing the total charge for each of the components (M, L, S, C, H, O and N, respectively); R is optional and in one embodiment, R is a lanthanoid element metal; 0

    Abstract translation: 提供加氢处理体积催化剂。 还提供了制备加氢处理大量催化剂的方法。 加氢处理催化剂具有式（RP）i（Mt）a（Lu）b（Sv）d（Cw）e（Hx）f（Oy）g（Nz）h，其中M至少为“d” 块元素金属; L也是至少一个“d”块元素金属，但不同于M; 表示各组分（M，L，S，C，H，O和N分别）的总电荷的t，u，v，w，x，y，z; R是任选的，在一个实施方案中，R是镧系元素金属; 0 <= i <= 1; pi + ta + ub + vd + we + xf + yg + zh = 0; 0

    Process for oxidizing the H2S contained at low concentration in a gas directly to sulphur by catalytic means and in the vapour pause
    19.
    发明授权
    Process for oxidizing the H2S contained at low concentration in a gas directly to sulphur by catalytic means and in the vapour pause 有权
    将气体中低浓度的H 2 S通过催化装置直接氧化成硫的方法，并且在蒸气暂停中进行氧化

    公开(公告)号：US06372193B1

    公开(公告)日：2002-04-16

    申请号：US09578148

    申请日：2000-05-24

    Applicant: Marc Ledoux ,  Jean Nougayrede ,  Cuong Pham-Huu ,  Nicolas Keller ,  Sabine Savin-Poncet ,  Claude Crouzet

    Inventor： Marc Ledoux ,  Jean Nougayrede ,  Cuong Pham-Huu ,  Nicolas Keller ,  Sabine Savin-Poncet ,  Claude Crouzet

    IPC: C01B1704

    CPC classification number: B01J27/047 ,  B01D53/8612 ,  B01J27/043 ,  B01J27/224 ,  C01B17/0465 ,  Y10S502/514

    Abstract: A process for catalytically oxidizing H2S contained in a gas directly to sulphur containing the following steps: combining the H2S-containing gas with a gas containing free oxygen in an amount to produce an oxygen-enriched H2S-containing gas having O2/H2S molar ratio ranging from about 0.05 to about 15; and contacting the oxygen-enriched H2S-containing gas with a catalyst for selective oxidation of H2S to sulphur, wherein the catalyst includes a catalytically active phase combined with a silicon carbide-based support and wherein the active phase of the catalyst consists of at least one oxysulphide of at least one metal selected from the group consisting of iron, copper, nickel, cobalt, chromium, molybdenum and tungsten, at a temperature above the dew point of sulphur formed during H2S oxidation.

    Abstract translation: 将包含在气体中的H 2 S直接催化氧化成硫的方法，其包括以下步骤：将含H 2 S的气体与含有游离氧气的气体组合，以产生具有O 2 / H 2 S摩尔比范围的富氧H 2 S的气体 约0.05至约15; 以及使所述含氧富H2S气体与用于将硫化氢选择性氧化成硫的催化剂接触，其中所述催化剂包括与碳化硅基载体结合的催化活性相，并且其中所述催化剂的活性相由至少一种 在高于硫化氢氧化期间形成的硫的露点的温度下，选自铁，铜，镍，钴，铬，钼和钨中的至少一种金属的硫代硫化物。

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