公开(公告)号：US10189716B2

公开(公告)日：2019-01-29

申请号：US15130522

申请日：2016-04-15

申请人： Susan Hilda Jones

发明人： Susan Hilda Jones

IPC分类号： C01B39/04 ,  B01D53/04 ,  C01B39/46 ,  C01B39/14 ,  C01B39/20 ,  C01B39/22 ,  C01B39/24 ,  C01B39/36 ,  C01B39/38 ,  C01B39/40 ,  B01J20/18 ,  B01J39/14 ,  C07C7/12 ,  C07C17/389 ,  B01D15/36 ,  B01D53/02 ,  B01D53/92 ,  B01J20/28 ,  B01J39/02

摘要： A method of manufacturing a porous monolithic zeolite structure including the steps of; taking a porous monolithic substrate; forming one or more zeolites on the substrate; and substantially or completely removing the substrate.

公开(公告)号：US20180362355A1

公开(公告)日：2018-12-20

申请号：US16056762

申请日：2018-08-07

申请人： ARKEMA FRANCE

发明人： Serge Nicolas ,  Ludivine Bouvier ,  Cécile Lutz

IPC分类号： C01B39/24 ,  C01B39/04

摘要： The present invention concerns Y-type FAU zeolites with hierarchical porosity having an Si/Al atomic ratio strictly greater than 1.4 and less than or equal to 6, having controlled and optimised crystallinity, and having mesoporosity such that the mesoporous outer surface area is between 40 m2·g−1 and 400 m2·g−1. The present invention also concerns the method for preparing said Y-type FAU zeolites with hierarchical porosity.

公开(公告)号：US10118152B2

公开(公告)日：2018-11-06

申请号：US14914220

申请日：2014-08-06

申请人： ARKEMA FRANCE

发明人： Ludivine Bouvier ,  Cecile Lutz ,  Serge Nicolas

IPC分类号： B01J20/18 ,  B01J29/04 ,  C01B39/02 ,  C01B39/24 ,  B01J29/08 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J20/30 ,  B01J20/28 ,  B01J20/12 ,  B01J37/06 ,  B01J37/08 ,  B01J29/00

摘要： The present invention relates to zeolite materials in the form of agglomerates comprising at least one mesoporous Faujasite zeolite with an Si/Al ratio which is strictly greater than 1.4 and having both the characteristics of mesoporous zeolites, the properties associated with microporosity and the mechanical properties of zeolite agglomerates without mesoporous zeolite.The invention also relates to the process for preparing the said zeolite materials in the form of agglomerates.

公开(公告)号：US20180222756A1

公开(公告)日：2018-08-09

申请号：US15750403

申请日：2016-08-04

申请人： PetroChina Company Limited

发明人： Xionghou Gao ,  Shuhong Sun ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Aiguo Lin ,  Xiaoyan Li ,  Lin Wang ,  Gengzhen Cao ,  Conghua Liu ,  Zhishuang Pan ,  Wei Ding ,  Yahong Wang ,  Dong Wang ,  Qiuxia Teng ,  Haitao Zhang

IPC分类号： C01B39/24 ,  C01B39/38 ,  B01J29/46 ,  B01J29/14 ,  B01J37/04 ,  B01J37/03 ,  B01J37/02 ,  B01J37/08

CPC分类号： C01B39/24 ,  B01J29/084 ,  B01J29/088 ,  B01J29/146 ,  B01J29/405 ,  B01J29/46 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  B01J2229/186 ,  B01J2229/42 ,  C01B39/38 ,  C10G11/05 ,  C10G2300/1033 ,  C10G2300/1048

摘要： A preparation method for modified molecular sieve and a modified molecular sieve-containing catalytic cracking catalyst. The preparation method comprises: mixing molecular sieve slurry, a compound solution containing ions of group IIIB metals of the periodic table of elements, organic complexing agent and/or dispersing agent and precipitating agent to obtain mixed slurry containing molecular sieve and precipitates of group IIIB elements in the periodic table of elements; and drying, and roasting or not roasting to obtain molecular sieve modified by the group IIIB elements. A weight ratio of group IIIB elements calculated based on oxides to molecular sieve dry basis is equal to (0.3-10):100, a molar ratio of organic complexing agent to ions of group IIIB metals is equal to (0.3-10):1, and a molar ratio of dispersing agent to the ions of group IIIB metals is equal to (0.2-16):1. Also related to is the catalytic cracking catalyst containing the modified molecular sieve prepared according to the method. The molecular sieve prepared by the method or the catalytic cracking catalyst containing same has good activity stability and heavy metal pollution resistance.

公开(公告)号：US20180093895A1

公开(公告)日：2018-04-05

申请号：US15566302

申请日：2016-04-14

申请人： Consejo Superior de Investigaciones Científicas (CSIC) ,  Universitat Politècnica de València

发明人： Avelino Corma Canós ,  Manuel Moliner Marín ,  Nuria Martín García

IPC分类号： C01B39/48 ,  C01B39/24 ,  C01B39/04 ,  C01B39/02 ,  B01J29/76 ,  B01J35/00 ,  B01D9/00

摘要： The present invention relates to a new process for synthesising the silicoaluminate form of the AEI zeolite structure based on the use of another zeolite, zeolite Y, as the only source of silicon and aluminum, in order to obtain high synthesis yields (greater than 80%) in the absence of any other source of silicon, phosphine-derivedcationsand fluoride anions in the synthesis medium. The N,N-dimethyl-3,5-dimethylpiperidinium cation may be used as the OSDA, and the FAU crystal structure is transformed into the AEI crystal structure with high yields. It also discloses the preparation of catalysts based on the silicoaluminate form of the AEI crystal structure, wherein Cu atoms have been introduced, and the subsequent application thereof as a catalyst, preferably in the SCR of NOx.

公开(公告)号：US09242234B2

公开(公告)日：2016-01-26

申请号：US14808519

申请日：2015-07-24

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  TOTAL MARKETING SERVICES

发明人： Sander Van Donk ,  Maxime Lacroix ,  Régine Kenmogne-Gatchuissi ,  François Fajula ,  Métin Bulut ,  Jean-Pierre Dath ,  Krijn Pieter De Jong ,  Petra Elisabeth De Jongh ,  Jovana Zecevic ,  Adrianus Nicolaas Cornelis Van Laak

IPC分类号： B01J29/08 ,  C01B39/24 ,  B01J37/04 ,  B01J37/00 ,  B01J37/06 ,  B01J37/08 ,  B01J37/02 ,  C10G47/18 ,  B01J29/04

CPC分类号： B01J29/084 ,  B01J29/126 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/108 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/38 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C10G47/18

摘要： The invention relates to a Y-type zeolite having a modified faujasite structure, the intracrystalline structure of which includes at least one network of micropores, at least one network of small mesopores having an average diameter ranging from 2 to 5 nm, and at least one network of large mesopores having an average diameter range from 10 to 50 nm. The invention also relates to particles including such zeolites and to the use thereof in a method for processing crude oil, particularly as a hydrocracking catalyst.

摘要翻译： 本发明涉及具有改性的八面沸石结构的Y型沸石，其结晶结构包括至少一个微孔网络，至少一个平均直径范围为2-5nm的小介孔网络，以及至少一个 具有平均直径范围为10至50nm的大介孔的网络。 本发明还涉及包括这种沸石的颗粒以及其在用于加工原油，特别是加氢裂化催化剂的方法中的用途。

公开(公告)号：US20160008797A1

公开(公告)日：2016-01-14

申请号：US14685819

申请日：2015-04-14

申请人： ZHANJIANG GIANT SUCCESS INVESTMENT CO.,LTD.

发明人： Letian Chen ,  Jianzhong Chen

IPC分类号： B01J29/46 ,  B01J29/14 ,  B01J29/40 ,  B01J21/16 ,  B01J21/08 ,  C01B39/38 ,  B01J35/00 ,  B01J37/02 ,  B01J37/06 ,  B01J37/08 ,  C10G11/05 ,  C01B39/24 ,  B01J29/08 ,  B01J21/04

CPC分类号： B01J29/46 ,  B01J29/049 ,  B01J29/084 ,  B01J29/146 ,  B01J29/40 ,  B01J29/80 ,  B01J35/0006 ,  B01J37/0236 ,  B01J2229/186 ,  B01J2229/64 ,  C01B39/24 ,  C01B39/38 ,  C10G11/05

摘要： A method for synthesis of porous inorganic materials, preparation of a catalyst and catalytic cracking of petroleum hydrocarbons thereof includes processes for synthesis of porous inorganic materials and preparation of the catalytic cracking catalyst and catalytic cracking of petroleum hydrocarbons. The synthesis process is advantaged in low cost in raw materials; the porous inorganic material has various pore structures; and transitional metal used overcomes the defects of the catalytic properties. The porous inorganic material serving as the main active ingredient and containing crystalline aluminum silicate zeolite structures provides surface acidity required by the catalytic reaction. The surface acidity is flexibly adjusted. The hierarchical pore profile improves the accessibility of the active center of the zeolite structure and favors the reaction efficiency and benefits of the petroleum hydrocarbon cracking, and reduces the negative effects caused by diffusion limit. The catalyst containing the porous inorganic material has low manufacturing cost and better properties.

摘要翻译： 多孔无机材料的合成方法，催化剂的制备和石油烃的催化裂化方法，包括合成多孔无机材料的方法，催化裂化催化剂的制备和石油烃的催化裂化。 合成工艺在原材料成本低廉方面具有优势; 多孔无机材料具有各种孔结构; 所使用的过渡金属克服了催化性能的缺陷。 用作主要活性成分并含有结晶硅酸铝沸石结构的多孔无机材料提供催化反应所需的表面酸性。 表面酸度灵活调节。 分层孔隙分布提高了沸石结构活性中心的可及性，有利于石油烃裂解的反应效率和有益效果，并减少了扩散极限引起的负面影响。 含有多孔无机材料的催化剂具有制造成本低，性能更好的特点。

公开(公告)号：US20150209767A1

公开(公告)日：2015-07-30

申请号：US14404774

申请日：2012-07-27

申请人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Xueli Li ,  Hongchang Duan ,  Zhengguo Tan ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Chenxi Zhang ,  Zhishuang Pan ,  Gengzhen Cao

发明人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Xueli Li ,  Hongchang Duan ,  Zhengguo Tan ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Chenxi Zhang ,  Zhishuang Pan ,  Gengzhen Cao

IPC分类号： B01J29/08 ,  B01J37/00 ,  B01J37/06 ,  B01J37/04 ,  C01B39/24 ,  B01J37/08

CPC分类号： B01J29/088 ,  B01J29/084 ,  B01J29/80 ,  B01J35/10 ,  B01J35/109 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C01B39/54

摘要： Provided is a phosphorus-containing ultrastable Y-type rare earth (RE) molecular sieve and the preparation method thereof. The method is: based on Na Y molecular sieve as a raw material, obtaining “one-exchange one-roast” RE-Na Y-type molecular sieve through the steps of exchanging with RE, pre-exchanging with dispersing, and the first calcination; and then performing ammonium salt exchange, phosphorus modification, and the second calcination on the “one-exchange one-roast” RE-Na Y-type molecular sieve, wherein the sequence of the RE exchange and the pre-exchange with dispersing is unlimited, and the sequence of the ammonium salt exchange and the phosphorus modification is unlimited as well. The obtained molecular sieve contains RE oxide 1-20 wt %, phosphorus 0.1-5 wt %, and sodium oxide no more than 1.2 wt %, and has a crystallization degree of 51-69% and a lattice parameter of 2.449-2.469 nm. Heavy oil conversion rate can be increased by using the molecular sieve as an active component in a catalytic cracking catalyst.

摘要翻译： 提供一种含磷超纯Y型稀土（RE）分子筛及其制备方法。 方法为：以Na Y分子筛为原料，通过与RE交换，分散预交换和第一次煅烧的步骤获得“一换一烘焙”RE-Na Y型分子筛 ; 然后在“一换一烘焙”RE-Na Y型分子筛上进行铵盐交换，磷改性和第二次煅烧，其中RE交换和分散预交换的顺序是无限的， 并且铵盐交换和磷改性的顺序也是无限的。 得到的分子筛含有1-20重量％的RE氧化物，0.1-5重量％的磷，不超过1.2重量％的氧化钠，结晶度为51-69％，晶格参数为2.449-2.469nm。 通过在催化裂化催化剂中使用分子筛作为活性组分可以提高重油转化率。

公开(公告)号：US08324415B2

公开(公告)日：2012-12-04

申请号：US12941730

申请日：2010-11-08

申请人： Yushan Yan ,  Brett Holmberg ,  Xin Wang

发明人： Yushan Yan ,  Brett Holmberg ,  Xin Wang

IPC分类号： C01B39/24 ,  C07F7/18 ,  H01M8/10

CPC分类号： B01D71/028 ,  B01D67/0051 ,  B01D2323/12 ,  B01D2325/20 ,  B01J29/084 ,  B01J29/7007 ,  B01J2229/16 ,  B01J2229/32 ,  B82Y30/00 ,  C01B39/026 ,  C01B39/205 ,  C01B39/48 ,  C08J5/2256 ,  C08J2381/06 ,  H01M8/04197 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1051 ,  H01M8/1067 ,  H01M8/1072 ,  H01M2250/20 ,  H01M2250/30 ,  Y02B90/18 ,  Y02E60/521 ,  Y02P70/56 ,  Y02T90/32

摘要： A suite of polymer/zeolite nanocomposite membranes. The polymer backbone is preferably a film forming fluorinated sulfonic acid containing copolymer, such as a Teflon type polymer, a perfluorinated polymer, or a perfluorinated polymer with sulfonic groups. The zeolites formed in accordance with the present invention and which are used in the membranes are plain, phenethyl functionalized and acid functionalized zeolite FAU(Y) and BEA nanocrystals. The zeolite nanocrystals are incorporated into polymer matrices for membrane separation applications like gas separations, and in polymer-exchange-membrane fuel cells. For the purpose of developing zeolite-polymer nanocomposite membranes, the zeolite nanocrystals are size-adjustable to match the polymer-network dimensions.

摘要翻译： 一套聚合物/沸石纳米复合膜。 聚合物主链优选为含氟磺酸共聚物的成膜剂，例如特氟隆型聚合物，全氟化聚合物或具有磺酸基团的全氟化聚合物。 根据本发明形成并用于膜中的沸石是纯的，苯乙基官能化的和酸官能化的沸石FAU（Y）和BEA纳米晶体。 沸石纳米晶体被结合到用于膜分离应用如聚合物交换膜燃料电池中的膜分离应用的聚合物基质中。 为了开发沸石 - 聚合物纳米复合膜，沸石纳米晶体的尺寸可调整以匹配聚合物网络尺寸。

公开(公告)号：US20060034757A1

公开(公告)日：2006-02-16

申请号：US10982708

申请日：2004-11-04

申请人： Yushan Yan ,  Brett Holmberg ,  Xin Wang

发明人： Yushan Yan ,  Brett Holmberg ,  Xin Wang

IPC分类号： H01M8/10 ,  C01B39/24 ,  B01J20/28 ,  B01J29/04 ,  B01J29/06 ,  C01B33/36 ,  C01B39/00

CPC分类号： B01D71/028 ,  B01D67/0051 ,  B01D2323/12 ,  B01D2325/20 ,  B01J29/084 ,  B01J29/7007 ,  B01J2229/16 ,  B01J2229/32 ,  B82Y30/00 ,  C01B39/026 ,  C01B39/205 ,  C01B39/48 ,  C08J5/2256 ,  C08J2381/06 ,  H01M8/04197 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1051 ,  H01M8/1067 ,  H01M8/1072 ,  H01M2250/20 ,  H01M2250/30 ,  Y02B90/18 ,  Y02E60/521 ,  Y02P70/56 ,  Y02T90/32

摘要： A suite of polymer/zeolite nanocomposite membranes. The polymer backbone is preferably a film forming fluorinated sulfonic acid containing copolymer, such as a Teflon type polymer, a perfluorinated polymer, or a perfluorinated polymer with sulfonic groups. The zeolites formed in accordance with the present invention and which are used in the membranes are plain, phenethyl functionalized and acid functionalized zeolite FAU(Y) and BEA nonocrystals. The zeolite nanocrystals are incorporated into polymer matrices for membrane separation applications like gas separations, and in polymer-exchange-membrane fuel cells. For the purpose of developing zeolite-polymer nanocomposite membranes, the zeolite nanocrystals are size-adjustable to match the polymer-network dimensions.

摘要翻译： 一套聚合物/沸石纳米复合膜。 聚合物主链优选为含氟磺酸共聚物的成膜剂，例如特氟隆型聚合物，全氟化聚合物或具有磺酸基团的全氟化聚合物。 根据本发明形成并用于膜中的沸石是纯的，苯乙基官能化的和酸官能化的沸石FAU（Y）和BEA非晶体。 沸石纳米晶体被结合到用于膜分离应用如聚合物交换膜燃料电池中的膜分离应用的聚合物基质中。 为了开发沸石 - 聚合物纳米复合膜，沸石纳米晶体的尺寸可调整以匹配聚合物网络尺寸。