Cationic dyeable polyester fiber and preparing method thereof

    公开(公告)号:US11248087B2

    公开(公告)日:2022-02-15

    申请号:US17277302

    申请日:2019-10-29

    IPC分类号: C08G63/688 D01F6/84

    摘要: A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following: The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.

    Cationic Dyeable Polyester Fiber and Preparing Method Thereof

    公开(公告)号:US20210309799A1

    公开(公告)日:2021-10-07

    申请号:US17277302

    申请日:2019-10-29

    IPC分类号: C08G63/688 D01F6/84

    摘要: A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following: The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.

    BI-DOTA COMPLEX-LOADED DENDRITIC POLYMER NANOPARTICLES

    公开(公告)号:US20210236665A1

    公开(公告)日:2021-08-05

    申请号:US17234323

    申请日:2021-04-19

    摘要: Disclosed are compositions comprising polymeric nanoparticles and methods of using the same. The polymeric nanoparticles can be conjugated with a targeting ligand that is a substrate for a solid tumor-specific cell protein. The polymeric nanoparticles can also comprises an imaging compound and/or a therapeutic agent encapsulated in the hydrophobic interior of the nanoparticle. A cancer therapeutic composition comprising the nanoparticle is also disclosed. The disclosed nanoparticles can be used to target and deliver imaging and/or therapeutic compounds to cancer cells, thereby identifying and/or treating a solid tumor cell target. Methods for treating cancer, such as lung cancer, using the polymeric nanoparticles are also disclosed.

    INKJET INK AND IMAGE FORMING METHOD

    公开(公告)号:US20210139726A1

    公开(公告)日:2021-05-13

    申请号:US17094879

    申请日:2020-11-11

    发明人: Seishi OJIMA

    摘要: The composite particles contained in an inkjet ink are particles of a composite of a polyester resin having a sulfur atom-containing polar group and a dye. The polyester resin is non-crystalline. The polyester resin has a first repeating unit derived from a polyvalent carboxylic acid having the sulfur atom-containing polar group, a second repeating unit derived from a polyvalent carboxylic acid having no sulfur atom-containing polar group, and a third repeating unit derived from a polyhydric alcohol. The content percentage of the first repeating unit relative to a total amount of the first repeating unit and the second repeating unit is 1 to 10 mol %. The content percentage of the polyester resin relative to the composite particles is 50% by mass or more and less than 100% by mass.

    Polyester polyols with increased clarity

    公开(公告)号:US10934390B2

    公开(公告)日:2021-03-02

    申请号:US15730105

    申请日:2017-10-11

    摘要: Polyester polyols, processes for making them, and applications for the polyols are disclosed. Some of the polyols comprise recurring units from a digested thermoplastic polyester (e.g., recycled polyethylene terephthalate), a diol, an optional hydrophobe, and a clarifier. The clarifier, which in some cases is a bisphenol, bisphenol alkoxylate, bisphenol polycarbonate, sulfonyl diphenol, or sulfonyl diphenol alkoxylate, helps the polyol remain clear for weeks or months after its preparation. In some aspects, the clarifier is a monophenol, bisphenol, or poly-phenol having two or more phenylene rings wherein at least two of the phenylene rings lack a common molecular axis. The clarifier may also be an alkylated phenol, an epoxy resin, an epoxy novolac resin, a diphenylmethane, or a tris(aryloxy)phosphate. The polyols are valuable for formulating a variety of polyurethanes and related products—including polyurethane dispersions, flexible and rigid foams, coatings, adhesives, sealants, and elastomers—and they provide a sustainable alternative to bio- or petrochemical-based polyols.

    Shape-memory polymers and methods of making and use thereof

    公开(公告)号:US10647812B2

    公开(公告)日:2020-05-12

    申请号:US15579629

    申请日:2016-06-06

    摘要: Described are shape-memory polymers that have a composite prepolymer crosslinked with a stoichiometric amount of a multifunctional crosslinker, the composite prepolymer having a branched or telechelic prepolymer having a low polydispersity reacted with a non-crystalline chain extender. Also described are methods of making shape-memory polymers by reacting a branched or telechelic prepolymer having a low polydispersity with a non-crystalline chain extender to form a composite prepolymer, and crosslinking a stoichiometric amount of a multifunctional crosslinker with the composite prepolymer, thereby forming the shape-memory polymer.