公开(公告)号：US11866618B2

公开(公告)日：2024-01-09

申请号：US16473650

申请日：2017-12-21

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Dietmar Golombowski ,  Andreas Lutz ,  Stefan Schmatloch

IPC: C09J175/06 ,  C08G18/10 ,  C08K3/04 ,  C08K3/36 ,  C08G18/12 ,  C08G18/16 ,  C08G18/18 ,  C08G18/24 ,  C08G18/30 ,  C08G18/42 ,  C08G18/76 ,  C08G18/79 ,  C08G18/72 ,  C09J175/04 ,  C09J175/08 ,  C08K3/22 ,  C08K3/26

CPC classification number: C09J175/06 ,  C08G18/12 ,  C08G18/165 ,  C08G18/1833 ,  C08G18/246 ,  C08G18/307 ,  C08G18/42 ,  C08G18/724 ,  C08G18/7671 ,  C08G18/792 ,  C08K3/04 ,  C08K3/36 ,  C09J175/04 ,  C09J175/08 ,  C08G18/10 ,  C08K2003/2237 ,  C08K2003/265 ,  C09J2400/143

Abstract: A novel primerless adhesive composition with unique properties in automotive related applications, particularly in glass bonding applications; the process of making thereof.

公开(公告)号：US10815405B2

公开(公告)日：2020-10-27

申请号：US16064578

申请日：2017-01-09

Applicant: Dow Global Technologies LLC

Inventor： Benjamin Haag ,  Andreas Lutz ,  Cathy Grossnickel ,  Raymond F. Bis

IPC: C09J5/06 ,  C09J163/00 ,  C09J175/00 ,  C08G59/20 ,  C08G59/24 ,  C08G59/40 ,  C08G59/68 ,  C09J175/08 ,  C08G18/10 ,  C08G18/20 ,  C08G59/10 ,  C08G59/04 ,  C08G18/32 ,  C08G59/06 ,  B32B27/38 ,  C08G65/333

Abstract: A one-component epoxy-modified polyurethane and/or urea adhesive includes very high levels of reactive urethane group- and/or urea group-containing tougheners, an epoxy resin and epoxy hardener. These adhesives are formulated to cure at high temperatures and surprisingly provide high elongations, excellent thermal stability and good adhesive properties.

公开(公告)号：US20190352549A1

公开(公告)日：2019-11-21

申请号：US16482925

申请日：2018-02-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Tyler Auvil ,  Bindu Krishnan ,  Andreas Lutz ,  Felix Koch ,  Cody Clinton

IPC: C09J163/00 ,  C08G59/40 ,  C08G64/04 ,  B32B7/12 ,  C09J109/00

Abstract: A one-component toughened epoxy-modified polyurethane and/or urea adhesive includes a mixture of dicyandiamide and a dihdyrazide as curing agents. The mixture of curing agents permits the adhesive to be cured at lower temperatures while developing good adhesive and mechanical properties in the cured adhesive.

公开(公告)号：US10155891B2

公开(公告)日：2018-12-18

申请号：US15314148

申请日：2015-07-14

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Daniel Schneider

IPC: B29C65/48 ,  B29C65/54 ,  C08G18/10 ,  C08G18/12 ,  C08G18/30 ,  C08G18/48 ,  C08G18/66 ,  C08G18/73 ,  C09J11/04 ,  C09J175/04 ,  C09J175/08

Abstract: A one-component structural adhesive comprising an isocyanate-terminated prepolymer having polymerized residues of: (a) 40 to 95 wt % of a polytetramethylene ether glycol; and (b) 5 to 60 wt % of an aliphatic diisocyanate.

公开(公告)号：US20170197397A1

公开(公告)日：2017-07-13

申请号：US15470753

申请日：2017-03-27

Applicant: Dow Global Technologies LLC

Inventor： Gary L. Jialanella ,  Glenn G. Eagle ,  Dakai Ren ,  Andreas Lutz

IPC: B32B37/12 ,  C08G59/42 ,  B62D65/00 ,  C08G18/48 ,  C08G18/10 ,  C08G18/80 ,  B32B37/06 ,  C09J163/00

CPC classification number: B32B37/1284 ,  B32B37/06 ,  B32B2037/1253 ,  B32B2307/558 ,  B32B2309/02 ,  B32B2311/24 ,  B32B2605/00 ,  B62D65/00 ,  C08G18/10 ,  C08G18/48 ,  C08G18/8012 ,  C08G18/8067 ,  C08G59/4253 ,  C09J163/00

Abstract: A heat-curable structural adhesive includes a non-rubber-modified epoxy resin, a reaction product of a carboxyl- or amine-terminated butadiene polymer or copolymer and a bisphenol F-based epoxy resin, a elastomeric toughener containing capped isocyanate groups, one or more epoxy curing agents a moisture scavenger and a heat activatable catalyst comprising a mixture of a solid or liquid tertiary amine compound that has a boiling temperature of at least 130° C. and a novolac resin. The structural adhesive develops excellent bonding properties when cured at moderate temperatures, especially from 120 to 170° C., and in addition performs very well in environmental aging stress testing. The adhesive is particularly good for bonding aluminum to another metal, or bonding aluminum to aluminum.

公开(公告)号：US20150267093A1

公开(公告)日：2015-09-24

申请号：US14437285

申请日：2013-03-13

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Zhou Lirong ,  Gary L. Jialanella ,  Andreas Lutz

IPC: C09J175/14 ,  C09J7/02

CPC classification number: C09J175/14 ,  C08F290/067 ,  C08G18/12 ,  C08G18/2081 ,  C08G18/4841 ,  C08G18/632 ,  C08J3/243 ,  C08J2375/16 ,  C09J4/06 ,  C09J7/22 ,  C09J7/38 ,  C09J175/16

Abstract: A composition comprising: a) one or more isocyanate functional components; b) one or more compounds containing a cycloaliphatic tertiary amine: c) one or more low functional acrylate containing components having about 1 to 4 acrylate groups per molecule; d) one or more high functional acrylate containing components having 5 to about 10 acrylate groups per molecule; and e) one or more compounds containing a peroxide group; wherein the composition is a two component composition and components a) and b) are kept separate from component e) until cure is desired. The composition may be utilized as an adhesive.

Abstract translation: 一种组合物，其包含：a）一种或多种异氰酸酯官能组分; b）一种或多种含有脂环族叔胺的化合物：c）每分子具有约1至4个丙烯酸酯基团的一种或多种低官能丙烯酸酯含量的组分; d）每分子具有5至约10个丙烯酸酯基团的一种或多种高官能丙烯酸酯含量的组分; 和e）一种或多种含有过氧化物基团的化合物; 其中所述组合物是双组分组合物，并且组分a）和b）与组分e）保持分离，直到需要固化。 组合物可以用作粘合剂。

公开(公告)号：US20140275423A1

公开(公告)日：2014-09-18

申请号：US14263134

申请日：2014-04-28

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Daniel Schneider

IPC: C08F283/00 ,  C09J163/00

CPC classification number: C08F283/006 ,  C08G18/12 ,  C08G18/2815 ,  C08G18/4854 ,  C08G18/6715 ,  C08G18/672 ,  C08G18/831 ,  C08L63/00 ,  C08L75/16 ,  C08L2666/20 ,  C09J163/00 ,  C09J163/04 ,  C09J175/16 ,  C08G18/6677

Abstract: Structural adhesives are prepared from an elastomeric toughener that contains urethane and/or urea groups, and have some terminal isocyanate groups that are capped with a phenol and other terminal isocyanate groups that are capped with a hydroxy-functional acrylate or a hydroxy-functional methacrylate. In certain embodiments, the presence of both types of capping on the toughener leads to higher impact peel strengths and a greater level of cohesive failure, than when the toughener is capped with a phenol an hydroxy-functional acrylate or hydroxy-functional methacrylate alone.

Abstract translation: 结构粘合剂由含有氨基甲酸酯和/或脲基团的弹性体增韧剂制备，并且具有一些末端异氰酸酯基团，其被带有羟基官能丙烯酸酯或羟基官能的甲基丙烯酸酯封端的苯酚和其它末端异氰酸酯基团封端。 在某些实施方案中，与增韧剂用酚羟基官能的丙烯酸酯或羟基官能的甲基丙烯酸酯单独加封时，在增韧剂上存在两种类型的覆盖物导致较高的冲击剥离强度和更大程度的内聚破坏。

公开(公告)号：US10435600B2

公开(公告)日：2019-10-08

申请号：US15121090

申请日：2015-03-19

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Jeannine Flueckiger ,  Benjamin Alexander Haag ,  Regina Ditschuneit

IPC: C09J163/00 ,  C09J5/06 ,  C09J9/00 ,  C09J11/08 ,  B05D3/02

Abstract: An epoxy adhesive composition is provided that has superior wash-off resistance after pre-gelling, and may be used, for example, in manufacturing processes, for example, in the automobile industry. The composition also provides unique viscosity profile after pre-gelling to significantly reduce failure mode in subsequent processing steps. In preferred embodiments the adhesive composition comprises an epoxy type resin and a gelling agent selected from polyesterdiols and polyvinyl butyrals.

公开(公告)号：US10392539B2

公开(公告)日：2019-08-27

申请号：US15509877

申请日：2015-08-13

Applicant: Dow Global Technologies LLC

Inventor： Gary L. Jialanella ,  Andreas Lutz ,  Eric E. Cole ,  Glenn G. Eagle ,  Rajesh H. Turakhia ,  Yanli Feng

IPC: C09J163/00 ,  C09J5/06 ,  C09J11/02 ,  C09J175/04 ,  C09J153/00 ,  C08L63/00

Abstract: Aspects of the present invention provide a one component epoxy adhesive composition having improved impact resistance at low temperatures, such as −40° C. or less. In a first aspect, the adhesive includes one or more epoxy resins; at least one polyurethane based toughener; at least one amphipathic block copolymer; and one or more epoxy curing agents. In a further, aspect epoxy adhesive compositions having improved wash off resistance are also provided.

公开(公告)号：US10190028B2

公开(公告)日：2019-01-29

申请号：US15111976

申请日：2015-03-24

Applicant: Dow Global Technologies LLC

Inventor： Andreas Lutz ,  Benjamin Alexander Haag ,  Beda Steiner

IPC: C08L63/00 ,  C09J163/00 ,  C08G59/24 ,  C09J11/08

Abstract: The invention relates to resin compositions for epoxy adhesives, comprising a di-functional aromatic epoxy compound. The resin compositions and/or uncured adhesive compositions having low viscosity at low temperatures. Adhesives made therefrom have good strength and bulk properties. The invention includes methods of making and using the compositions, as well as adhesives made from the compositions.