公开(公告)号：US20240010773A1

公开(公告)日：2024-01-11

申请号：US18253758

申请日：2021-11-23

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Guang Ming Li ,  Santosh S. Bawiskar ,  Xiaosong Wu ,  Colin Li Pi Shan

IPC: C08F210/18 ,  C08F210/06 ,  C08F8/48

CPC classification number: C08F210/18 ,  C08F210/06 ,  C08F8/48

Abstract: The present disclosure provides a process and resultant composition. In an embodiment, the process includes providing an ethylene/propylene/non-conjugated polyene terpolymer (EPDM) having at least 3.5 wt % non-conjugated polyene. The process includes reacting the EPDM with a metal-Lewis acid, and forming a rheology-modified EPDM. The rheology-modified EPDM has (i) a z average molecular weight (Mz) from greater than 500,000 g/mole to 10,000,000 g/mole, (ii) a Mz/Mw from 3 to 10, (iii) a g value from 0.4 to 1.0, (iv) a z value from 1.0 to 3.5, (v) a Mooney viscosity from 50 to 150, and (vi) a tan delta value from 0.1 to less than 1.0.

公开(公告)号：US11866530B2

公开(公告)日：2024-01-09

申请号：US17607551

申请日：2019-04-30

Applicant: Dow Global Technologies LLC

Inventor： Xiaosong Wu ,  Colin Li Pi Shan ,  Juan C. Tuberquia ,  Tao Han ,  Guangming Li

IPC: C08F210/18 ,  C08F2/06

CPC classification number: C08F210/18 ,  C08F2/06

Abstract: The present disclosure provides a composition. The composition can be formed into a foam composition. In an embodiment, the composition includes a neat ethylene/propylene/nonconjugated polyene interpolymer. The neat ethylene/propylene/nonconjugated polyene interpolymer includes from greater than 6.0 wt % to 15.0 wt % nonconjugated polyene. The neat ethylene/propylene/nonconjugated polyene interpolymer has the following properties: (i) a molecular weight (Mw) from 240,000 to 270,000; (ii) a Mooney viscosity (ML (1+4), 125° C.) from 85 to 95; (iii) a rheology ratio (RR) from 35 to 65; (iv) a Mw/Mn from 2.2 to 3.5; and (v) Mw

公开(公告)号：US11155693B2

公开(公告)日：2021-10-26

申请号：US15755722

申请日：2016-08-22

Applicant: Dow Global Technologies LLC

Inventor： Bharat I. Chaudhary ,  Juan C. Tuberquia ,  Rennisha Wickham ,  Philip P. Fontaine ,  Colin Li Pi Shan ,  Morgan M. Hughes ,  Jan Bazen ,  Edward O. Madenjian ,  Gregory J. Brennan

IPC: H01B3/30 ,  C08K5/14 ,  C08F210/16 ,  C08J3/24 ,  H01B3/44

Abstract: Crosslinkable polymeric compositions comprising (a) 10 to 99 weight percent of an ethylene-based interpolymer having the following properties: (i) a density of 0.93 g/cm3 or less, (ii) a high-shear viscosity (V100) at 190° C. and 10% strain of 1,200 Pa-s or less, and (iii) a shear thinning ratio (V0.1/V100) at 190° C. and 10% strain of at least 8; and (b) 0 to less than 10 weight percent of a filler, where the ethylene-based interpolymer is not prepared in a high-pressure reactor. Such crosslinkable polymeric compositions may be employed as insulation layers in flexible power cables.

公开(公告)号：US10563099B2

公开(公告)日：2020-02-18

申请号：US15505459

申请日：2014-08-21

Applicant: Dow Global Technologies LLC

Inventor： Liwen Chen ,  Colin Li Pi Shan ,  Selim Yalvac

IPC: C09J11/08 ,  B32B5/02 ,  B32B7/12 ,  B32B21/13 ,  C09J5/06 ,  C09J123/06 ,  C09J123/12

Abstract: A hot melt adhesive composition includes (A) 20-95 wt % of a polymer component including an ethylene-based polymer and a propylene based polymer, the ethylene-based polymer being present in an amount greater than 30 wt %, based on a total weight of the polymer component, and (B) 1-60 wt % of a crystalline block composite comprising (1) a crystalline ethylene based polymer, (2) a crystalline alpha-olefin based polymer derived from at least one of a C3-10 α olefin, and (3) a block copolymer comprising 10-90 wt % of a crystalline ethylene block comprising 90 or more wt % units derived from ethylene and comprising 10-90 wt % of a crystalline alpha-olefin block comprising 90 or more wt % units derived from at least one of a C3-10 α olefin, (C) Optionally, from greater than zero to 70 wt % tackifier, and (D) Optionally, from greater than zero to 40 wt % of at least one selected from the group of a wax and an oil.

公开(公告)号：US10155889B2

公开(公告)日：2018-12-18

申请号：US15505493

申请日：2015-08-20

Applicant: Dow Global Technologies LLC

Inventor： Yi Jin ,  Kim L. Walton ,  Gary R. Marchand ,  Selim Yalvac ,  Allan Walter Mclennaghan ,  Burcak Conley ,  Dean Lee ,  Rongjuan Cong ,  Colin Li Pi Shan

IPC: C09J153/00 ,  C08L23/14 ,  C08L23/06 ,  C08L91/06 ,  C09J7/35 ,  C08L53/00 ,  C09J123/20 ,  C09J123/14

Abstract: A hot melt adhesive (HMA) composition includes (A) from 1-60 wt % of a block composite compatibilizer comprising (i) a hard polymer that includes propylene, (ii) a soft polymer that includes ethylene, and (iii) a block copolymer having a soft block and a hard block, the hard block of the block copolymer having the same composition as the hard polymer of the block composite compatibilizer and the soft block of the block copolymer having the same composition as the soft polymer of the block composite compatibilizer; (B) from 1-70 wt % of a tackifier; (C) from 1-40 wt % of at least one selected from the group of a wax and an oil; and (D) Optionally, from greater than zero to 97 wt % of a polymer component that includes an ethylene-based polymer and/or a propylene-based polymer.

公开(公告)号：US20180105626A1

公开(公告)日：2018-04-19

申请号：US15553356

申请日：2016-03-01

Applicant: Dow Global Technologies LLC

Inventor： Philip P. Fontaine ,  Lixin Sun ,  Colin Li Pi Shan ,  Juan C. Tuberquia ,  Susan G. Brown ,  Edward O. Madenjian ,  Gregory J. Brennan

IPC: C08F210/18 ,  C08F236/20 ,  C08F4/64 ,  C08F2/01 ,  C08L23/16

CPC classification number: C08F210/18 ,  C08F2/01 ,  C08F4/64189 ,  C08F4/64193 ,  C08F4/64196 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F236/20 ,  C08F2500/01 ,  C08L23/16 ,  C08F2/001 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/25

Abstract: The invention provides a process to form a polymer composition comprising at least one ethylene/α-olefin/non-conjugated polyene interpolymer, and wherein the polymer composition has at least the following properties: a) a Mw/V0.1 ratio greater than, or equal to, 1.80 (g/mol)/(Pa·s); said process comprising polymerizing one or more mixture(s) comprising ethylene, an α-olefin and a non-conjugated polyene in the presence of a catalyst system comprising a metal-ligand complex of Formula (I), as described herein.

公开(公告)号：US09511567B2

公开(公告)日：2016-12-06

申请号：US14425400

申请日：2013-09-13

Applicant: Dow Global Technologies LLC

Inventor： Yushan Hu ,  Burcak Conley ,  Kim L. Walton ,  Colin Li Pi Shan ,  Gary R. Marchand ,  Rajen M. Patel ,  Eva-Maria Kupsch ,  Brian W. Walther

IPC: B32B27/08 ,  B32B27/32 ,  B32B27/34 ,  B32B27/30

CPC classification number: B32B27/08 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/34 ,  B32B2250/03 ,  B32B2250/40 ,  B32B2274/00 ,  B32B2307/31 ,  B32B2307/7244 ,  B32B2307/734 ,  B32B2307/738 ,  B32B2439/70 ,  Y10T428/31757 ,  Y10T428/31913

Abstract: Disclosed are multilayer structures comprising a polyolefin layer, a tie layer and a barrier layer wherein the tie layer is a formulation comprising a crystalline block copolymer composite (CBC) comprising i) an ethylene polymer (EP) comprising at least 90 mol % polymerized ethylene; ii) an alpha-olefin-based crystalline polymer (CAOP) and iii) a block copolymer comprising (a) an ethylene polymer block comprising at least 90 mol % polymerized ethylene and (b) a crystalline alpha-olefin block (CAOB).

Abstract translation: 公开了包含聚烯烃层，连结层和阻挡层的多层结构，其中连接层是包含结晶嵌段共聚物复合物（CBC）的制剂，其包含i）包含至少90mol％聚合的乙烯的乙烯聚合物（EP） ii）基于α-烯烃的结晶聚合物（CAOP）和iii）包含（a）包含至少90mol％聚合的乙烯和（b）结晶α-烯烃嵌段（CAOB））的乙烯聚合物嵌段的嵌段共聚物。

公开(公告)号：US09243090B2

公开(公告)日：2016-01-26

申请号：US14278472

申请日：2014-05-15

Applicant: Dow Global Technologies LLC

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  Yunwa Wilson Cheung ,  David D. Devore ,  David D. Graf ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Colin Li Pi Shan ,  Benjamin C. Poon ,  Gordon R. Roof ,  James C. Stevens ,  Pamela J. Stirn ,  Timothy T. Wenzel

IPC: C08F10/00 ,  C08F2/38 ,  C08F210/14 ,  C08F297/08 ,  C08F4/6592 ,  B32B27/32 ,  C08F297/00 ,  C08L23/08 ,  C08F4/659 ,  C08F110/02 ,  C08L23/02 ,  C08L23/10

CPC classification number: B32B27/327 ,  B32B27/06 ,  B32B27/32 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C08F110/02 ,  C08F210/14 ,  C08F210/16 ,  C08F295/00 ,  C08F297/00 ,  C08F297/08 ,  C08F297/083 ,  C08F297/086 ,  C08F2410/01 ,  C08F2410/04 ,  C08F2420/02 ,  C08L23/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/10 ,  C08L53/00 ,  C08L53/005 ,  Y10T428/24942 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31573 ,  Y10T428/31587 ,  C08F2/38 ,  C08F4/65904 ,  C08L2666/06 ,  C08F2500/09 ,  C08F2500/03 ,  C08F4/64148 ,  C08F4/64193 ,  C08F4/64048 ,  C08F4/6411 ,  C08F4/64144 ,  C08F2500/08 ,  C08F4/64113 ,  C08L2666/02 ,  C08L2666/04 ,  C08F2500/12 ,  C08F2500/20 ,  C08F210/08 ,  C08F2500/11 ,  C08F2500/21 ,  C08F210/02 ,  C08F212/08 ,  C08F232/02 ,  C08F232/08

Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract translation: 一种用于形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，使用该多嵌段共聚物的聚合方法和所得聚合物，其中组合物包含混合物或反应产物 由（A）第一金属络合物烯烃聚合催化剂，（B）能够在等效聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二金属络合物烯烃聚合催化剂，以及 （C）链式穿梭剂。

公开(公告)号：US20250145795A1

公开(公告)日：2025-05-08

申请号：US18719400

申请日：2021-12-17

Applicant: Dow Global Technologies LLC

Inventor： Yabin Sun ,  Gaoxiang Wu ,  Colin Li Pi Shan ,  Wenxin Zhang

IPC: C08K5/134 ,  C08K5/1545 ,  C08K5/3492 ,  C08K5/52 ,  C08L23/08

Abstract: A process to form a composition, and related composition, the process comprising mixing at least the following components: a) at least one olefin/silane interpolymer comprising at least one Si—H group, and b) at least one hindered phenol selected from Formula H, as described herein.

公开(公告)号：US20250136798A1

公开(公告)日：2025-05-01

申请号：US18719668

申请日：2021-12-17

Applicant: Dow Global Technologies LLC

Inventor： Andong Liu ,  Yabin Sun ,  Wenxin Zhang ,  Colin Li Pi Shan ,  Gaoxiang Wu

IPC: C08L23/12 ,  C08J3/00

Abstract: A process to form a composition, and related composition, the process comprising thermally treating at least the following components: a) an olefin/silane interpolymer comprising at least one Si—H group, and b) a propylene-based polymer, or a propylene-based composition that comprises a propylene-based polymer. A process to form a composition, the process comprising thermally treating at least the following component(s): a) an olefin/silane interpolymer comprising at least one Si—H group, and wherein the olefin/silane interpolymer is formed in the presence of a bis-biphenyloxy metal complex; and wherein the composition does not comprise a peroxide.