摘要:
Environmentally safe and compatible fluids that are useful as lubricants, and especially as hydraulic fluids, in mobile machinery are formulated to be non-contaminating when accidentally contacted with surrounding vegetation, and removable from vegetation by simply washing the vegetation with tap water. The fluids of the invention are polyalkylene glycol-based and having an ethylene oxide to propylene oxide ratio of from about 68:32 to about 78:22.
摘要:
A composition and method for providing a silicon-nitrogen surface on metals wherein is reacted a source of silicon, a source of ammonium ions, an alkali metal hydroxide in an aqueous medium to produce an electrolyte solution comprising a complex ion mixture. The electrolyte solution can be used to deposit a silicon surface on conductive substrates. The electrolyte solution can be dehydrated in a hydrocarbon medium, thus providing novel materials for use as lubricating oil additives and as fuel additives. The fuels and lubricants can be used as carriers for depositing the complex to form a silicon/nitrogen and silicon/nitrogen bimetallic surfaces on metal surfaces including, but not limited to, metals in the combustion chamber either through an aqueous phase or through a hydrocarbon phase. These new silicon/nitrogen surfaces may significantly reduce coefficient of friction, smooth the flame front, reduce corrosion, enhance fuel economy, and reduce hydrocarbon emissions when used in internal combustion engines.
摘要:
Internal combustion engines exhibit improved efficiency of the emissions control system by using a lubricating oil composition of a base oil, an alkali or alkaline earth metal-containing detergent; a metal salt of one or more phosphorus-containing compounds represented by the formula (I), wherein X1 and X2 are independently O or S, and R1 and R2 are independently hydrocarbyl groups, the average total number of carbon atoms in R1 and R2 for the one or more phosphorus-containing compounds being at least 10.4; and an acylated nitrogen-containing compound having at least about 10 alphatic carbon atoms and a TBN of at least about 2; the lubricating oil composition being characterized by a phosphorus concentration of up to about 0.12% by weight and the substantial absence of copper, thereby generating a lean-phosphorus containing exhaust gas.
摘要:
Graft copolymers, particularly useful as dispersant viscosity index improvers in lubricating oil compositions have a polymer backbone selected from is selected from the group consisting of olefin polymers, diene polymers, vinyl polymers and vinylidene polymers, is grafted with an amine selected from N-p-diphenylamine, 1,2,3,6-tetrahydrophthalimide; 4-anilinophenyl methacrylamide; 4-anilinophenyl maleimide; 4-anilinophenyl itaconamide; acrylate and methacrylate esters of 4-hydroxydiphenylamine; the reaction product of p-aminodiphenylamine or p-alkylaminodiphenylamine with glycidyl methacrylate; the reaction product of p-aminodiphenylamine with isobutyraldehyde, derivatives of p-hydroxydiphenylamine; derivatives of phenothiazine; vinylogous derivatives of diphenylamine; and mixtures thereof and may be prepared in a single step process using solution or bulk grafting conditions.
摘要:
Liquid phase liquid crystal polymers (LCPs) are disclosed having a composition and structure that can be varied to provide desirable properties. The liquid phase LCPs have polyiminoborane, polyaminoborane, and/or borozine polymer backbone molecules, with silicon and/or phosphorous side chain molecules linked to the backbone that provide a degree of alignment assigned an Order Parameter (S), defined as S=⅓[3 cos2 θ−1], where θ is the angle between the axis of an LCP molecule and the vertical direction. The inventive liquid phase LCPs have an average Order Parameter in the range of about 0.2 to about 0.99 and are applicable to a number of rinse, coolant, lubricant, sterilization and other protectant processes.
摘要翻译:公开了液相液晶聚合物(LCP),其具有可以改变以提供所需性质的组成和结构。 液相LCP具有聚亚氨基硼烷,聚氨基硼烷和/或硼嗪聚合物主链分子,其中连接至骨架的硅和/或磷侧链分子提供一定程度的对准,其定义为S = 1 / 3 [3 cos <2θ-1],其中θ是LCP分子的轴线与垂直方向之间的角度。 本发明的液相LCP具有约0.2至约0.99范围内的平均订单参数,并且可应用于多种冲洗,冷却剂,润滑剂,灭菌和其它保护剂方法。
摘要:
A fuel composition, and a method and an apparatus for combusting it in a two-stroke engine, in which molybdenum introduced from the fuel will interact with alkaline earth metal originating from a detergent or other co-ingredient of the fuel in the combustion products to increase detergency without increasing the level of alkaline earth metal or compounds present in the fuel or combustion products thereof. In this manner, the engine operates more cleanly and efficiently without increasing the risk of harmful alkaline earth materials and compounds thereof blocking and poisoning catalysts, sensors and/or automotive on-board diagnostic devices, and it can lead to improved durability of exhaust after treatment systems.
摘要:
Soot induced kinematic viscosity increase of lubricating oil compositions for diesel engines equipped with EGR systems can be ameliorated by selection of viscosity modifier, lubricating oil flow improvers, detergents and/or dispersants.
摘要:
Lubricating oil compositions comprise a lubricating base oil and (A) at least one compound selected from the group consisting of compounds represented by formula (1) below and compounds represented by formula (2) below: wherein R2, R1, R3 and R4 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X1, X2, X3 and X4 are each independently oxygen or sulfur, but at least one of them is oxygen, and Y1 is a metal atom; and wherein R11 and R12 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X11 and X12are each independently oxygen or sulfur, but at least one of them is oxygen, U is a monovalent metal ion, an ammonium ion or a proton, and k1 is an integer of 1 to 20. Lubricating oil compositions have excellent anti-wear properties and base number maintaining properties.
摘要:
A lubricant containing (a) a synthetic base oil composition having an overall kinematic viscosity of at least about 4.8×10−6 m2/s (4.8 cSt) at 100° C. and a viscosity index of at least about 110; (b) a dispersant-viscosity modifier; and (c) a sulfur-free functionalized hydrocarbyl-substituted phenol detergent provides improved valve train wear, with longer drain intervals, to heavy duty diesel engines.
摘要翻译:一种含有(a)合成基础油组合物的润滑剂,其总运动粘度在100℃下至少为约4.8×10 -6 m 2 / s(4.8cSt),粘度指数为至少约110; (b)分散剂 - 粘度调节剂; 和(c)无硫官能化烃基取代的苯酚清净剂为重型柴油发动机提供改进的气门机构磨损,并具有较长的排水间隔。
摘要:
Lubricant compositions including an additive composition and methods for its use in engines that produce soot. The lubricant composition contains a base oil and an additive composition having (a) at least 0.05 percent by weight of a first dispersant that is a reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine; and (b) at least 0.05 percent by weight, both based on a total weight of the lubricant composition, of a second dispersant that is a reaction product of A′) a hydrocarbyl-dicarboxylic acid or anhydride, and B′) at least one polyamine, wherein the reaction product is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.