Method of manufacturing o- and p-nitrobenzaldehyde
    32.
    发明授权
    Method of manufacturing o- and p-nitrobenzaldehyde 失效
    制备邻硝基苯甲醛和对硝基苯甲醛的方法

    公开(公告)号:US4605777A

    公开(公告)日:1986-08-12

    申请号:US744143

    申请日:1985-06-12

    Applicant: Boris Holm

    Inventor: Boris Holm

    CPC classification number: C07C201/10 C07C45/63

    Abstract: This invention relates to a method of manufacturing ortho- and para-nitrobenzaldehyde from o-chloro or o-bromobenzaldehyde and p-chloro or p-bromobenzaldehyde respectively through a nucleophilic aromatic substitution reaction performed in an organic solvent.

    Abstract translation: 本发明涉及分别通过在有机溶剂中进行的亲核芳族取代反应从邻氯或邻溴苯甲醛和对氯或对溴苯甲醛生产邻硝基苯甲醛和对硝基苯甲醛的方法。

    Preparation of petachloronitrobenzene
    33.
    发明授权
    Preparation of petachloronitrobenzene 失效
    制备氯化亚硝基苯

    公开(公告)号:US3984487A

    公开(公告)日:1976-10-05

    申请号:US638394

    申请日:1975-12-08

    CPC classification number: C07C201/10

    Abstract: A novel method for preparing pentachloronitrobenzene directly from the corresponding pentachlorobenzonitrile compound is disclosed. Pentachlorobenzonitrile is heated in the presence of an excess of sulfuric acid and a nitrating agent, e.g., nitric acid at elevated temperatures of from about 100.degree.C to about 160.degree.C for a time sufficient to convert the pentachlorobenzonitrile to a pentachloronitrobenzene.In one embodiment the pentachlorobenzonitrile compound is first heated in the presence of an excess of concentrated sulfuric acid at temperatures in excess of 180.degree.C to activate the pentachlorobenzonitrile and the activated material is then heated at lower temperatures of about 100.degree. to 120.degree.C in the presence of a nitrating agent to convert the activated pentachlorobenzonitrile to the corresponding pentachloronitrobenzene.

    Abstract translation: 公开了一种从相应的五氯苯腈化合物中直接制备五氯硝基苯的新方法。 在过量的硫酸和硝化剂例如硝酸的存在下,将五氯苄腈在约100℃至约160℃的升高的温度下加热足够的时间以将五氯苄腈转化为五氯硝基苯。

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