公开(公告)号：US20110262699A1

公开(公告)日：2011-10-27

申请号：US13175865

申请日：2011-07-03

Applicant: Angelo Yializis ,  Gordon Goodyear ,  Steven Yializis

Inventor： Angelo Yializis ,  Gordon Goodyear ,  Steven Yializis

IPC: E04B1/94 ,  E04B1/62 ,  B32B5/18 ,  B32B3/10 ,  B32B15/04 ,  B32B27/06

CPC classification number: C23C14/022 ,  B32B5/022 ,  B32B5/024 ,  B32B5/026 ,  B32B5/18 ,  B32B15/046 ,  B32B15/08 ,  B32B15/12 ,  B32B15/14 ,  B32B27/32 ,  B32B29/002 ,  B32B2255/06 ,  B32B2255/20 ,  B32B2307/304 ,  B32B2307/3065 ,  B32B2307/416 ,  B32B2307/538 ,  B32B2307/546 ,  B32B2307/712 ,  B32B2307/714 ,  B32B2307/7145 ,  B32B2307/724 ,  B32B2307/7265 ,  B32B2307/732 ,  B82Y10/00 ,  C23C14/20 ,  C23C14/562 ,  C23C14/5826 ,  C23C14/5853 ,  G21K1/062 ,  G21K2201/061 ,  Y10T428/24331 ,  Y10T428/24851 ,  Y10T428/24975 ,  Y10T428/249976 ,  Y10T428/24998 ,  Y10T428/249987 ,  Y10T428/249991 ,  Y10T442/3398 ,  Y10T442/475 ,  Y10T442/657

Abstract: A multilayer radiant-barrier structure is formed on one or both sides of a substrate that can be attached to an insulating layer to produce a reflective insulating material. The metallized layer is protected from environmental degradation without interfering with flammability properties that are critical for radiant and reflective insulation materials used in housing applications. The metal layer is modified to insulate enclosures without blocking cellular communications and the protective functional layer in modified to minimize emissivity, create a hydrophobic and/or oleophobic surface, and/or prevent mold, fungi and bacteria growth. Solutions are provided to solve occupational-hazard problems associated with the use of these materials in enclosures that include power wires.

Abstract translation: 在衬底的一侧或两侧上形成多层辐射阻挡结构，该衬底可附接到绝缘层以产生反射绝缘材料。 金属化层被保护免受环境退化，而不会干扰对于在住房应用中使用的辐射和反射绝缘材料至关重要的可燃性。 金属层被修饰以绝缘外壳而不阻塞细胞通信，并且保护功能层被修饰以最小化发射率，产生疏水和/或疏油表面，和/或防止霉菌，真菌和细菌生长。 提供解决方案来解决与在包括电力线的外壳中使用这些材料相关的职业危害问题。

公开(公告)号：US20090041936A1

公开(公告)日：2009-02-12

申请号：US12250083

申请日：2008-10-13

Applicant: Angelo Yializis ,  James DiBattista ,  Gordon Goodyear

Inventor： Angelo Yializis ,  James DiBattista ,  Gordon Goodyear

IPC: C23C16/00

CPC classification number: C23C14/022 ,  C23C14/20 ,  C23C14/562 ,  C23C14/5826 ,  C23C14/5853

Abstract: A coated, low-emissivity aluminum film is manufactured entirely in vacuum by depositing an aluminum layer over a substrate and then immediately coating the metal layer with a very thin protective polymeric layer. The thickness of this coating is selected to minimize absorption in the 3-15 micron wavelength. In vacuum, the metal layer is coated substantially in the absence of moisture, thereby preventing the formation of hydrated oxides that promote corrosion. The aluminum layer is preferably also passivated by in-line exposure to a plasma gas containing an oxygen-bearing component. A leveling polymeric layer may also be deposited between relatively rough substrates and the aluminum layer in order to improve the reflectivity of the resulting structures.

Abstract translation: 通过在衬底上沉积铝层，然后立即用非常薄的保护性聚合物层涂覆金属层，完全在真空中制造涂覆的低发射率铝膜。 选择该涂层的厚度以使在3-15微米波长的吸收最小化。 在真空中，基本上没有水分地涂覆金属层，从而防止形成促进腐蚀的水合氧化物。 铝层优选通过在线暴露于含有含氧组分的等离子体气体而被钝化。 为了提高所得结构的反射率，也可以在相对粗糙的基底和铝层之间沉积出均匀的聚合物层。

公开(公告)号：US20070166556A1

公开(公告)日：2007-07-19

申请号：US11586478

申请日：2006-10-25

Applicant: Angelo Yializis ,  Michael G. Mikhael

Inventor： Angelo Yializis ,  Michael G. Mikhael

IPC: C23C16/00 ,  H05H1/00 ,  B32B15/04 ,  B32B15/20

CPC classification number: C23C14/022 ,  C23C14/20 ,  C23C14/562 ,  C23C14/5826 ,  C23C14/5853 ,  Y10T428/31678

Abstract: In a continuous in-vacuum process for the manufacture of a film metallized with aluminum, the aluminum layer is exposed to a passivating agent, inline, immediately after deposition and prior to rewinding of the film onto a take-up roller. Passivation is carried out by plasma treatment in an oxidizing atmosphere (oxygen, nitrogen or others). The resulting product exhibits no peel-off problems during unwinding of the take-up roller and greatly improved corrosion resistance.

Abstract translation: 在用于制造用铝金属化的膜的连续真空过程中，铝层在沉积之后并且在将膜重新卷绕到卷取辊上之前立即暴露于钝化剂。 钝化通过在氧化气氛（氧气，氮气或其它）中等离子体处理进行。 所得产品在卷取辊的卷绕过程中不会出现剥离问题，并且极大地改善了耐腐蚀性。

公开(公告)号：US20070166528A1

公开(公告)日：2007-07-19

申请号：US11334211

申请日：2006-01-18

Applicant: John James Barnes ,  Ioannis V. Bletsos ,  Angelo Yializis ,  Michael G. Mikhael

Inventor： John James Barnes ,  Ioannis V. Bletsos ,  Angelo Yializis ,  Michael G. Mikhael

IPC: B32B15/04 ,  B32B3/26 ,  B05D3/00

CPC classification number: C23C14/562 ,  B05D3/142 ,  B05D7/02 ,  B05D7/14 ,  B05D2350/65 ,  C23C14/5826 ,  C23C14/5853 ,  E04B1/625 ,  E04B2001/7691 ,  E04D12/002 ,  Y10T428/24322 ,  Y10T428/249953 ,  Y10T428/265 ,  Y10T428/2935 ,  Y10T428/31678 ,  Y10T442/259

Abstract: A process for forming a low emissivity, moisture vapor permeable metallized composite sheet by coating a moisture vapor permeable sheet with at least one metal and exposing the freshly deposited metal to an oxidizing plasma thereby forming a protective synthetic metal oxide over the metal. The composite sheet material is suitable for use as a building construction barrier layer such as roof lining and house wrap.

Abstract translation: 一种通过用至少一种金属涂覆水蒸汽可透过的片材并将新沉积的金属暴露于氧化等离子体从而在金属上形成保护性合成金属氧化物，形成低辐射率，透湿度的金属化复合片材的方法。 复合片材适用于建筑施工阻隔层，例如屋顶衬砌和房屋包装。

公开(公告)号：US20070048512A1

公开(公告)日：2007-03-01

申请号：US11589564

申请日：2006-10-30

Applicant: Michael Mikhael ,  Angelo Yializis

Inventor： Michael Mikhael ,  Angelo Yializis

IPC: B32B3/26 ,  B32B3/06

CPC classification number: B01D71/022 ,  B01D39/1623 ,  B01D39/18 ,  B01D39/2017 ,  B01D39/2065 ,  B01D67/0072 ,  B01D67/0088 ,  B01D67/009 ,  B01D71/02 ,  B01D2239/0241 ,  B01D2239/0414 ,  B01D2239/0421 ,  B01D2239/0428 ,  B01D2239/045 ,  B01D2239/0457 ,  B01D2239/0478 ,  B01D2239/0492 ,  B01D2239/065 ,  B01D2239/10 ,  B01D2239/1291 ,  B01D2325/04 ,  B01D2325/26 ,  B01D2325/30 ,  B01D2325/36 ,  B01D2325/38 ,  B05D1/60 ,  B05D3/142 ,  B05D3/144 ,  C23C8/02 ,  C23C8/20 ,  C23C8/80 ,  C23C28/00 ,  C23C30/00 ,  D04H1/42 ,  D06M10/025 ,  D06M10/08 ,  D06M14/18 ,  Y10T428/249953 ,  Y10T428/249956 ,  Y10T428/249987 ,  Y10T428/24999

Abstract: A porous substrate is pretreated in a plasma field and a functionalizing monomer is immediately flash-evaporated, deposited and cured over the porous substrate in a vacuum vapor-deposition chamber. By judiciously controlling the process so that the resulting polymer coating adheres to the surface of individual fibers in ultra-thin layers (approximately 0.02-3.0 μm) that do not extend across the pores in the material, the porosity of the porous substrate is essentially unaffected while the fibers and the final product acquire the desired functionality. The resulting polymer layer is also used to improve the adherence and durability of metallic and ceramic coatings.

Abstract translation: 多孔基材在等离子体场中进行预处理，并且在真空气相沉积室中立即将功能化单体快速蒸发，沉积并固化在多孔基材上。 通过明智地控制该方法，使得所得到的聚合物涂层附着在不延伸穿过材料孔隙的超薄层（约0.02-3.0μm）中的单个纤维的表面上，多孔基材的孔隙率基本上不受影响 而纤维和最终产品获得所需的功能。 所得聚合物层也用于改善金属和陶瓷涂层的粘附性和耐久性。

公开(公告)号：US20050045103A1

公开(公告)日：2005-03-03

申请号：US10502274

申请日：2003-01-23

Applicant: Michael Mikhael ,  Angelo Yializis

Inventor： Michael Mikhael ,  Angelo Yializis

IPC: C03C17/32 ,  C03C23/00 ,  H05H1/24

CPC classification number: C03C23/006 ,  C03C17/32 ,  C03C2218/31 ,  H05H1/2406 ,  H05H2001/2418

Abstract: A method of applying a polymer (116) to a glass surface (100) includes applying atmospheric plasma (110) to a glass surface (100), applying a film (116) of polymerizable fluid to the surface (100) and curing the film with high-energy radiation (114). Apparatus for applying atmospheric plasma includes positive (14, 21) and ground (15, 23) electrodes, and an emitter strip (16, 22) of porous material with a plasma gas (108) diffusing between the electrodes and through the emitter strip onto the glass surface.

Abstract translation: 将聚合物（116）施加到玻璃表面（100）的方法包括将大气等离子体（110）施加到玻璃表面（100），将可聚合流体的膜（116）施加到表面（100）并固化膜 具有高能辐射（114）。 用于施加大气等离子体的装置包括正（14,21）和地（15,23）电极和多孔材料的发射极条（16,22），其中等离子体气体（108）在电极之间扩散并通过发射器条带到 玻璃表面。

公开(公告)号：US06774018B2

公开(公告)日：2004-08-10

申请号：US10228358

申请日：2002-08-26

Applicant: Michael G. Mikhael ,  Angelo Yializis ,  Richard E. Ellwanger

Inventor： Michael G. Mikhael ,  Angelo Yializis ,  Richard E. Ellwanger

IPC: H01L2120

CPC classification number: H01J37/32009 ,  C23C16/30 ,  C23C16/509 ,  H01J37/32018 ,  H01J37/3244 ,  H01J37/32449 ,  H01J37/32532 ,  H01J37/32724 ,  H01J37/32825 ,  H05H1/2406 ,  H05H2001/2412 ,  H05H2240/10

Abstract: A plasma is produced in a treatment space by diffusing a plasma gas at atmospheric pressure and subjecting it to an electric field created by two metallic electrodes separated by a dielectric material, a vapor precursor is mixed with the plasma, and a substrate material is coated by vapor deposition of the vaporized substance at atmospheric pressure in the plasma field. The use of vaporized silicon-based materials, fluorine-based materials, chlorine-based materials, and organo-metallic complex materials enables the manufacture of coated substrates with improved properties with regard to moisture-barrier, oxygen-barrier, hardness, scratch- and abrasion-resistance, chemical-resistance, low-friction, hydrophobic and/or oleophobic, hydrophilic, biocide and/or antibacterial, and electrostatic-dissipative/conductive characteristics.

Abstract translation: 在处理空间中通过在大气压下扩散等离子体气体而产生等离子体，并使其被由电介质材料分离的两个金属电极产生的电场，蒸气前体与等离子体混合，并且基板材料被涂覆 气化物质在大气压下在等离子体场中气相沉积。 使用蒸发的硅基材料，氟基材料，氯基材料和有机金属复合材料使得能够制造具有改善的防潮性，阻氧性，硬度，划痕和耐刮擦性能的涂层基材 耐磨性，耐化学性，低摩擦性，疏水性和/或疏油性，亲水性，杀生物剂和/或抗菌和静电消散/导电特性。

公开(公告)号：US06649433B2

公开(公告)日：2003-11-18

申请号：US09892120

申请日：2001-06-26

Applicant: Michael G. Mikhael ,  Angelo Yializis

Inventor： Michael G. Mikhael ,  Angelo Yializis

IPC: H01L2100

CPC classification number: H01L51/56 ,  C23C14/12 ,  H01L51/0002 ,  H01L51/001 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/0081 ,  H01L51/5012 ,  H01L51/5221 ,  H01L2251/568 ,  Y10T428/239 ,  Y10T428/31504

Abstract: A heterogeneous blend of small electron-donor organic molecules and polymerizable monomers is flash evaporated to provide a molecular-level vapor-phase mixture, which is then condensed and cured in-line as a homogeneous liquid layer on a flexible web containing an anodic layer. The procedure is repeated with an electron-acceptor organic substance, which is deposited over the electron-donor layer. A metallic cathode is then deposited over the electron-acceptor layer and the composite OLED product is packaged. The electrical characteristics and the thickness of the metallic cathode and the composition of the polymer layers are selected such as to produce the gasification of elemental carbon generated by dielectric breakdowns and the oxidation of any exposed cathodic surface, thereby providing a built-in mechanism to prevent the propagation of the damage caused by electrical shorts.

公开(公告)号：US06447553B1

公开(公告)日：2002-09-10

申请号：US09695746

申请日：2000-10-24

Applicant: Michael G. Mikhael ,  Angelo Yializis

Inventor： Michael G. Mikhael ,  Angelo Yializis

IPC: C09B6200

CPC classification number: C08F2/44 ,  B01J19/1887 ,  B01J2219/00128 ,  B01J2219/0013 ,  F26B5/041 ,  F26B5/048 ,  F26B5/065 ,  F26B17/023

Abstract: A radiation curable monomer and a dystuff are mixed in a curable formulation and fed into a hot evaporator under vacuum. The blend is flash evaporated through a nozzle and recondensed onto a moving substrate in contact with a temperature-controlled rotating drum. The condensed film is then crosslinked with a high-energy ultraviolet or electron-beam radiation source to effect cross-linking of the monomer. The resulting product consists of a crosslinked polymer matrix incorporating dyestuff molecules within its structure, which dramatically enhances the durability, solvent resistance, heat stability and migration fastness of the product. These properties can be further improved by chemically bonding the dyestuff molecules with the crosslinked polymer network, which can be accomplished by judiciously functionalizing the dyestuff with appropriate functional groups designed to polymerize or to react with the curable monomer.

Abstract translation: 将可辐射固化的单体和吸收剂混合在可固化制剂中并在真空下进料到热蒸发器中。 混合物通过喷嘴快速蒸发并重新凝结到与受温度控制的旋转鼓接触的移动基板上。 然后将冷凝的膜与高能量紫外线或电子束辐射源交联以实现单体的交联。 所得产品由在其结构内掺入染料分子的交联聚合物基质组成，其显着提高了产品的耐久性，耐溶剂性，热稳定性和迁移牢度。 通过将染料分子与交联聚合物网络化学键合可以进一步改善这些性能，这可以通过用设计为聚合或与可固化单体反应的合适的官能团明智地使染料官能化来实现。

公开(公告)号：US6118218A

公开(公告)日：2000-09-12

申请号：US241882

申请日：1999-02-01

Applicant: Angelo Yializis ,  Shahid A. Pirzada ,  Wolfgang Decker

Inventor： Angelo Yializis ,  Shahid A. Pirzada ,  Wolfgang Decker

IPC: H05H1/24 ,  B01J19/08 ,  H01J37/32 ,  H05H1/46

CPC classification number: H01J37/32009 ,  H01J37/3244 ,  H01J37/32449 ,  H01J37/32532

Abstract: A plasma treater incorporates a porous metallic layer in one of the electrodes. The porous layer is selected with pores of average size within one order of magnitude of the mean free path of the plasma gas at atmospheric pressure. The plasma gas is injected into the electrode at substantially atmospheric pressure and allowed to diffuse through the porous layer, thereby forming a uniform glow-discharge plasma. The film material to be treated is exposed to the plasma created between this electrode and a second electrode covered by a dielectric layer. Because of the micron size of the pores of the porous metal, each pore also produces a hollow cathode effect that facilitates the ionization of the plasma gas. As a result, a steady-state glow-discharge plasma is produced at atmospheric pressure and at power frequencies as low as 60 Hz.

Abstract translation: 等离子体处理器在其中一个电极中并入多孔金属层。 多孔层的选择是在大气压下等离子体气体的平均自由程的一个数量级的平均尺寸孔。 等离子体气体在大气压下注入电极，并使其扩散通过多孔层，从而形成均匀的辉光放电等离子体。 待处理的薄膜材料暴露于由该电极和被电介质层覆盖的第二电极之间产生的等离子体。 由于多孔金属的孔的微米尺寸，每个孔也产生促进等离子体气体电离的空心阴极效应。 结果，在大气压力和低至60Hz的功率频率下产生稳态辉光放电等离子体。