Polyarylene sulfide manufacturing method and polyarylene sulfide manufacturing device

    公开(公告)号:US10407551B2

    公开(公告)日:2019-09-10

    申请号:US15872210

    申请日:2018-01-16

    Abstract: To provide a polyarylene sulfide (hereinafter, PAS) manufacturing method and PAS manufacturing device that further eliminates processing costs in manufacturing PAS, by recovering from solid content containing an unreacted sulfur source and alkali metal halide produced as a byproduct the sulfur source and the solid content with a reduced amount of the sulfur source, and then conveniently and easily reusing the unreacted sulfur source without performing a large-scale process. A method of manufacturing PAS according to the present invention comprises: a polymerizing step of producing PAS; an extracting step of bringing an extraction solvent into content with solid content produced in the polymerizing step, and extracting at least a portion of a sulfur source from the solid content; a recovering step of separating and recovering the solid content passing through the extracting step and an extraction liquid produced in the extracting step; and a recycling step of supplying at least a portion of the extraction liquid preferably as at least a portion of PAS produced raw material in the polymerizing step; where the extraction solvent is (1) a protic organic solvent or (2) a mixed solvent containing water and an organic solvent, and the amount of the sulfur source in the solid content recovered in the recovering step is 2 parts by mass or less with regard to 100 parts by mass of the alkali metal halide.

    Polyarylene sulfide production method and polyarylene sulfide produced using production method

    公开(公告)号:US10196486B2

    公开(公告)日:2019-02-05

    申请号:US15327472

    申请日:2015-08-03

    Abstract: The present invention is a production method for producing polyarylene sulfide, wherein an unreacted dihalo aromatic compound is recovered and reused. The present production method includes: (a) a polymerization step; (b) a separation step; and (c) a recovery step of recovering unreacted dihalo aromatic compound from a water-containing mixture of the separated liquid by steam distillation entailing adjusting the reflux ratio of water in the steam distillation column without adding water other than the refluxed water. Alternatively, the production method includes: (a) a polymerization step; (d) a dehydration step; and (c) a recovery step of recovering unreacted dihalo aromatic compound from a water-containing mixture of a water-containing liquid mixture and/or a water-containing steam mixture containing a raw material mixture and/or a polymerization reaction solution by steam distillation entailing adjusting the reflux ratio of water in the steam distillation column without adding water other than the refluxed water in the dehydration step.

    GEL ELECTROLYTE AND METHOD FOR PREPARING SAME

    公开(公告)号:US20190013547A1

    公开(公告)日:2019-01-10

    申请号:US16067849

    申请日:2017-02-08

    Inventor: Keisuke WATANABE

    Abstract: Provided is a gel electrolyte that has a lower concentration of matrix polymer and that can maintain a gel state. The gel electrolyte contains a non-aqueous electrolyte solution in which a lithium-containing electrolyte is dissolved in a non-aqueous solvent and a matrix polymer, the matrix polymer being a copolymer containing a vinylidene fluoride unit and a fluorine atom-containing monomer unit as a repeating unit, and the crystallization temperature Tc of the matrix polymer being within a range that satisfies the following Relationship (I) relative to the concentration C (mass %) of the matrix polymer included in the gel electrolyte: Tc≥110−C  (I), where 0.1≤C≤30.

    ELECTRODE STRUCTURAL BODY AND PRODUCTION METHOD THEREOF

    公开(公告)号:US20180248193A1

    公开(公告)日:2018-08-30

    申请号:US15559100

    申请日:2016-04-13

    Abstract: In an electrode structural body, a coated film is obtained by applying an electrode mixture including an electrode active material, a first fluorine based polymer, and a solvent and drying the mixture, then formed on the surface of a current collector, the first fluorine based polymer has one or more side chains represented by the following Formula (1), and the coated film is subjected to heat treatment. —X—COOH   (1) (In Formula (1), X is an atomic group having a molecular weight of less than 500, the main chain of which is made up of 1 to 20 atoms.)

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