Perfluoroaliphatic substituted amine mixtures and the method for
preparing the same
    44.
    发明授权
    Perfluoroaliphatic substituted amine mixtures and the method for preparing the same 失效
    全氟脂肪族取代胺混合物及其制备方法

    公开(公告)号:US4059629A

    公开(公告)日:1977-11-22

    申请号:US593173

    申请日:1975-07-03

    摘要: The invention comprises perfluoroalkyl substituted amines of the formula ##STR1## wherein n is an integer from 1 to about 20, m is an integer between 2 or 4, R.sup.1 and R.sup.2 each is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms and R.sup.3 and R.sup.4 each is a hydrogen atom, an alkyl containing 1 to 20 carbon atoms, an alkenyl containing 3 to 10 carbon atoms, a cycloparaffin radical containing 3 to 12 carbon atoms, a cycloalkenyl radical containing 5 to 12 carbon atoms, and N or O ring substituted cycloalkenyl radical containing 5 to 12 carbon atoms, or an aryl, or R.sup.3 or R.sup.4 are joined in the form of an alkylene radical of the formula--(CHR).sub.p --wherein p is an integer from 2 to 6 and R is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms. These compounds are prepared by reacting at a temperature in the range between 0.degree. to 200.degree. C. perfluoroalkyl halides of the formulaC.sub.n F.sub.2n+1 (CR.sup.1 R.sup.2).sub.m Y (II)wherein n, m, R.sup.1 and R.sup.2 each has the same meaning as defined hereinabove and Y is an iodine or a bromine atom with amines of the formula ##STR2## wherein R.sup.3 and R.sup.4 have the same meaning as previously stated. The invention also comprises perfluoroalkyl substituted amines of the formula ##STR3## and mixtures of products of formula IV with ##STR4## in which R.sup.1, R.sup.3 and R.sup.4 have the same meaning as designated above and where n is an integer from 4 to 20.The process for producing the products of formulas IV and V and mixtures thereof is the same as that used for the products of the compounds of formula I except that in the starting compounds of formula II at least one of the radicals R.sup.1 or R.sup.2 is hydrogen, m is equal to 2 and n is an integer between 4 and 20.

    摘要翻译: 本发明包括式(I)的全氟烷基取代的胺,其中n为1至约20的整数,m为2或4之间的整数,R 1和R 2各自为氢原子或含有1至 3个碳原子,R 3和R 4各自为氢原子,含有1至20个碳原子的烷基,含有3至10个碳原子的烯基,含有3至12个碳原子的环烷基,含有5至12个碳原子的环烯基 ,并且含有5至12个碳原子的N或O环取代的环烯基或芳基或R 3或R 4以式 - (CHR)p - 亚烷基的亚烷基的形式连接在一起,从2到 6 AND R是氢原子或含有1至3个碳原子的低级烷基。 这些化合物通过在0℃至200℃范围内的温度下反应制备,式C n F 2n + 1(CR 1 R 2)m Y(II)的全氟烷基卤化物,其中n,m,R 1和R 2各自具有与所定义相同的含义 并且Y是碘或溴原子与式(III)的胺,其中R3和R4具有与前述相同的含义。

    Textile treatment composition
    45.
    发明授权
    Textile treatment composition 失效
    纺织品处理组成

    公开(公告)号:US4043923A

    公开(公告)日:1977-08-23

    申请号:US446003

    申请日:1974-02-26

    申请人: Basil L. Loudas

    发明人: Basil L. Loudas

    摘要: Textiles, particularly carpets, are endowed with oil and water repellency and soil resistance by treatment thereof with certain detergent-compatible fluorochemical compounds which can also be used in conjunction with anionic or nonionic detergents to provide cleaning/treating compositions for cleaning such textiles simultaneously with the treatment. The textile treating compositions of the invention comprise certain detergent-compatible fluorochemical compounds which are dissolved and/or dispersed in a suitable liquid vehicle. The textile treating/cleaning compositions of the invention also contain an anionic and/or a nonionic detergent.

    摘要翻译: 纺织品,特别是地毯,通过用某些与洗涤剂相容的含氟化合物进行处理,具有防油和防水性和抗污性,其也可与阴离子或非离子洗涤剂结合使用以提供清洁/处理组合物,用于与 治疗。 本发明的纺织品处理组合物包含溶解和/或分散在合适的液体载体中的某些与洗涤剂相容的含氟化合物。 本发明的纺织品处理/清洁组合物还含有阴离子和/或非离子洗涤剂。

    Perfluoro-aliphatic substituted aminoalcohols
    46.
    发明授权
    Perfluoro-aliphatic substituted aminoalcohols 失效
    全氟脂族取代​​氨基醇

    公开(公告)号:US3873619A

    公开(公告)日:1975-03-25

    申请号:US13880871

    申请日:1971-04-29

    申请人: UGINE KUHLMANN

    摘要: The invention comprises perfluoroalkyl substituted aminoalcohols of the formula

    WHEREIN N IS AN INTEGER FROM 1 TO ABOUT 20, M IS 2 OR 4, R1 and R2 each is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms, Q is a radical -(CHR)q- wherein R is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms and q is an integer from 1 to 10, R3 is a hydrogen atom, an alkyl radical containing 1 to 20 carbon atoms, a cycloalkyl radical containing 3 to 12 carbon atoms, a cycloalkenyl radical containing 5 to 12 carbon atoms, an N or O ring substituted cycloalkenyl containing 5 to 12 carbon atoms, an aryl radical, the radical -QOH, the radical CnF2n 1(CR1R2)m- or R3 and Q are joined in the form of an alkylene radical of the formula

    摘要翻译: 本发明包括下式的全氟烷基取代的氨基醇,其中N为1至约20的整数,M为2或4,R 1和R 2各自为氢原子或含有1至3个碳原子的低级烷基,Q为基团 - (CHR)q-,其中R是氢原子或含有1至3个碳原子的低级烷基,q是1至10的整数,R 3是氢原子,含有1至20个碳原子的烷基,环烷基 含有3至12个碳原子的环烯基,含有5至12个碳原子的环烯基,含有5至12个碳原子的N或O环取代的环烯基,芳基,基团-QOH,基团CnF2n + 1(CR1R2)m- 或R 3和Q以式 - (CHR) - 的亚烷基的形式连接,其中p为2至6的整数。本发明还包括下式的全氟脂族取代​​的氨基醇和式IV的产物的混合物与IN R1,R3和Q具有与上述相同的含义及其中 n为4〜20的整数。

    Fluorocarbon oil-repellency agents
    49.
    发明授权
    Fluorocarbon oil-repellency agents 失效
    氟油代用品

    公开(公告)号:US3576019A

    公开(公告)日:1971-04-20

    申请号:US3576019D

    申请日:1968-08-01

    申请人: ALLIED CHEM

    IPC分类号: D06M13/408 C09F7/00

    CPC分类号: D06M13/408 Y10T442/2172

    摘要: FLUORINATED AMIDE OIL-REPELLENCY AGENTS FOR FIBROUS MATERIALS AS TEXTILES AND PAPER HAVE THE STRUCTURAL FORMULA

    R5-CO-NH-(CXH2X-N(-Z''))Y-CXH2X-NH-Z

    WHEREIN RF IS A FLUORINE-CONTAINING ALKYL RADICAL HAVING A TERMINAL FLUOROISOALKOXYFLUOROALKYL GROUP; X A AND Y ARE INTEGERS FROM 2 TO 6 AND 1 TO 4, RESPECTIVELY; Z IS H, ALKYL, HYDROXYALKYL OR AN ACYL RADICAL OF THE FORMULA -CORF WHEREIN RF IS A DESCRIBED ABOVE; AND Z'' IS H, ALKYL, HYDROXYALKYL, THE ABOVE-DESCRIBED ACYL RADICAL OR A RADICAL OF THE FORMUAL -CXH2XNHZ WHEREIN Z IS AS DESCRIBED ABOVE.