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378 条记录 (耗时 0.018 秒)

    Oxidation catalyst and process
    51.
    发明授权
    Oxidation catalyst and process 失效
    氧化催化剂和工艺

    公开(公告)号：US4042531A

    公开(公告)日：1977-08-16

    申请号：US736564

    申请日：1976-10-28

    申请人： Ellis K. Fields

    发明人： Ellis K. Fields

    IPC分类号： B01J27/08 ,  B01J27/24 ,  B01J27/25 ,  C07C2/84 ,  C07C5/48 ,  C07C29/50 ,  C07C45/36 ,  C07C51/265

    CPC分类号： C07C5/48 ,  B01J27/08 ,  B01J27/24 ,  B01J27/25 ,  C07C2/84 ,  C07C29/50 ,  C07C45/36 ,  C07C51/265 ,  C07C2527/122 ,  C07C2527/132 ,  C07C2527/24

    摘要： This invention relates to a new catalyst and to a novel oxidation process. In this novel process, aromatic compounds with an alkyl group having at least one alpha hydrogen, including aromatic compounds wherein the alkyl groups are unsubstituted and substituted, are contacted in the liquid phase at reaction conditions with an oxygen-containing gas in the presence of a novel catalyst which is prepared by milling an anhydrous transition metal halide with silver nitrite, the transition metal being selected from the Groups IVb to VIII and Ib and IIb of the Periodic Table, wherein the mole ratios of metal halide to silver nitrite are in the ratio of 1:1 to 1:5.

    摘要翻译： 本发明涉及新的催化剂和新的氧化方法。 在该新方法中，具有至少一个α氢的芳基化合物，包括其中烷基未被取代和取代的芳族化合物在反应条件下与含氧气体在液相中在存在下接触 通过用亚硝酸银研磨无水过渡金属卤化物制备的新型催化剂，过渡金属选自元素周期表第IVb至VIII族和Ib和IIb族，其中金属卤化物与亚硝酸银的摩尔比为 为1：1至1：5。

    Hydroprocessing aromatics to make cycloparaffins
    53.
    发明授权
    Hydroprocessing aromatics to make cycloparaffins 失效
    加氢处理芳烃以制备环烷烃

    公开(公告)号：US3992464A

    公开(公告)日：1976-11-16

    申请号：US648544

    申请日：1976-01-12

    申请人： Ernest L. Pollitzer ,  John C. Hayes

    发明人： Ernest L. Pollitzer ,  John C. Hayes

    IPC分类号： B01J23/89 ,  B01J27/08 ,  C07C5/10 ,  C10G35/09 ,  C10G47/14 ,  B01J23/62 ,  C10G13/04

    CPC分类号： B01J27/08 ,  B01J23/8966 ,  C07C5/10 ,  C10G35/09 ,  C10G47/14 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/40 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/89

    摘要： A process for hydrotreating (hydroprocessing) hydrocarbons and mixtures of hydrocarbons utilizing a catalytic composite comprising a porous carrier material containing, on an elemental basis, about 0.01 to about 2 wt. % platinum group metal, about 0.5 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % tin and about 0.1 to about 3.5 wt. % halogen, wherein the platinum group metal, cobalt and tin are uniformly dispersed throughout the porous carrier material, wherein substantially all of the platinum group metal is present in the elemental metallic state, wherein substantially all of the tin is present in an oxidation state above that of the elemental metal, and wherein substantially all of the cobalt is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions, in which process there is effected a chemical consumption of hydrogen. A specific example of one such catalyst is a composite of a crystalline aluminosilicate, a platinum group metal component, a cobalt component, a tin component, and a halogen component, for utilization in a hydrocracking process. Other hydrocarbon hydroprocesses are directed toward the hydrogenation of aromatic nuclei, the ring-opening of cyclic hydrocarbons, hydrogenation, etc.

    摘要翻译： 使用包含多孔载体材料的催化复合物加氢处理（加氢处理）烃和烃的混合物的方法，该多孔载体材料在元素基础上含有约0.01至约2wt。 ％铂族金属，约0.5至约5wt。 ％钴，约0.01至约5wt。 ％锡和约0.1至约3.5重量％ ％卤素，其中铂族金属，钴和锡均匀分散在整个多孔载体材料中，其中基本上所有的铂族金属以元素金属状态存在，其中基本上全部锡以上述氧化态存在 并且其中基本上所有的钴以元素金属状态存在，或者在碳氢化合物转化条件下可还原成元素金属状态的状态下，其中进行氢的化学消耗。 一种这样的催化剂的具体实例是结晶铝硅酸盐，铂族金属组分，钴组分，锡组分和卤素组分的复合物，用于加氢裂化方法。 其他烃类加氢工艺涉及芳烃氢化，环状烃开环，氢化等。

    Catalyst containing a Lewis acid intercalated in graphite
    55.
    发明授权
    Catalyst containing a Lewis acid intercalated in graphite 失效
    含有插入石墨的路易斯酸的催化剂

    公开(公告)号：US3984352A

    公开(公告)日：1976-10-05

    申请号：US554868

    申请日：1975-03-03

    申请人： Paul Gerhard Rodewald

    发明人： Paul Gerhard Rodewald

    IPC分类号： B01J27/08 ,  B01J27/02 ,  B01J27/10 ,  B01J27/12

    CPC分类号： B01J27/08 ,  C07C2101/08 ,  C07C2523/42 ,  C07C2527/126 ,  C07C2527/133 ,  Y02P20/582

    摘要： Hydrocarbon conversion is effected in the presence of a catalyst consisting essentially of graphite having intercalated in the lattice thereof between about 5 and about 75 weight percent of a Lewis acid. The catalyst may additionally have intercalated therein a minor proportion of a Bronsted acid and/or a Group VI-B or Group VIII metal. The catalyst of graphite having the specified components intercalated in its structure is shown to be much more effective in hydrocarbon conversion, e.g. isomerization, than catalysts having said components deposited on the surface of the graphite.

    摘要翻译： 烃转化在催化剂存在下进行，所述催化剂基本上由在其格子中插入约5至约75重量％的路易斯酸之间的石墨组成。 催化剂还可以在其中插入少量的布朗斯台德酸和/或VI-B族或VIII族金属。 具有插入其结构中的特定组分的石墨催化剂显示在烃转化中更有效，例如。 异构化，比具有沉积在石墨表面上的所述组分的催化剂。

    Process for producing aromatic carboxylic acid
    56.
    发明授权
    Process for producing aromatic carboxylic acid 失效
    芳香族羧酸的制造方法

    公开(公告)号：US3970696A

    公开(公告)日：1976-07-20

    申请号：US492796

    申请日：1974-07-29

    申请人： Motoo Shigeyasu ,  Michio Kuki

    发明人： Motoo Shigeyasu ,  Michio Kuki

    IPC分类号： B01J27/00 ,  B01J27/08 ,  B01J31/04 ,  B01J31/26 ,  B01J37/22 ,  C07C51/00 ,  C07C51/265 ,  C07C63/26 ,  C07C67/00 ,  C07C51/33

    CPC分类号： B01J31/26 ,  B01J27/08 ,  B01J31/04 ,  B01J37/22 ,  C07C51/265 ,  B01J2231/70

    摘要： A process for producing an aromatic carboxylic acid by liquid-phase oxidizing an alkylbenzene with a molecular oxygen-containing gas in a lower aliphatic carboxylic acid solvent in the presence of a heavy-metal-bromine oxidation catalyst, in which the oxidation reaction is conducted using a material containing as inorganic elements only cobalt, manganese, and bromine as the catalyst components and while withdrawing from the reaction system, at least partially, the condensed liquid of a gaseous mixture discharged from the top of the reactor during the reaction and maintaining the water content of the reaction system below a definite level by introducing fresh solvent (or, preferably, the solvent recovered as a side cut fraction by distilling the condensed liquid) in an amount corresponding to the amount of the solvent withdrawn contained in the condensed liquid, and a reaction mother liquor which is formed by separating the aromatic carboxylic acid from the reaction mixture withdrawn from the reactor is recycled, as it is, to the reactor for reuse in the oxidation reaction.

    摘要翻译： 在重金属 - 溴氧化催化剂存在下，通过在低级脂肪族羧酸溶剂中用含氧分子氧气体将烷基苯进行液相氧化生产芳族羧酸的方法，其中使用 当作为催化剂成分含有仅作为钴，锰和溴的无机元素的材料，并且在反应期间至少部分地从反应器顶部排出的气态混合物的冷凝液体从反应体系中排出并维持水 通过引入新鲜溶剂（或优选地，通过蒸馏冷凝液作为侧馏分回收的溶剂）以相当于冷凝液中所含的溶剂量的量的量将反应体系的含量降低到一定水平，以及 通过从引入的反应混合物中分离出芳族羧酸形成的反应母液 反应器原样循环到反应器中，以便在氧化反应中重新使用。

    Hydrocarbon conversion with a multimetallic catalytic composite
    57.
    发明授权
    Hydrocarbon conversion with a multimetallic catalytic composite 失效

    公开(公告)号：US3900387A

    公开(公告)日：1975-08-19

    申请号：US43630574

    申请日：1974-01-24

    申请人： UNIVERSAL OIL PROD CO

    发明人： WILHELM FREDERICK C

    IPC分类号： B01J23/644 ,  B01J27/08 ,  C10G35/09 ,  C10G35/08 ,  B01J11/78 ,  C07C5/28

    CPC分类号： B01J27/08 ,  B01J23/6447 ,  C10G35/09

    摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with a trimetallic acidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a Group IVA component, a bismuth component and a halogen component with a porous carrier material. The platinum group component, Group IVA metallic component, a halogen component are present in the trimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % Group IVA metal and about 0.1 to about 3.5 wt. % halogen. The bismuth component is present in amounts corresponding to an atomic ratio of bismuth to platinum group metal of about 0.1:1 to about 1:1. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal and bismuth components are present therein in the corresponding elemental metallic states while substantially all of the Group IVA metallic component is present therein in an oxidation state above that of the corresponding metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and hydrogen stream are contacted with the novel trimetallic catalyst disclosed herein at reforming conditions.

    Process for the production of fiber grade terephthalic acid
    59.
    发明授权
    Process for the production of fiber grade terephthalic acid 失效
    生产纤维级联过硫酸的方法

    公开(公告)号：US3846487A

    公开(公告)日：1974-11-05

    申请号：US19446871

    申请日：1971-11-01

    申请人： MARUZEN OIL CO LTD

    发明人： SHIGEYASU M ,  KUIHARA K ,  KUKI M

    IPC分类号： B01J19/08 ,  B01J27/08 ,  B01J27/128 ,  B01J31/04 ,  B01J37/04 ,  C07C51/265 ,  C07C63/26 ,  C07C51/20

    CPC分类号： B01J37/04 ,  B01J19/088 ,  B01J27/08 ,  B01J27/128 ,  B01J31/04 ,  B01J2231/70 ,  B01J2531/72 ,  B01J2531/845 ,  C07C51/265 ,  Y02P20/52 ,  C07C63/26

    摘要： A process for producing fiber grade terephthalic acid by subjecting p-xylene to a liquid phase oxidation with oxygen or an oxygen-containing gas in the presence of an oxidation catalyst comprising cobalt, manganese and bromine and in the presence of a lower aliphatic carboxylic acid solvent, said catalyst comprising: (a) the amount of cobalt is in the range of 0.05 0.50 percent by weight based on the solvent, (b) the amount of the manganese is in the range of 1 - 20 percent by weight based on cobalt, (c) the source of bromine is cobalt bromide, free bromine, or a mixture thereof, and (d) the weight ratio of bromine to cobalt is in the range of 1.5:1 - 6.0: 1. Terephthalic acid thus obtained can be used as a raw material of direct polymerization with glycols for providing high quality polyester.

    摘要翻译： 一种在含有钴，锰和溴的氧化催化剂存在下，在低级脂族羧酸溶剂存在下，用氧或含氧气体对对二甲苯进行液相氧化生产纤维级对苯二甲酸的方法 ，所述催化剂包括：（a）钴的用量相对于溶剂为0.05-0.50％（重量），（b）锰的量为1-20％（重量），基于钴 ，（c）溴源是溴化钴，游离溴或其混合物，（d）溴与钴的重量比在1.5:1至6.0:1的范围内。如此获得的对苯二甲酸可以是 用作直接聚合的二醇用于提供高品质聚酯的原料。