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    HONEYCOMB STRUCTURE
    55.
    发明申请
    HONEYCOMB STRUCTURE 审中-公开
    蜂窝结构

    公开(公告)号：US20150273446A1

    公开(公告)日：2015-10-01

    申请号：US14433023

    申请日：2012-10-03

    申请人： IBIDEN CO., LTD.

    发明人： Masafumi Kunieda ,  Serika Murakoshi

    IPC分类号： B01J29/00 ,  B01J35/04

    CPC分类号： B01J29/005 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2258/012 ,  B01J23/06 ,  B01J29/7015 ,  B01J29/763 ,  B01J29/85 ,  B01J35/04 ,  B01J37/0018 ,  B01J2229/186 ,  B01J2229/42

    摘要： Provided is a honeycomb structure which is suppressed in the occurrence of cracks and hydration degradation, while maintaining excellent NOx removal performance of SAPO. A honeycomb structure having a honeycomb unit that comprises two zeolite species and an inorganic binder, and that has a plurality of through holes arranged side by side with a partition wall therebetween to be extended in the longitudinal direction of the unit. This honeycomb structure is characterized in that one of the two zeolite species is silicoaluminophosphate (SAPO) having a composition ratio Si/(Si+Al+P) of 0.1-0.25, and the other is aluminosilicate (CHA) having a composition ratio Si/Al of 2-10.

    摘要翻译： 提供了抑制SAPO的优异的NOx去除性能的蜂窝结构体，其在发生裂纹和水化降解的同时被抑制。 一种具有蜂窝单元的蜂窝结构体，其包含两种沸石种类和无机粘合剂，并且具有并排布置的多个通孔，其间具有分隔壁，以在所述单元的纵向延伸。 该蜂窝结构体的特征在于，两种沸石种类之一是Si /（Si + Al + P）的组成比为0.1-0.25的硅铝磷酸盐（SAPO），另一种为硅/硅酸盐（CHA），其组成比为Si / Al 2-10。

    Process For The Preparation Of Zeolites Having CHA Structure
    58.
    发明申请
    Process For The Preparation Of Zeolites Having CHA Structure 有权
    具有CHA结构的沸石的制备方法

    公开(公告)号：US20150132215A1

    公开(公告)日：2015-05-14

    申请号：US14534642

    申请日：2014-11-06

    申请人： BASF SE

    发明人： Ivor Bull ,  Ulrich Müller

    IPC分类号： B01J29/76 ,  B01D53/94 ,  C01B39/48

    CPC分类号： B01J29/763 ,  B01D53/9418 ,  B01D2251/2067 ,  B01D2253/108 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2258/012 ,  B01J29/7015 ,  B01J35/04 ,  B01J37/0246 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/46 ,  C01B39/48 ,  Y02C20/10 ,  Y02P20/153

    摘要： The present invention relates to a process for the preparation of zeolites having CHA framework structure and a composition comprising the molar ratio (n SiO2):X2O3, wherein X is a trivalent element, and wherein n is at least 10, the process comprising (i) preparation of an aqueous solution containing at least one source for X2O3, wherein X is selected from Al, B, Ga, and a mixture of two or more, and at least one source for SiO2, at least one organic structure directing agent (SDA) other than Tetramethylammonium hydroxide (TMAOH), acting as a template for the CHA structure, and Tetramethylammonium hydroxide (TMAOH), wherein the SDA or mixtures thereof are employed in such amounts that the aqueous solution in (i) exhibits a molar ratio of SDA:TMAOH of 0.01 to 5; (ii) hydrothermal crystallization of the aqueous solution according to (i); wherein the aqueous solution of (i) contains copper in an amount less than 0.005 Cu: ((n YO2)+X2O3) where n is in the range of 10 to 50. The present invention also relates to the zeolitic materials obtainable and/or obtained by this process as well as to a zeolitic material as such, having framework structure CHA, having a composition comprising the molar ratio (n SiO2):X2O3, wherein X is a trivalent element and n is at least 10, and wherein the crystal size, as determined from Scanning Electron Microscopy, is greater than 1 micrometer and wherein the chabazite framework is phase-pure having an impurity of other zeolitic frameworks, such as RUT as determined by X-ray Diffraction, of less than 5%.

    摘要翻译： 本发明涉及一种制备具有CHA骨架结构的沸石和包含摩尔比（n SiO 2）：X 2 O 3的组合物的方法，其中X是三价元素，并且其中n至少为10，该方法包括（i ）制备含有至少一种X 2 O 3的源的水溶液，其中X选自Al，B，Ga，以及两种或更多种的混合物和至少一种SiO 2源，至少一种有机结构导向剂（SDA ），作为CHA结构的模板的四甲基氢氧化铵（TMAOH）和氢氧化四甲基铵（TMAOH），其中SDA或其混合物的使用量使得（i）中的水溶液表现出的摩尔比为SDA ：TMAOH为0.01〜5; （ii）根据（i）的水溶液的水热结晶; 其中（i）的水溶液含有小于0.005 Cu：（（n YO 2）+ X 2 O 3）的铜，其中n在10至50的范围内。本发明还涉及可获得的和/或 通过该方法获得的沸石材料以及具有骨架结构CHA的沸石材料，其具有包含摩尔比（n SiO 2）：X 2 O 3的组成，其中X是三价元素，n至少为10，并且其中晶体 通过扫描电子显微镜测定的尺寸大于1微米，其中菱沸石框架是相纯的，具有小于5％的其它沸石骨架的杂质，例如通过X射线衍射测定的RUT。

    SEEDED SYNTHESIS OF ALUMINOSILICATE MOLECULAR SIEVES
    60.
    发明申请
    SEEDED SYNTHESIS OF ALUMINOSILICATE MOLECULAR SIEVES 审中-公开
    酸性分子筛的合成

    公开(公告)号：US20150118151A1

    公开(公告)日：2015-04-30

    申请号：US14065581

    申请日：2013-10-29

    申请人： Guang Cao ,  Matu J. Shah

    发明人： Guang Cao ,  Matu J. Shah

    IPC分类号： B01J29/85 ,  B01J29/70

    CPC分类号： C01B39/04 ,  B01J29/70 ,  B01J29/7015 ,  B01J29/85 ,  C01B39/02 ,  C01B39/48

    摘要： A process for producing an aluminosilicate molecular sieve comprises crystallizing a reaction mixture comprising water, a source of silica and seeds of a silicoaluminophosphate and/or an aluminophosphate molecular sieve. The resultant aluminosilicate molecular sieve product can advantageously be substantially free of framework phosphorus.

    摘要翻译： 制备硅铝酸盐分子筛的方法包括使包含水，二氧化硅源和硅铝磷酸盐和/或磷酸铝分子筛的种子的反应混合物结晶。 所得的铝硅酸盐分子筛产物可以有利地基本上不含骨架磷。