LUBRICANTS COMPRISING CARBON PARTICLES AND METHODS OF MAKING THE SAME
    52.
    发明申请
    LUBRICANTS COMPRISING CARBON PARTICLES AND METHODS OF MAKING THE SAME 审中-公开
    包含碳粒子的润滑剂及其制备方法

    公开(公告)号:US20160289586A1

    公开(公告)日:2016-10-06

    申请号:US15085256

    申请日:2016-03-30

    IPC分类号: C10M125/02 C10M125/22

    摘要: A lubricant includes carbon particles in a carrier. The carbon particles may be nearly spherical, individually have maximum and minimum diameters that differ by no more than ten nanometers, and the maximum diameters of the carbon particles are less than one micrometer. The lubricant may be manufactured by preparing the carbon particles by ultrasound-assisted polymerization of resorcinol and formaldehyde in an aqueous system followed by a heat treatment in an inert or non-oxidizing atmosphere and dispersion of the carbon particles in the liquid hydrocarbon carrier to form the lubricant. Optionally, inorganic metals, alloys, or oxides are coated on the surface of the carbon particles via an additional thermolysis step.

    摘要翻译: 润滑剂包括载体中的碳颗粒。 碳颗粒可以接近球形,单独具有不超过10纳米的最大和最小直径,并且碳颗粒的最大直径小于1微米。 可以通过在水性体系中通过间苯二酚和甲醛的超声辅助聚合制备碳颗粒,然后在惰性或非氧化性气氛中进行热处理并且将碳颗粒分散在液体烃载体中形成润滑剂来制备润滑剂, 润滑剂。 任选地,通过额外的热解步骤将无机金属,合金或氧化物涂覆在碳颗粒的表面上。

    ESTER COMPOUNDS INCLUDING TRIESTERS HAVING TERMINAL VICINAL ACYL GROUPS
    53.
    发明申请
    ESTER COMPOUNDS INCLUDING TRIESTERS HAVING TERMINAL VICINAL ACYL GROUPS 审中-公开
    具有终端乙酸酯基团的酯的酯化合物

    公开(公告)号:US20160280631A1

    公开(公告)日:2016-09-29

    申请号:US15073540

    申请日:2016-03-17

    发明人: Jeremy FOREST

    摘要: Provided herein are certain esters, including those of the Formula I: wherein z is an integer selected from 0 to 15; R1, independently for each occurrence, is an optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Hydroxy compounds are also described herein, which may be suitable end products, or serve as intermediates, to provide the desired ester products. Also described are compositions containing certain esters (e.g., triesters) and methods of making such esters and compositions thereof.

    摘要翻译: 其中z是选自0至15的整数; R1各自独立地为任选被取代的烷基,其为饱和或不饱和的,支链或非支链的; 并且R 2选自氢和任选取代的饱和或不饱和的烷基,并且是支链或非支链的。 本文还描述了羟基化合物,其可以是合适的终产物,或用作中间体以提供所需的酯产物。 还描述了含有某些酯(例如三酯)的组合物和制备这些酯及其组合物的方法。

    Lubrication with oil-compatible polymer brushes
    54.
    发明授权
    Lubrication with oil-compatible polymer brushes 有权
    润滑与油相容的聚合物刷

    公开(公告)号:US09441177B2

    公开(公告)日:2016-09-13

    申请号:US14113448

    申请日:2012-04-03

    摘要: A polymer-brush-based, surface-modification strategy for friction and wear reduction in hard contact under boundary-lubrication conditions is proposed, specifically for a non-aqueous environment. Surface-initiated Atom Transfer Radical Polymerization (SI-ATRP) was employed for the synthesis of three different oil-compatible, hydrophobic polymer brushes based on alkyl methacrylates. This study presents polymerization kinetics, chemical characterization by means of Fourier transform infrared spectroscopy (FTIR) and surface morphologies observed in atomic force microscopy (AFM). The lubrication properties of the anchored polymers were evaluated macroscopically by means of ball-on-disk methods and on the nanonewton scale by lateral force microscopy (AFM/LFM) and showed significant reduction in friction up to contact pressures as high as 460 MPa. The frictional response of surface-grafted polymers is shown to depend strongly on the compatibility of the polymer with the chosen lubricating fluid. Their good tribological performances have also been proven with watchmaking lubricants. These results do make the prevent invention a suitable candidate for a watchmaking application (such as at the balance pivot or the escapement) in order to increase the efficiency and reliability of the movements.

    摘要翻译: 提出了一种基于聚合物刷的表面改性策略,用于在边界润滑条件下硬接触的摩擦和磨损降低,特别适用于非水环境。 表面引发的原子转移自由基聚合(SI-ATRP)用于合成基于甲基丙烯酸烷基酯的三种不同的油相容性疏水性聚合物刷。 本研究通过傅立叶变换红外光谱(FTIR)和原子力显微镜(AFM)观察到的表面形态,提出了聚合动力学,化学特征。 锚定聚合物的润滑性能通过球盘法和纳米级尺度横向力显微镜(AFM / LFM)进行宏观评估,并显示高达460MPa的接触压力下的摩擦力显着降低。 显示表面接枝聚合物的摩擦响应强烈依赖于聚合物与所选择的润滑流体的相容性。 他们的良好的摩擦学性能也被制表润滑剂证明。 这些结果确实使得防止发明成为制表应用(例如平衡枢轴或擒纵机构)的合适候选者,以便提高运动的效率和可靠性。

    PROCESS TO PREPARE TWO OR MORE BASE OILS
    60.
    发明申请
    PROCESS TO PREPARE TWO OR MORE BASE OILS 审中-公开
    制备两种或多种基础油的方法

    公开(公告)号:US20160177204A1

    公开(公告)日:2016-06-23

    申请号:US14904763

    申请日:2014-07-14

    申请人: SHELL OIL COMPANY

    IPC分类号: C10G69/00 C10M101/02

    摘要: The present invention provides a process to prepare two or more base oils, which process at least comprises the following steps: a) providing two or more paraffinic hydrocarbon feedstock streams; b) subjecting a first paraffinic hydrocarbon feedstock stream provided in step a) to a hydrocracking/hydroisomerization step to obtain a first at least partially isomerised product stream; c) subjecting a second paraffinic hydrocarbon feedstock stream provided in step a) to a hydrocracking/hydroisomerization step to obtain a second at least partially isomerised product stream; d) separating the first product stream of step b), thereby obtaining a first lower boiling fraction and a first higher boiling fraction; e) separating the second product stream of step c), thereby obtaining a second lower boiling fraction and a second higher boiling fraction; f) combining the first lower boiling fraction of step d) with the second lower boiling fraction of step e) thereby obtaining a combined lower boiling fraction; g) combining the first higher boiling fraction of step d) with the second higher boiling fraction of step e) thereby obtaining a combined higher boiling fraction; h) dewaxing the combined lower boiling fraction of step f) to obtain a lightbase oil; and i) dewaxing the combined higher boiling fraction of step g) to obtain a heavy base oil.

    摘要翻译: 本发明提供一种制备两种或更多种基础油的方法,该方法至少包括以下步骤:a)提供两种或多种链烷烃原料流; b)使步骤a)中提供的第一链烷烃原料流进行加氢裂化/加氢异构化步骤以获得第一至少部分异构化的产物流; c)使步骤a)中提供的第二链烷烃原料流进行加氢裂化/加氢异构化步骤以获得第二至少部分异构化的产物流; d)分离步骤b)的第一产物流,从而获得第一较低沸点馏分和第一较高沸点馏分; e)分离步骤c)的第二产物流,从而获得第二低沸点馏分和第二较高沸点馏分; f)将步骤d)的第一低沸点馏分与步骤e)的第二较低沸点馏分组合,从而获得组合的较低沸点馏分; g)将步骤d)的第一较高沸点馏分与步骤e)的第二较高沸点馏分组合,从而获得组合较高沸点馏分; h)将步骤f)的组合较低沸点馏分脱蜡得到浅基油; 和i)将步骤g)的组合较高沸点馏分脱蜡得到重质基础油。