公开(公告)号：US09932680B2

公开(公告)日：2018-04-03

申请号：US15473346

申请日：2017-03-29

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Jeffrey M. Sullivan

IPC: C08G63/48 ,  C08F2/00 ,  C08F118/02 ,  C25B3/10 ,  C08K3/04 ,  C08L35/02 ,  C08K3/36 ,  C25B9/04 ,  C25B9/06

CPC classification number: C25B3/10 ,  C08F2/38 ,  C08F2/44 ,  C08F2/58 ,  C08F20/16 ,  C08K3/04 ,  C08K3/36 ,  C08K5/42 ,  C08L35/02 ,  C08L2201/10 ,  C09J4/00 ,  C25B9/04 ,  C25B9/06

Abstract: Electropolymerizable systems are disclosed. The electropolymerizable systems include an electropolymerizable composition including one or more 1,1-disubstituted alkene compounds and one or more conductive synergists.

公开(公告)号：US09890227B1

公开(公告)日：2018-02-13

申请号：US15783181

申请日：2017-10-13

Applicant: SIRRUS, INC.

Inventor： Jeffrey M. Sullivan ,  Aniruddha Palsule ,  Alexander R. Holzer ,  Kshitij K. Parab ,  Ami Doshi

IPC: C08F22/10 ,  C08F2/06 ,  C08F222/14 ,  C07C69/593 ,  C09J125/02 ,  C09J135/02

CPC classification number: C08F22/10 ,  C07C69/593 ,  C08F2/06 ,  C08F222/14 ,  C09J135/02

Abstract: The disclosure relates to compositions containing 1,1-di-substituted alkene compounds capable of preparing polymers having glass transition temperatures above room temperature. The present teaching also relates to polymers prepared 1,1-di-substituted alkene compounds which exhibit glass transition temperatures of 60° C. The disclosure also relate to methods for enhancing the glass transition temperatures of polymers prepared from 1,1-di-substituted alkene compounds.

公开(公告)号：US20180037681A1

公开(公告)日：2018-02-08

申请号：US15783181

申请日：2017-10-13

Applicant: SIRRUS, INC.

Inventor： Jeffrey M. Sullivan ,  Aniruddha Palsule ,  Alexander R. Holzer ,  Kshitij K. Parab ,  Ami Doshi

IPC: C08F22/10 ,  C08F222/14 ,  C08F2/06 ,  C09J135/02 ,  C07C69/593

CPC classification number: C08F22/10 ,  C07C69/593 ,  C08F2/06 ,  C08F222/14 ,  C09J135/02

Abstract: The disclosure relates to compositions containing 1,1-disubstituted alkene compounds capable of preparing polymers having glass transition temperatures above room temperature. The present teaching also relates to polymers prepared 1,1-disubstituted alkene compounds which exhibit glass transition temperatures of 60° C. The disclosure also relate to methods for enhancing the glass transition temperatures of polymers prepared from 1,1-disubstituted alkene compounds.

公开(公告)号：US20170349701A1

公开(公告)日：2017-12-07

申请号：US15610854

申请日：2017-06-01

Applicant: Sirrus, Inc.

Inventor： Jeffrey M. Sullivan ,  Ami Doshi

IPC: C08G63/52

CPC classification number: C08G63/52 ,  B32B27/36 ,  C09D151/08 ,  C12P7/625

Abstract: Disclosed are graft copolymers, compositions including graft copolymers, intermediate materials, and related methods, where the graft copolymer includes a first polymer component including a 1,1-disubstituted-1-alkene compound (preferably a methylene malonate compound) and is grafted to a second component. The resulting graft copolymer may be hydrophilic or water soluble. The second component preferably is a hydrophilic component.

公开(公告)号：US09718989B1

公开(公告)日：2017-08-01

申请号：US15410003

申请日：2017-01-19

Applicant: SIRRUS, INC.

Inventor： Aniruddha S. Palsule ,  Jeffrey M. Sullivan ,  Katherine E. Vanderpool ,  Alexander R. Holzer ,  Anushree Deshpande ,  John Klier

IPC: C09D167/06 ,  C08L67/06 ,  C08G63/52 ,  C08G63/00 ,  C08G63/78 ,  C12P7/62

CPC classification number: C09D167/06 ,  C08G63/00 ,  C08G63/553 ,  C08G63/676 ,  C08G63/78 ,  C08L67/06 ,  C09D133/06 ,  C09D167/02 ,  C12P7/625 ,  C08L83/04 ,  C08L79/02

Abstract: Compositions comprising a) one or more polyester macromers containing one or more chains of the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols; and b) one or more polymers having pendant Michael Addition donor groups. Disclosed are coating prepared from these compositions.

公开(公告)号：US20170204524A1

公开(公告)日：2017-07-20

申请号：US15473346

申请日：2017-03-29

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Jeffrey M. Sullivan

IPC: C25B3/10 ,  C25B9/06 ,  C08K3/36 ,  C25B9/04 ,  C08K3/04 ,  C08L35/02

CPC classification number: C25B3/10 ,  C08F2/38 ,  C08F2/44 ,  C08F2/58 ,  C08F20/16 ,  C08K3/04 ,  C08K3/36 ,  C08K5/42 ,  C08L35/02 ,  C08L2201/10 ,  C09J4/00 ,  C25B9/04 ,  C25B9/06

Abstract: Electropolymerizable systems are disclosed. The electropolymerizable systems include an electropolymerizable composition including one or more 1,1-disubstituted alkene compounds and one or more conductive synergists.

公开(公告)号：US20170198181A1

公开(公告)日：2017-07-13

申请号：US15467597

申请日：2017-03-23

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Alexander R. Holzer ,  Aniruddha Sudhir Palsule ,  Jeffrey M. Sullivan

IPC: C09J135/02 ,  C09J11/08 ,  C09J11/06 ,  C09D135/02 ,  C09D7/12

CPC classification number: C08F2/26 ,  B01J19/10 ,  B01J19/18 ,  C08F2/30 ,  C08F22/10 ,  C08F122/14 ,  C08F267/06 ,  C08J3/07 ,  C08K5/103 ,  C08K5/1535 ,  C08K5/42 ,  C09D7/63 ,  C09D7/65 ,  C09D135/02 ,  C09J11/06 ,  C09J11/08 ,  C09J135/02

Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.

公开(公告)号：US20170190807A1

公开(公告)日：2017-07-06

申请号：US15467330

申请日：2017-03-23

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Alexander R. Holzer ,  Aniruddha Sudhir Palsule ,  Jeffrey M. Sullivan

IPC: C08F2/26 ,  C08F267/06 ,  C08F122/14

CPC classification number: C09J135/02 ,  B01J19/10 ,  B01J19/18 ,  C08F2/26 ,  C08F2/30 ,  C08F22/10 ,  C08F122/14 ,  C08F267/06 ,  C08J3/07 ,  C08K5/103 ,  C08K5/1535 ,  C08K5/42 ,  C09D7/63 ,  C09D7/65 ,  C09D135/02 ,  C09J11/06 ,  C09J11/08

Abstract: The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.

公开(公告)号：US09617354B2

公开(公告)日：2017-04-11

申请号：US14948734

申请日：2015-11-23

Applicant: Sirrus, Inc.

Inventor： Peter Rulon Stevenson ,  Jeffrey M. Sullivan

IPC: C08G63/48 ,  C08F2/00 ,  C08F118/02 ,  C08F2/58 ,  C08F2/38 ,  C08F2/44 ,  C08L35/02 ,  C08K3/04 ,  C09J4/00

CPC classification number: C25B3/10 ,  C08F2/38 ,  C08F2/44 ,  C08F2/58 ,  C08F20/16 ,  C08K3/04 ,  C08K3/36 ,  C08K5/42 ,  C08L35/02 ,  C08L2201/10 ,  C09J4/00 ,  C25B9/04 ,  C25B9/06

Abstract: Electropolymerizable compositions are disclosed. Certain electropolymerizable compositions include one or more 1,1-disubstituted alkene compounds and one or more conductive synergists. Other certain electropolymerizable compositions include one or more 1,1-disubstituted alkene compounds and one or more acid stabilizers and one or more free radical stabilizers.

公开(公告)号：US20170073438A1

公开(公告)日：2017-03-16

申请号：US15363169

申请日：2016-11-29

Applicant: SIRRUS, INC.

Inventor： Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan

IPC: C08F20/28 ,  C09J133/16 ,  C08L33/16 ,  C08L21/00 ,  C09D133/14 ,  C09J133/14 ,  C08L33/14 ,  C08F20/30 ,  C08F20/38 ,  C09D135/02 ,  C09J135/02 ,  C08L35/02 ,  C08F22/20 ,  C08K3/00 ,  C08K5/00 ,  C09D133/16

CPC classification number: C08F20/28 ,  C07C45/75 ,  C07C49/794 ,  C07C49/796 ,  C07C49/798 ,  C07C49/80 ,  C07C67/03 ,  C07C67/30 ,  C07C69/604 ,  C07C69/738 ,  C07C2601/14 ,  C07D307/46 ,  C07D307/54 ,  C07D333/22 ,  C07D333/24 ,  C08F20/14 ,  C08F20/30 ,  C08F20/38 ,  C08F20/68 ,  C08F22/20 ,  C08F24/00 ,  C08F28/06 ,  C08F116/36 ,  C08F128/06 ,  C08F222/1006 ,  C08F222/14 ,  C08K3/013 ,  C08K5/0008 ,  C08L21/00 ,  C08L33/14 ,  C08L33/16 ,  C08L35/02 ,  C09D4/00 ,  C09D129/12 ,  C09D133/14 ,  C09D133/16 ,  C09D135/02 ,  C09D141/00 ,  C09J133/06 ,  C09J133/14 ,  C09J133/16 ,  C09J135/02 ,  Y02P20/127 ,  C07C69/593

Abstract: The present invention provides methylene beta-ketoester monomers, methods for producing the same, and compositions and products formed therefrom. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester is reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to further processing, which may be vaporization by contact with an energy transfer means in order to isolate the beta-ketoester monomer. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

Abstract translation: 本发明提供亚甲基β-酮酯单体，其制备方法，以及由其形成的组合物和产品。 在制备本发明的亚甲基β-酮酯的方法中，β-酮酯与改性的Knoevenagel反应中的甲醛源反应，任选地在酸性或碱性催化剂存在下，任选地在酸性或碱性 非酸性溶剂，形成反应络合物。 反应络合物可以是低聚物。 将反应复合物进行进一步处理，其可以通过与能量转移装置接触而蒸发，以分离β-酮酯单体。 本发明还包括由本发明的亚甲基β-酮酯单体形成的组合物和产品，包括基于单体的产品（例如油墨，粘合剂，涂料，密封剂或反应性模塑）和基于聚合物的产品（例如纤维，薄膜，片材 ，医用聚合物，复合聚合物和表面活性剂）。