摘要:
An α-sialon which is represented by general formula: (M1)x (M2)y (Si, Al)12 (O, N)16 (wherein M1 represents one or more elements selected from the group which consists of Li, Mg, Ca, Y and lanthanoid (except La and Ce) and M2 represents one or more elements selected from the group which consists of Ce, Pr, Eu, Tb, Yb and Er and wherein 0.3
摘要:
The invention relates to a process for the preparation, by nitriding, of a refractory powder containing more than 40% of silicon nitride from spent contact masses issuing from chlorosilane synthesis. The process involves mixing with the copper-free spent mass, silicon or a silicon-rich alloy and optionally a refractory compound to adjust the non-oxidised silicon content to a predetermined value >30%, heating the mixture in a nitrogen atmosphere to trigger the exothermic nitriding reaction, then reducing the product obtained to powder. The refractory powder thus obtained can be mixed with an organic binder to produce taphole blocking masses for blast furnaces or electric furnaces for pyrometallurgy.
摘要:
A process for using nitride-containing aluminum dross residues to produce refractory products. The process involves mixing a dross residue which contains AlN, without prior conversion of the aluminum nitride in the dross to aluminum oxide or hydroxide, with a material comprising a metal oxide or a metal oxide precursor, and calcining the resulting mixture at a temperature suitable to produce a refractory product. During the calcination step, the AlN reacts with other components of the mixture. Since the reaction is exothermic, less heat is required for the calcination step than if a dross residue containing no AlN were used. The AlN can also reduce various contaminants (e.g. Fe.sub.2 O.sub.3, silicon and titanium) present in the metal oxide refractories, and so the invention can be used to produce conventional refractory products of improved purity and appearance. The process enables dross residues to be used for useful purposes rather than being discarded.
摘要翻译:一种使用含氮化物的铝渣渣生产耐火产品的方法。 该方法包括混合含有AlN的渣滓残渣,而不用事先将浮渣中的氮化铝转化为氧化铝或氢氧化物,与包含金属氧化物或金属氧化物前体的材料混合,并在适于 生产耐火产品。 在煅烧步骤期间,AlN与混合物的其它组分反应。 由于反应是放热的,与使用不含AlN的浮渣残渣相比,煅烧步骤需要较少的热量。 AlN还可以减少存在于金属氧化物耐火材料中的各种污染物(例如Fe 2 O 3,硅和钛),因此本发明可用于生产具有改进的纯度和外观的常规耐火产品。 该方法使浮渣残留物用于有用的目的而不是被丢弃。
摘要:
Carbides, nitrides or carbonitrides of elements from the main groups III and IV and sub-groups III, IV, V and VI of the periodic system of elements are prepared by(i) reacting compounds of the formula MX.sub.m or R.sub.n MX.sub.m-n with a reactive hydrocarbon-containing compound or a mixture of compounds which is polymerizable and which contains a reactive compound with one C--OH-group in whichM is an element of the main group III or IV or sub-group of III, IV, V or VI of the periodic system of elements,X is a halogen,R is hydrogen or alkyl or aryl,m is an integer corresponding to the valency stage of M,n is an integer from 1 to one less than the velency stage of M, and(ii) thermally decomposing the resulting product from (i) to the corresponding carbide or to the corresponding nitrides or carbonitrides with further nitridation.
摘要:
An .alpha.-SIALON powder composed essentially of .alpha.-SIALON having the formula M.sub.x (Si,Al).sub.12 (O,N).sub.16 wherein M is at least one element selected from the group consisting of Li, Mg, Ca, Mn, Y and lanthanide metals and O
摘要:
A process for preparing aluminum nitride powder, which comprises mixing (i) aluminum hydroxide powder, (ii) carbon powder or a substance capable of forming carbon powder by heating and (iii) at least one of additives selected from the group consisting of aluminum nitride powder, silicon nitride powder, silicon carbide powder and powder of substances capable of forming the powder corresponding to these powders, and baking the mixture thus obtained in a non-oxidative atmosphere containing nitrogen. The process is useful for preparing aluminum nitride powder having small particle size and small particle size distribution and also having a uniform shape of particles, at a lower temperature and in a shorter period of time.
摘要:
A process for producing a refractory material comprising essentially beta'-SiAlON wherein initial reactants comprising Al.sub.2 O.sub.3 and SiO.sub.2 are nitrided for sufficient times and temperatures to convert at least a portion of the initial reactants to at least a portion of effective reactants and the effective reactants are then further heated to produce an essentially beta'-SiAlON refractory material.
摘要翻译:制备基本上包含Al-SiAlON的耐火材料的方法,其中将包含Al 2 O 3和SiO 2的初始反应物渗氮足够的时间和温度以将至少一部分初始反应物转化为至少一部分有效反应物,并且有效反应物为 然后进一步加热以产生基本上β'-SiAlON耐火材料。
摘要:
A method of producing a sinterable refractory material having a low coefficient of thermal expansion and comprising essentially a dispersion of aluminum oxide throughout a silicon nitride matrix, herein called SIALON. The process includes obtaining aluminum and silicon from generally readily available raw material sources.
摘要:
A ceramic material includes of β-sialon (Si(6-z)AlzOzN(8-z)), polytype 15R, an intergranular phase, and yttrium. The polytype 15R includes twin grains.
摘要:
There are provided a phosphor which is a divalent europium-activated oxynitride phosphor substantially represented by General formula (A): EuaSibAlcOdNe, a divalent europium-activated oxynitride phosphor substantially represented by General formula (B): MIfEugSihAlkOmNn or a divalent europium-activated nitride phosphor substantially represented by General formula (C): (MII1−pEup)MIIISiN3, having a reflectance of light emission in a longer wavelength region of visible light than a peak wavelength of 95% or larger, and a method of producing such phosphor; a nitride phosphor and an oxynitride phosphor which emit light efficiently and stably by the light having a wavelength ranging from 430 to 480 nm from a semiconductor light emitting device by means of a light emitting apparatus using such phosphor, and a producing method of such phosphor; and a light emitting apparatus having stable characteristics and realizing high efficiency.