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    REFORMING CATALYST AND PROCESS
    82.
    发明申请
    REFORMING CATALYST AND PROCESS 有权
    改造催化剂和工艺

    公开(公告)号：US20130015103A1

    公开(公告)日：2013-01-17

    申请号：US13184248

    申请日：2011-07-15

    Applicant: Mark Paul Lapinski ,  Paul Barger

    Inventor： Mark Paul Lapinski ,  Paul Barger

    IPC: C10G35/09 ,  B01J23/63 ,  B01J27/13 ,  B01J27/135

    CPC classification number: B01J23/63 ,  B01J23/8966 ,  B01J23/96 ,  B01J27/13 ,  B01J27/32 ,  B01J35/0026 ,  B01J35/008 ,  B01J35/08 ,  B01J37/0201 ,  C10G35/09

    Abstract: One exemplary embodiment can be a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, a lanthanide-series metal including one or more elements of atomic numbers 57-71 of the periodic table, and a support. Generally, an average bulk density of the catalyst is about 0.300-about 0.620 gram per cubic centimeter, and an atomic ratio of the lanthanide-series metal:noble metal is less than about 1.3:1. Moreover, the lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than about two times a concentration of the lanthanide-series metal at a central core of the catalyst.

    Abstract translation: 一个示例性实施方案可以是用于石脑油的催化重整的催化剂。 催化剂可以具有包括铂，钯，铑，钌，锇和铱中的一种或多种的贵金属，包括元素周期表中的一个或多个原子序数57-71的元素的镧系金属和载体。 通常，催化剂的平均体积密度为约0.300-约0.620克/立方厘米，镧系金属：贵金属的原子比小于约1.3:1。 此外，镧系元素金属可以在催化剂的100微米表面层中以镧系金属的浓度分布，其量小于催化剂中心核心处的镧系金属浓度的约两倍。

    Moving Bed Hydrocarbon Conversion Process
    85.
    发明申请
    Moving Bed Hydrocarbon Conversion Process 审中-公开
    移动床烃转化过程

    公开(公告)号：US20100152516A1

    公开(公告)日：2010-06-17

    申请号：US12332567

    申请日：2008-12-11

    Applicant: Christopher Naunheimer ,  Paul A. Sechrist

    Inventor： Christopher Naunheimer ,  Paul A. Sechrist

    IPC: C07C5/333

    CPC classification number: C10G45/66 ,  B01J8/125 ,  B01J23/58 ,  B01J23/626 ,  B01J27/13 ,  B01J29/061 ,  B01J38/10 ,  B01J38/22 ,  B01J2208/00849 ,  C07C2/76 ,  C07C5/333 ,  C10G35/12 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/584 ,  C07C11/02

    Abstract: Moving bed hydrocarbon conversion processes are provided for contacting a catalyst moving downward through a reaction zone with a hydrocarbon feed, withdrawing the catalyst from the reaction zone and conveying the catalyst to a regeneration zone wherein the catalyst moves downward. The catalyst is withdrawn from the regeneration zone and passed downward to an upper zone of a particle transfer apparatus wherein the transfer of catalyst from the upper zone through an intermediate zone to a lower zone is regulated by varying the pressure of the intermediate zone and the flow rate of gas passing through the valveless conduits. A body within the lower zone is in catalyst communication with a valveless conduit and provides more consistent catalyst flows. The catalyst from the lower zone of the particle transfer apparatus is conveyed to the reactions zone.

    Abstract translation: 提供了移动床烃转化方法，用于使向下移动通过反应区的催化剂与烃进料接触，将催化剂从反应区取出并将催化剂输送到催化剂向下移动的再生区。 催化剂从再生区抽出并向下传送到颗粒转移装置的上部区域，其中催化剂从上部区域通过中间区域转移到下部区域是通过改变中间区域和流动的压力来调节的 气体通过无阀管道的速率。 下部区域内的一个物体与无阀管道催化剂连通，并提供更一致的催化剂流。 来自颗粒转移装置的下部区域的催化剂被输送到反应区。

    METAL-RICH SILICEOUS COMPOSITIONS AND METHODS OF PRODUCING SAME
    86.
    发明申请
    METAL-RICH SILICEOUS COMPOSITIONS AND METHODS OF PRODUCING SAME 有权
    金属矿物质组合物及其生产方法

    公开(公告)号：US20100074974A1

    公开(公告)日：2010-03-25

    申请号：US12628472

    申请日：2009-12-01

    Applicant: Brian T. Holland

    Inventor： Brian T. Holland

    IPC: A61K8/25 ,  B01J23/56 ,  B01J23/44 ,  B01J21/08 ,  C09K13/00 ,  C09D1/00 ,  C07K1/14 ,  H01L21/461 ,  C12H1/048 ,  C09K8/74 ,  A61K8/00 ,  A61K8/04 ,  D21H21/00

    CPC classification number: B01J20/103 ,  B01J20/16 ,  B01J20/3236 ,  B01J23/44 ,  B01J23/66 ,  B01J23/70 ,  B01J27/13 ,  B01J29/049 ,  B01J35/0013 ,  B01J37/031 ,  B01J37/04 ,  B82Y30/00 ,  C01B33/141 ,  C01B33/151 ,  C01G55/00 ,  C01P2002/72 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14

    Abstract: A modified sol-gel method to create metal-rich siliceous material, such as colloidal silica or aluminosilicate particles is disclosed. Initially, the metal salt of choice is added to a silicic acid solution or a silicic acid solution containing aluminum salt. The aluminum is added to vary the metal-support interaction as it forms Al—O—Si linkages within the silica matrix. Besides aluminum, other metals can be added that form M—O—Si (M=Ti, B, etc.) linkages, which do not become reduced when treated with a reducing agent. Once the metal, silicic acid and/or aluminum salt is generated, it is subjected to colloidal growth by addition to a basic heel. Upon colloidal synthesis, the metal salt containing colloidal particle is left as is to maximize colloidal stability or is reduced with hydrazine to produce the zero valence metal-containing colloidal particle. Keeping a particle colloidal before use may be an effective method of forming a catalyst material as it can be easily spray-dried or mixed with other materials for extruded catalyst particles.

    Abstract translation: 公开了一种改进的溶胶 - 凝胶法制备富含硅的硅质材料，例如胶体二氧化硅或硅铝酸盐颗粒。 首先，将所选择的金属盐加入到含有铝盐的硅酸溶液或硅酸溶液中。 添加铝以改变金属 - 载体相互作用，因为它在二氧化硅基体内形成Al-O-Si键。 除了铝之外，可以加入形成M-O-Si（M = Ti，B等）键的其它金属，当用还原剂处理时，其不会降低。 一旦生成了金属，硅酸和/或铝盐，则通过加入到基础鞋跟中进行胶体生长。 在胶体合成时，含有胶体颗粒的金属盐保持原样以使胶体稳定性最大化，或者用肼还原以产生含零价金属的胶体颗粒。 在使用前保持颗粒胶体可能是形成催化剂材料的有效方法，因为它可以容易地喷雾干燥或与挤出的催化剂颗粒的其它材料混合。

    Extending the life of an aromatization catalyst
    87.
    发明申请
    Extending the life of an aromatization catalyst 有权
    延长芳构化催化剂的使用寿命

    公开(公告)号：US20090124840A1

    公开(公告)日：2009-05-14

    申请号：US11940115

    申请日：2007-11-14

    Applicant: Scott H. Brown ,  Tin-Tack Peter Cheung ,  Daniel P. Hagewiesche ,  Baiyi Zhao

    Inventor： Scott H. Brown ,  Tin-Tack Peter Cheung ,  Daniel P. Hagewiesche ,  Baiyi Zhao

    IPC: B01J21/20

    CPC classification number: B01J29/90 ,  B01J27/13 ,  B01J27/32 ,  B01J29/62 ,  B01J38/14 ,  C07C2/76 ,  C07C5/31 ,  C10G35/085 ,  C10G45/70 ,  C10G2300/1044 ,  C10G2400/30 ,  Y02P20/584 ,  Y10S585/904 ,  Y10S585/906 ,  C07C15/02

    Abstract: A method of extending the life of an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst, and oxidizing the catalyst prior to reaching the RDT. A method of aromatizing a hydrocarbon comprising identifying a rapid deactivation threshold (RDT) for an aromatization catalyst, and operating an aromatization reactor comprising the catalyst to extend the Time on Stream of the reactor prior to reaching the RDT. A method of characterizing an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst. A method of extending the life of an aromatization catalyst comprising predicting a rapid deactivation threshold (RDT) for an aromatization reactor by employing the catalyst in a reactor system under an accelerated fouling condition to identify a test rapid deactivation threshold (t-RDT), predicting the RDT for the aromatization reactor based upon the t-RDT, and oxidizing the catalyst prior to the predicted RDT to extend the Time on Stream of the aromatization catalyst.

    Abstract translation: 延长芳构化催化剂寿命的方法，包括鉴定催化剂的快速失活阈值（RDT），并在达到RDT之前氧化催化剂。 一种芳构化烃的方法，包括鉴定用于芳族化催化剂的快速失活阈值（RDT），以及操作包含催化剂的芳构化反应器以在达到RDT之前延长反应器上的时间。 表征芳构化催化剂的方法包括鉴定催化剂的快速失活阈值（RDT）。 一种延长芳构化催化剂的寿命的方法，包括通过在加速结垢条件下在反应器系统中使用催化剂来预测芳构化反应器的快速失活阈值（RDT），以鉴定测试快速失活阈值（t-RDT），预测 基于t-RDT的芳构化反应器的RDT，以及在预测的RDT之前氧化催化剂以延长芳构化催化剂的时间。

    Process for conjugating carbon-carbon double bonds in oils
    89.
    发明授权
    Process for conjugating carbon-carbon double bonds in oils 有权
    在油中共轭碳 - 碳双键的方法

    公开(公告)号：US06696581B1

    公开(公告)日：2004-02-24

    申请号：US10219518

    申请日：2002-08-15

    Applicant: Ronald T. Sleeter

    Inventor： Ronald T. Sleeter

    IPC: C07C51347

    CPC classification number: C11C3/14 ,  B01J23/462 ,  B01J27/13

    Abstract: A process for conjugating organic compounds containing methylene interrupted carbon-carbon double bonds comprising (a) contacting ruthenium trichloride hydrate and an organic solvent or carboxylic acid to form a first mixture, the organic solvent or carboxylic acid being present in an amount sufficient to solubilize the ruthenium trichloride hydrate, and (b) contacting the first mixture with an organic compound containing methylene interrupted carbon-carbon double bonds at a sufficient temperature and for a sufficient time to conjugate the organic compound containing methylene interrupted carbon-carbon double bonds; wherein the ruthenium in the ruthenium trichloride hydrate in (b) is present in an amount of about 5 ppm to about 100 ppm based on the weight of the organic compound containing methylene interrupted carbon-carbon double bonds.

    Abstract translation: 一种含有亚甲基间断碳 - 碳双键的有机化合物的共轭方法，包括（a）使三氯化钌水合物与有机溶剂或羧酸接触以形成第一混合物，有机溶剂或羧酸的存在量足以溶解 三氯化钌水合物，和（b）在足够的温度下使第一混合物与含有亚甲基中断的碳 - 碳双键的有机化合物接触足够的时间以使含有亚甲基中断的碳 - 碳双键的有机化合物结合; 其中（b）中三氯化钌水合物中的钌以含有亚甲基中断碳 - 碳双键的有机化合物的重量计约5ppm至约100ppm的量存在。

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