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公开(公告)号：US4532230A
公开(公告)日：1985-07-30
申请号：US506559
申请日：1983-06-21
CPC分类号： B01J23/12
摘要： A ThO.sub.2 catalyst having a high surface area of about 80-125 m.sup.2 /g is synthesized. The compound is synthesized by simultaneously mixing an aqueous solution of ThNO.sub.3 (NO.sub.3).sub.4.4H.sub.2 O with an aqueous solution of Na.sub.2 CO.sub.3.H.sub.2 O, to produce a solution and solid ThOCO.sub.3. The solid ThOCO.sub.3 is separated from the solution, and then calcined at a temperature of about 225.degree.-300.degree. C. for about 40-55 hours to produce ThO.sub.2. The ThO.sub.2 catalyst produced includes Na present as a substitutional cation in an amount equal to about 5-10 atom percent.
摘要翻译： 合成具有约80-125m 2 / g的高表面积的ThO 2催化剂。 通过同时将ThNO 3（NO 3）4·4H 2 O的水溶液与Na 2 CO 3·H 2 O的水溶液同时混合来合成化合物，得到溶液和固体的ThOOC 3。 将固体ThOCO 3与溶液分离，然后在约225-300℃的温度下煅烧约40-55小时以产生ThO 2。 产生的ThO 2催化剂包括以等于约5-10原子％的量作为取代阳离子存在的Na。
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2.发明授权Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making 有权包括包围空间的纳米反应器壳的纳米反应器及其制造方法公开(公告)号：US07875351B2
公开(公告)日：2011-01-25
申请号：US10599250
申请日：2005-03-22
IPC分类号： B32B5/16
CPC分类号： C30B29/60 , B22F1/0025 , B22F2001/0029 , B82Y30/00 , C01B13/32 , C01B13/322 , C01B17/20 , C01B19/007 , C01B21/06 , C01B21/0602 , C01B21/0632 , C01B21/0637 , C01G11/02 , C01G49/06 , C01G51/00 , C01G51/04 , C01G51/30 , C01G53/00 , C01G53/09 , C01G55/00 , C01P2002/72 , C01P2004/04 , C01P2004/13 , C01P2004/16 , C01P2004/34 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C30B7/00 , C30B29/16 , C30B29/48 , Y10S977/70 , Y10S977/773 , Y10T428/12181 , Y10T428/13 , Y10T428/2991
摘要： Described herein are nanoreactors having various shapes that can be produced by a simple chemical process. The nanoreactors described herein may have a shell as thin as 0.5 nm and outside diameters that can be controlled by the process of making and have a nanoparticle enclosed therein. The nanoreactors have catalytic activity and may be used to catalyze a variety of chemical reactions.
摘要翻译： 本文描述了具有可以通过简单化学方法生产的各种形状的纳米反应器。 本文所述的纳米反应器可以具有薄至0.5nm的外壳，并且可以通过制备方法控制外部直径并且将纳米颗粒封闭在其中。 纳米反应器具有催化活性，可用于催化各种化学反应。
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3.发明授权
公开(公告)号：US4460443A
公开(公告)日：1984-07-17
申请号：US416351
申请日：1982-09-09
CPC分类号： C25B1/003 , Y02E60/368
摘要： Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor diode having visible light as its sole source of energy. The diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.
摘要翻译： 通过使化合物与具有可见光的p / n型半导体二极管作为其唯一能量源接触来解离化合物。 在p型电极的情况下，二极管由低成本，易于获得的材料，特别是在n型半导体电极的情况下掺杂有硅的多晶铁氧化物和掺杂有镁的多晶铁氧体组成。 只要光源具有大于2.2电子伏特的能量，就不需要添加能量来实现解离。
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4.发明授权Generation of highly N-type, defect passivated transition metal oxides using plasma fluorine insertion 有权使用等离子体氟插入产生高度N型，缺陷钝化的过渡金属氧化物公开(公告)号：US09312342B2
公开(公告)日：2016-04-12
申请号：US13994663
申请日：2011-12-16
CPC分类号： H01L29/24 , H01L21/02565 , H01L21/02576 , H01L21/02631 , H01L21/324 , H01L27/2436 , H01L45/08 , H01L45/1233 , H01L45/146 , H01L45/1625 , H01L45/1641
摘要： A new composition of matter is disclosed wherein oxygen vacancies in a semiconducting transition metal oxide such as titanium dioxide are filled with a halogen such as Fluorine, whereby the conductivity of the composition is greatly enhanced, while at the same time the chemical stability of the composition is greatly improved. Stoichiometric titanium dioxide having less than 3 % oxygen vacancies is subject to fluorine insertion such that oxygen vacancies are filled, limited amounts of fluorine replace additional oxygen atoms and fluorine interstitially inserts into the body of the TiO2 composition.
摘要翻译： 公开了一种新的物质组合物，其中半导体过渡金属氧化物如二氧化钛中的氧空位填充有诸如氟的卤素，由此组合物的导电性大大增强，同时组合物的化学稳定性 大大提高。 具有小于3％氧空位的化学计量二氧化钛经受氟插入，使得氧空位被填充，有限量的氟替代另外的氧原子和氟间隙插入到TiO 2组合物的体内。
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公开(公告)号：US20080226934A1
公开(公告)日：2008-09-18
申请号：US10599250
申请日：2005-03-22
CPC分类号： C30B29/60 , B22F1/0025 , B22F2001/0029 , B82Y30/00 , C01B13/32 , C01B13/322 , C01B17/20 , C01B19/007 , C01B21/06 , C01B21/0602 , C01B21/0632 , C01B21/0637 , C01G11/02 , C01G49/06 , C01G51/00 , C01G51/04 , C01G51/30 , C01G53/00 , C01G53/09 , C01G55/00 , C01P2002/72 , C01P2004/04 , C01P2004/13 , C01P2004/16 , C01P2004/34 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C30B7/00 , C30B29/16 , C30B29/48 , Y10S977/70 , Y10S977/773 , Y10T428/12181 , Y10T428/13 , Y10T428/2991
摘要： Described herein are nanoreactors having various shapes that can be produced by a simple chemical process. The nanoreactors described herein may have a shell as thin as 0.5 nm and outside diameters that can be controlled by the process of making and have a nanoparticle enclosed therein. The nanoreactors have catalytic activity and may be used to catalyze a variety of chemical reactions.
摘要翻译： 本文描述了具有可以通过简单化学方法生产的各种形状的纳米反应器。 本文所述的纳米反应器可以具有薄至0.5nm的外壳，并且可以通过制备方法控制外部直径并且将纳米颗粒封闭在其中。 纳米反应器具有催化活性，可用于催化各种化学反应。
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6.发明授权Electrolytic photodissociation of chemical compounds by iron oxide photochemical diodes 失效化学化合物电解光解由氧化铁光化学二极管
公开(公告)号：US4533608A
公开(公告)日：1985-08-06
申请号：US614282
申请日：1984-05-24
CPC分类号： C25B1/003 , Y10S204/03
摘要： Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor photochemical diode having visible light as its sole source of energy. The photochemical diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.
摘要翻译： 可以通过将其与具有可见光的p / n型半导体光化学二极管作为其唯一能量源接触来解离化学化合物。 在p型电极的情况下，光化学二极管由低成本，易于获得的材料，特别是在n型半导体电极的情况下掺杂有硅的多晶铁氧化物和掺杂有镁的多晶铁氧体组成。 只要光源具有大于2.2电子伏特的能量，就不需要添加能量来实现解离。
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7.发明授权Fuel compositions and additive mixtures for reducing hydrocarbon emissions 失效用于减少碳氢化合物排放的燃料组合物和添加剂混合物
公开(公告)号：US4390345A
公开(公告)日：1983-06-28
申请号：US207371
申请日：1980-11-17
申请人： Gabor A. Somorjai
发明人： Gabor A. Somorjai
CPC分类号： C10L10/02 , C10L1/14 , C10L10/10 , C10L1/1855 , C10L1/305
摘要： Gasoline compositions and additive mixtures containing compounds having the formula: ##STR1## wherein R.sub.1 -R.sub.6 are each independently selected from hydrogen or hydrocarbyl radicals in an amount sufficient to reduce exhaust hydrocarbon emissions from an internal combustion engine being operated on gasoline containing a cyclopentadienyl manganese antiknock. Preferred hydrocarbon exhaust emission reducing compounds are 1,3-dioxolane and the lower alkyl and alkenyl substituted derivatives thereof.
摘要翻译： 含有下式化合物的汽油组合物和添加剂混合物，其中R1-R6各自独立地选自氢或烃基，其量足以减少在含有环戊二烯基锰抗爆炸剂的汽油上操作的内燃机的排放烃排放 。 优选的烃废气排放减少化合物是1,3-二氧戊环及其低级烷基和烯基取代的衍生物。
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8.发明申请GENERATION OF HIGHLY N-TYPE, DEFECT PASSIVATED TRANSITION METAL OXIDES USING PLASMA FLUORINE INSERTION 有权使用等离子体氟化物插入物生成高N型，缺陷钝化金属氧化物公开(公告)号：US20140306215A1
公开(公告)日：2014-10-16
申请号：US13994663
申请日：2011-12-16
CPC分类号： H01L29/24 , H01L21/02565 , H01L21/02576 , H01L21/02631 , H01L21/324 , H01L27/2436 , H01L45/08 , H01L45/1233 , H01L45/146 , H01L45/1625 , H01L45/1641
摘要： A new composition of matter is disclosed wherein oxygen vacancies in a semiconducting transition metal oxide such as titanium dioxide are filled with a halogen such as Fluorine, whereby the conductivity of the composition is greatly enhanced, while at the same time the chemical stability of the composition is greatly improved. Stoichiometric titanium dioxide having less than 3% oxygen vacancies is subject to fluorine insertion such that oxygen vacancies are filled, limited amounts of fluorine replace additional oxygen atoms and fluorine interstitially inserts into the body of the TiO2 composition.
摘要翻译： 公开了一种新的物质组合物，其中半导体过渡金属氧化物如二氧化钛中的氧空位填充有诸如氟的卤素，由此组合物的导电性大大增强，同时组合物的化学稳定性 大大提高。 具有小于3％氧空位的化学计量二氧化钛经受氟插入，使得氧空位被填充，有限量的氟替代另外的氧原子和氟间隙插入到TiO 2组合物的体内。
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公开(公告)号：US20120244038A1
公开(公告)日：2012-09-27
申请号：US13388223
申请日：2010-06-22
申请人： Feng Tao , Miquel Salmeron , Gabor A. Somorjai
发明人： Feng Tao , Miquel Salmeron , Gabor A. Somorjai
CPC分类号： G01Q60/16 , B82Y35/00 , G01Q30/12 , G01Q30/16 , Y10S977/86 , Y10S977/861 , Y10S977/869 , Y10S977/871
摘要： An embodiment of a scanning tunneling microscope (STM) reactor includes a pressure vessel, an STM assembly, and three spring coupling objects. The pressure vessel includes a sealable port, an interior, and an exterior. An embodiment of an STM system includes a vacuum chamber, an STM reactor, and three springs. The three springs couple the STM reactor to the vacuum chamber and are operable to suspend the scanning tunneling microscope reactor within the interior of the vacuum chamber during operation of the STM reactor. An embodiment of an STM assembly includes a coarse displacement arrangement, a piezoelectric fine displacement scanning tube coupled to the coarse displacement arrangement, and a receiver. The piezoelectric fine displacement scanning tube is coupled to the coarse displacement arrangement. The receiver is coupled to the piezoelectric scanning tube and is operable to receive a tip holder, and the tip holder is operable to receive a tip.
摘要翻译： 扫描隧道显微镜（STM）反应器的一个实施例包括压力容器，STM组件和三个弹簧耦合物体。 压力容器包括可密封的端口，内部和外部。 STM系统的实施例包括真空室，STM反应器和三个弹簧。 三个弹簧将STM反应器耦合到真空室，并且可操作以在STM反应器的操作期间将扫描隧道显微镜反应器悬挂在真空室内部。 STM组件的实施例包括粗排列布置，耦合到粗位移布置的压电精细位移扫描管和接收器。 压电精细位移扫描管耦合到粗排位置。 接收器耦合到压电扫描管并且可操作以接收尖端保持器，并且尖端保持器可操作以接收尖端。
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公开(公告)号：US08893309B2
公开(公告)日：2014-11-18
申请号：US13388223
申请日：2010-06-22
申请人： Feng Tao , Miquel Salmeron , Gabor A. Somorjai
发明人： Feng Tao , Miquel Salmeron , Gabor A. Somorjai
IPC分类号： G01Q60/10 , G01Q30/18 , G01Q30/16 , G01Q60/16 , G01Q30/12 , G01Q60/00 , G21K5/10 , B82Y35/00
CPC分类号： G01Q60/16 , B82Y35/00 , G01Q30/12 , G01Q30/16 , Y10S977/86 , Y10S977/861 , Y10S977/869 , Y10S977/871
摘要： An embodiment of a scanning tunneling microscope (STM) reactor includes a pressure vessel, an STM assembly, and three spring coupling objects. The pressure vessel includes a sealable port, an interior, and an exterior. An embodiment of an STM system includes a vacuum chamber, an STM reactor, and three springs. The three springs couple the STM reactor to the vacuum chamber and are operable to suspend the scanning tunneling microscope reactor within the interior of the vacuum chamber during operation of the STM reactor. An embodiment of an STM assembly includes a coarse displacement arrangement, a piezoelectric fine displacement scanning tube coupled to the coarse displacement arrangement, and a receiver. The piezoelectric fine displacement scanning tube is coupled to the coarse displacement arrangement. The receiver is coupled to the piezoelectric scanning tube and is operable to receive a tip holder, and the tip holder is operable to receive a tip.
摘要翻译： 扫描隧道显微镜（STM）反应器的一个实施例包括压力容器，STM组件和三个弹簧耦合物体。 压力容器包括可密封的端口，内部和外部。 STM系统的实施例包括真空室，STM反应器和三个弹簧。 三个弹簧将STM反应器耦合到真空室，并且可操作以在STM反应器的操作期间将扫描隧道显微镜反应器悬挂在真空室内部。 STM组件的实施例包括粗排列布置，耦合到粗位移布置的压电精细位移扫描管和接收器。 压电精细位移扫描管耦合到粗排位置。 接收器耦合到压电扫描管并且可操作以接收尖端保持器，并且尖端保持器可操作以接收尖端。
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