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170 条记录 (耗时 0.031 秒)

    Process for preparing unsaturated cyclic ethers
    1.
    发明授权
    Process for preparing unsaturated cyclic ethers 失效
    不饱和环醚的制备方法

    公开(公告)号：US6063939A

    公开(公告)日：2000-05-16

    申请号：US226144

    申请日：1999-01-07

    申请人： Carsten Groning ,  Michael Hesse ,  Daniel Heineke ,  Heinz-Josef Kneuper ,  Gerhard Fritz

    发明人： Carsten Groning ,  Michael Hesse ,  Daniel Heineke ,  Heinz-Josef Kneuper ,  Gerhard Fritz

    IPC分类号： B01J23/89 ,  B01J27/045 ,  C07D309/18 ,  C07D507/02 ,  C07D309/00 ,  C07D319/12

    CPC分类号： B01J27/045 ,  B01J23/8913 ,  C07D309/18

    摘要： Unsaturated cyclic ethers of the formula I ##STR1## whereZ is --(CHR.sup.4).sub.q -- or --(CHR.sup.4).sub.q --O--,q is 0, 1, 2 or 3 andR.sup.1,R.sup.2,R.sup.3,R.sup.4 are hydrogen or C.sub.1 -C.sub.4 -alkylare prepared by reacting diols of the formula II ##STR2## where Z, R.sup.1, R.sup.2 and R.sup.3 are as defined above, in the liquid phase at from 150 to 300.degree. C. in the presence of a cobalt-containing supported catalyst which has not been activated by reduction before use and comprises cobalt and a noble metal selected from the group consisting of platinum, palladium, rhodium, iridium, ruthenium, osmium, rhenium or a mixture thereof applied by sol impregnation on an inert support, wherein the supported catalyst is doped with sulfur. Sulfur-doped supported catalysts comprising cobalt and noble metals are also provided.

    摘要翻译： Z为 - （CHR 4）q-或 - （CHR 4）q O - ，q为0,1,2或3且R 1，R 2，R 3，R 4为氢或C 1 -C 4烷基的式I的不饱和环醚为 通过使其中Z，R 1，R 2和R 3如上所定义的式II的二醇在150-300℃的液相中，在没有被还原活化的含钴担载催化剂存在下反应制备 并且包括钴和选自铂，钯，铑，铱，钌，锇，铼的贵金属或其通过溶胶浸渍施加到惰性载体上的混合物，其中负载型催化剂掺杂有硫。 还提供了包含钴和贵金属的硫掺杂负载型催化剂。

    Method for producing oxidic catalysts containing copper with oxidation number>0
    2.
    发明授权
    Method for producing oxidic catalysts containing copper with oxidation number>0 失效
    生产含氧化值> 0的铜的氧化催化剂的方法

    公开(公告)号：US06716789B1

    公开(公告)日：2004-04-06

    申请号：US09581988

    申请日：2000-06-21

    申请人： Daniel Heineke ,  Ruprecht Meissner ,  Michael Hesse ,  Henning-Peter Gehrken

    发明人： Daniel Heineke ,  Ruprecht Meissner ,  Michael Hesse ,  Henning-Peter Gehrken

    IPC分类号： B01J2108

    CPC分类号： C07C45/002 ,  B01J23/72 ,  B01J37/0203 ,  C07C49/403

    摘要： The disclosure is directed to a process for preparing an oxidic catalyst comprising copper in an oxidation state >0, which comprises treating a solid oxidic support material with an aqueous solution comprising at least one copper salt and at least one organic water soluble polymer which binds copper ions coordinatively in a concentration of from 0.1 to 100 g/l and then calcining, to the catalyst obtainable by this process and also to a process for dehydrogenating secondary alcohols to ketones using the catalysts, especially for dehydrogenating cyclohexanol.

    摘要翻译： 本发明涉及制备氧化态> 0的铜的氧化催化剂的方法，该方法包括用包含至少一种铜盐和至少一种与铜结合的有机水溶性聚合物的水溶液处理固体氧化载体材料 离子以0.1至100g / l的浓度配位，然后煅烧至可通过该方法获得的催化剂，并且还涉及一种使用催化剂，特别是用于使环己醇脱氢来将仲醇脱氢成酮的方法。

    CATALYST AND PROCESS FOR HYDROGENATING CARBONYL COMPOUNDS
    10.
    发明申请
    CATALYST AND PROCESS FOR HYDROGENATING CARBONYL COMPOUNDS 有权
    催化剂和加氢处理碳化合物

    公开(公告)号：US20100056364A1

    公开(公告)日：2010-03-04

    申请号：US12608125

    申请日：2009-10-29

    申请人： Sylvia HUBER-DIRR ,  Michael Hesse ,  Andrea Haunert ,  Henrik Junicke

    发明人： Sylvia HUBER-DIRR ,  Michael Hesse ,  Andrea Haunert ,  Henrik Junicke

    IPC分类号： B01J21/18

    CPC分类号： C07C29/149 ,  B01J23/83 ,  C07C31/20

    摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.

    摘要翻译： 氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在成型制品存在下氢化，所述成型制品包含（i）包含氧化铜，氧化铝和氧化镧的氧化物质和（ii ）粉末状金属铜，铜薄片，水泥粉末，石墨或其混合物。