摘要:
An organic fine particle comprising a core polymer and a shell polymer. The core polymer has a Tg or a melting point of 15° C. or more, the core polymer has a water contact angle of 100° or more, all monofunctional monomers constituting the core polymer are a hydrophobic core monomer of which homopolymer has a water contact angle of 100° or more, the shell polymer has a Tg or a melting point lower than Tg or the melting point of the core polymer, the shell polymer has a water contact angle of less than 100°, and all monofunctional monomers constituting the shell polymer are a water-insoluble shell monomer of which homopolymer is water-insoluble. Also disclosed is a surface coating structure including the organic fine particle and a water-repellant composition including a dispersion of the organic fine particle.
摘要:
Organic fine particles and a slip-resistance agent composition which are capable of providing excellent slip-resistance to a base material. The organic fine particles contain a polymer having a repeating unit formed of: (I) a hydrophobic monomer that has a single ethylenically unsaturated double bond and at least one branched or cyclic hydrocarbon group having 3-40 carbon atoms; and, if necessary, (II) a cross-linking monomer having at least two ethylenically unsaturated double bonds. The slip-resistance agent composition contains (A) the organic fine particles and (B) an aqueous medium.
摘要:
The present invention aims to provide a production method that can produce an aqueous dispersion containing polyvinylidene fluoride with high productivity. The present invention relates to a method of producing an aqueous dispersion of polyvinylidene fluoride, including: emulsion polymerization of vinylidene fluoride in the presence of a surfactant, an organic peroxide, and water to produce an aqueous dispersion that contains polyvinylidene fluoride. The surfactant has a surface tension of 55 mN/m or smaller when added in an amount of 1000 ppm.
摘要:
The disclosure provides a production method capable of producing a hollow fine particulate containing a fluorine-containing resin and having a large average particle size. The production method includes a step A of dispersing a solution containing a fluorinated monomer and a non-polymerizable solvent into water to provide a dispersion; a step B of polymerizing the fluorinated monomer to provide a phase-separated fine particulate containing a fluorine-containing resin; and a step C of removing the non-polymerizable solvent in the phase-separated fine particulate to provide a hollow fine particulate.
摘要:
An oil repellent agent including a modified natural product having at least one hydroxyl group, wherein a hydrogen atom of the hydroxyl group is replaced with an R group represented by —Y—Z, wherein Y represents a direct bond, —C(═O)—, —C(═O)—NR′— or —C(═S)—NR′—, where R′ represents a hydrogen atom or a C1 to C4 alkyl group); and Z represents a hydrocarbon group having 1 to 40 carbon atoms and optionally having a substituent or a polysiloxane. The natural material is a natural product other than starch and preferably is a monosaccharide, a polysaccharide, glycerin or polyglycerin. Also disclosed is a textile product to which the oil-resistant agent is attached, an oil-resistant paper and a method of treating paper with the oil-resistant agent.
摘要:
The present disclosure provides organic fine particles and a slip-resistance agent composition which are capable of providing excellent slip-resistance to a base material. Said organic fine particles contain a polymer having a repeating unit formed of: (I) a hydrophobic monomer that has a single ethylenically unsaturated double bond and at least one branched or cyclic hydrocarbon group having 3-40 carbon atoms; and, if necessary, (II) a cross-linking monomer having at least two ethylenically unsaturated double bonds. Said slip-resistance agent composition contains (A) the organic fine particles and (B) an aqueous medium.
摘要:
An oil-resistant agent containing a modified natural product which is a bio-based compound having at least one carboxyl group and in which a hydroxyl group of a carboxyl group is substituted with an R group, or a carboxyl group is substituted with an Ra group.
R group: —X—R1 or —X-D-X′—R1. Ra group:
wherein X is a direct bond, —O—, —NR11—, or —S—, and R1 is a hydrocarbon group having 1-40 carbon atoms, or a polysiloxane, D is an alkylene group having 1-10 carbon atoms, X′ is —C(═O)—O—, —O—(═O)—, —C(═O)—NR12—, or —NR12—C(═O)— (where, R11 and R12 are each hydrogen or an alkyl group having 1-40 carbon atoms). Also disclosed is a textile product, an oil-resistant paper, a food packaging material or a food container each including the oil-resistant agent, as well as a method of treating paper with the oil-resistant agent.