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    Energy storage devices and composite articles associated with the same
    6.
    发明申请
    Energy storage devices and composite articles associated with the same 审中-公开
    储能装置和与之相关的复合制品

    公开(公告)号：US20080212261A1

    公开(公告)日：2008-09-04

    申请号：US11509316

    申请日：2006-08-24

    申请人： Pulickel M. Ajayan ,  Robert J. Linhardt ,  Omkaram Nalamasu ,  Ashavani Kumar ,  Saravanababu Murugesan ,  Shaijumon M. Manikoth ,  Victor L. Pushparaj

    发明人： Pulickel M. Ajayan ,  Robert J. Linhardt ,  Omkaram Nalamasu ,  Ashavani Kumar ,  Saravanababu Murugesan ,  Shaijumon M. Manikoth ,  Victor L. Pushparaj

    IPC分类号： H01G9/00 ,  H01M10/40 ,  H01B1/24 ,  H01M10/36 ,  H01G9/022 ,  C23C16/44 ,  B29C39/02 ,  H01G9/035

    CPC分类号： H01G9/155 ,  H01G11/48 ,  Y02E60/13

    摘要： Embodiments of the invention relate to energy storage devices, e.g., capacitors and batteries, that may include a composite article of elongated conductive structures embedded in a polymer matrix. In some embodiments, a liquid containing ionic species may be dispersed within the polymer matrix of the article. The liquid may contact the elongated conductive structures within the polymer matrix. When the composite article is used as an energy storage device, the large surface area at the interface between the elongated conductive structures and the liquid can provide high energy storage. Embodiments of the invention enable storing energy using a composite article that exhibits both high and low temperature stability, high cyclic repeatability, and mechanical flexibility. The composite article can also be non-toxic, biocompatible and environmentally friendly. Thus, the composite article may be useful for a variety of energy storage applications, such as in the automotive, RFID, MEMS and medical fields.

    摘要翻译： 本发明的实施例涉及可以包括嵌入在聚合物基质中的细长导电结构的复合制品的能量存储装置，例如电容器和电池。 在一些实施方案中，含有离子物质的液体可以分散在制品的聚合物基质内。 液体可以接触聚合物基质内的细长导电结构。 当复合制品​​用作能量存储装置时，细长导电结构和液体之间的界面处的大的表面积可以提供高能量储存。 本发明的实施例能够使用表现出高低温稳定性，高循环重复性和机械柔性的复合制品来储存能量。 复合制品也可以是无毒的，生物相容的和环保的。 因此，复合制品可用于各种能量存储应用，例如在汽车，RFID，MEMS和医疗领域。

    Reconfigurable polymeric self-healing coating
    10.
    发明授权
    Reconfigurable polymeric self-healing coating 有权
    可重构的聚合物自愈膜

    公开(公告)号：US08802801B1

    公开(公告)日：2014-08-12

    申请号：US13429943

    申请日：2012-03-26

    申请人： Ashavani Kumar ,  Vinod P. Veedu ,  Venkat Kamavaram ,  Sumil Thapa

    发明人： Ashavani Kumar ,  Vinod P. Veedu ,  Venkat Kamavaram ,  Sumil Thapa

    IPC分类号： C08F218/00 ,  C08K5/09

    CPC分类号： C08F222/40 ,  C09D5/00

    摘要： A self-healing polymer additive includes diene (e.g. butadiene, cyclohexadiene, pentadiene, tetrahydrofuron or their derivatives) and dienophile (e.g. maleic anhydride, maleamide, conjugated carbonyls or their derivatives etc.). One polymer includes tetrahydrofuron and maleimide. Furfurylamine 12 (1-10 gm) is diluted in acetone. Under an inert atmosphere an equivalent amount of granular maleic acid is added slowly, and the reaction is allowed to take place. Resulting maleamic acid precipitates. The maleamic acid product is separated, dried and purified by re-crystallization. The maleamic (1-5 gm) acid is dissolved in acetic anhydride along with a catalytic amount of sodium acetate. The resulting solution is heated for a few hours in 80-120° C. The precipitated final product is separated, purified and dried in a vacuum. The self-healing polymer is dissolved in a solvent, and self-healing molecules are cross linked and are mixed with a polymer matric for various applications such as coatings and structural materials.

    摘要翻译： 自愈合聚合物添加剂包括二烯（例如丁二烯，环己二烯，戊二烯，四氢呋喃或其衍生物）和亲二烯体（例如马来酸酐，马来酰亚胺，共轭羰基或其衍生物等）。 一种聚合物包括四氢呋喃和马来酰亚胺。 将糠胺12（1-10克）稀释在丙酮中。 在惰性气氛下，缓慢加入等量的马来酸颗粒，使反应发生。 产生的马来酰胺酸沉淀。 马来酰胺酸产物被分离，干燥并通过重结晶纯化。 将马来酰胺（1-5克）酸与催化量的乙酸钠一起溶解在乙酸酐中。 将所得溶液在80-120℃下加热数小时。沉淀的最终产物被分离，纯化并在真空中干燥。 将自修复聚合物溶解在溶剂中，自愈合分子交联并与聚合物基质混合，用于各种应用如涂料和结构材料。