公开(公告)号：US20150263210A1

公开(公告)日：2015-09-17

申请号：US14428349

申请日：2012-12-26

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Tae Won Kim ,  Jae Cheol Park ,  Ho Sung Kim ,  Ik Hyun Oh ,  Jeon Ryang Lee ,  Bo Ra Koo ,  Seung Hyoun Lee

IPC: H01L31/0749 ,  H01J37/34 ,  C23C14/34

CPC classification number: H01L31/0749 ,  C23C14/0623 ,  C23C14/34 ,  C23C14/3464 ,  H01J37/3426 ,  H01J37/3429 ,  H01L31/0322 ,  Y02E10/541 ,  Y02P70/521

Abstract: Provided are a CIS/CGS/CIGS thin-film manufacturing method and a solar cell manufactured by using the same. The CIS/CGS/CIGS thin-film manufacturing method enables CIS, CGS, and CIGS thin-films through depositing an electrode layer on a substrate and depositing a light absorber layer by sputtering a single target of each of CIS including copper (Cu), indium (In), and selenium (Se) and CGS copper (Cu), gallium (Ga) and selenium (Se). In addition, a solar cell having excellent structural, optical and electrical properties is prepared by using the same. Thus, a thin-film can be prepared by depositing a CIG, CGS, or CIGS light absorber layer with a single sputtering process by using a single target of each of CIS (CuInSe2) and CGS (CuGaSe2), to thereby enable to manufacture thin-films of various characteristics according to a control of a composition ratio of In and Ga as well as simplification of the process, and to thus provide a very favorable effect on the economics and efficiency.

Abstract translation: 提供了CIS / CGS / CIGS薄膜制造方法和使用该方法制造的太阳能电池。 CIS / CGS / CIGS薄膜制造方法通过在基板上沉积电极层并且通过溅射CIS中的每一个的单个靶沉积光吸收层来实现CIS，CGS和CIGS薄膜，包括铜（Cu）， 铟（In）和硒（Se）和CGS铜（Cu），镓（Ga）和硒（Se）。 此外，通过使用具有优异的结构，光学和电学性能的太阳能电池。 因此，可以通过使用CIS（CuInSe 2）和CGS（CuGaSe 2）中的每一个的单个靶沉积具有单次溅射工艺的CIG，CGS或CIGS光吸收层来制备薄膜，从而能够制造薄 - 根据In和Ga的组成比的控制以及工艺的简化，具有各种特性的膜，从而对经济性和效率提供非常有利的影响。

公开(公告)号：US20150004526A1

公开(公告)日：2015-01-01

申请号：US14377109

申请日：2012-11-20

Applicant: Korea Institute of Industrial Technology

Inventor： Ho Sung Kim ,  Ju Hee Kang ,  Hyo Sin Kim ,  Jin Hun Jo ,  Yeong Mok Kim ,  Sang Hun Heo ,  Tae Won Kim

IPC: H01M8/12 ,  H01M4/90 ,  H01M4/88

CPC classification number: H01M8/1253 ,  H01M4/8803 ,  H01M4/8835 ,  H01M4/8857 ,  H01M4/8875 ,  H01M4/8885 ,  H01M4/8889 ,  H01M4/9025 ,  H01M4/9033 ,  H01M8/1213 ,  H01M8/1226 ,  H01M8/126 ,  H01M2008/1293 ,  H01M2300/0077 ,  Y02E60/521 ,  Y02E60/525 ,  Y02P70/56

Abstract: The present invention relates to a technique for manufacturing a unit cell for a solid oxide fuel cell (SOFC) which can improve the output of the unit cell of the solid oxide fuel cell, without occurring cost due to an additional process. The unit cell of the solid oxide fuel cell, comprises: a fuel electrode support body; a fuel electrode reaction layer; an electrolyte; and an air electrode, wherein the fuel electrode support body is made from an NiO and YSZ mixed material, the fuel electrode reaction layer is made from a CeScSZ and NiO mixed material, the electrolyte is made from a CeCsSZ material, and wherein the air electrode is made from an LSM and CeScSZ mixed material.

Abstract translation: 本发明涉及用于制造固体氧化物型燃料电池（SOFC）的单元电池的技术，该技术能够提高固体氧化物型燃料电池的单位电池的输出，而不会由于额外的处理而产生成本。 固体氧化物型燃料电池的单电池包括：燃料电极支撑体; 燃料电极反应层; 电解液 以及空气电极，其中所述燃料电极支撑体由NiO和YSZ混合材料制成，所述燃料电极反应层由CeScSZ和NiO混合材料制成，所述电解质由CeCsSZ材料制成，并且其中所述空气极 由LSM和CeScSZ混合材料制成。

公开(公告)号：US10033032B1

公开(公告)日：2018-07-24

申请号：US15506443

申请日：2015-06-18

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Ho Sung Kim ,  Byeong Su Kang ,  Sun Woo Yang ,  Min Young Kim ,  Chae Hwan Jeong

IPC: H01M4/13 ,  H01M4/1397 ,  C01B25/45 ,  H01M4/58 ,  H01M4/62 ,  H01M4/04 ,  H01M10/052 ,  B01J2/22 ,  H01M4/02

Abstract: Disclosed is a method of preparing a cathode electrode material for a secondary battery, including a hydrate precursor preparation step of preparing a manganese phosphate hydrate precursor using a coprecipitation process, a synthetic powder preparation step of preparing a synthetic powder by mixing the manganese phosphate hydrate precursor in a powder form with lithium phosphate and carbon, an oxide material powder preparation step of preparing a lithium manganese phosphate oxide material powder by milling and annealing the synthetic powder, a composite powder preparation step of preparing a composite powder by mixing the lithium manganese phosphate oxide material powder with a Li2MnO3-based cathode material, and a slurry preparation step of preparing a slurry by mixing the composite powder with a conductor and a binder.

公开(公告)号：US09972732B2

公开(公告)日：2018-05-15

申请号：US15368024

申请日：2016-12-02

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Chae Hwan Jeong ,  Jong Hwan Lee ,  Chang Heon Kim ,  Ho Sung Kim

IPC: H01L31/0352 ,  H01L31/0236 ,  H01L31/18 ,  H01L31/0224

CPC classification number: H01L31/035227 ,  H01L31/022425 ,  H01L31/02363 ,  H01L31/035281 ,  H01L31/03529 ,  H01L31/068 ,  H01L31/18 ,  H01L31/1804 ,  Y02E10/50 ,  Y02E10/547 ,  Y02P70/521

Abstract: One embodiment of the present invention relates to a method for manufacturing solar cells having a nano-micro composite structure on a silicon substrate and solar cells manufactured thereby. The technical problem to be solved is to provide a method for manufacturing solar cells and solar cells manufactured thereby, the method being capable of forming micro wires in various sizes according to the lithographic design of a photoresist and forming nano wires, which have various sizes and aspect ratios, by adjusting the concentration of a wet etching solution and immersion time. To this end, the present invention provides a method for manufacturing solar cells and solar cells manufactured thereby, the method comprising the steps of: preparing a first conductive semiconductor substrate having a first surface and a second surface; patterning a photoresist on the second surface of the first conductive semiconductor substrate such that the plane form of the photoresist becomes a form in which multiple horizontal lines and multiple vertical lines intersect each other; electrolessly etching the semiconductor substrate so as to form a micro wire having a width of 1-3 μm and a height of 3-5 μm in a region corresponding to the photoresist and to form multiple nano wires having a width of 1-100 nm and a height of 1-3 μm in a region not corresponding to the photoresist; doping the micro wire and nano wires with a second conductive impurity by using POCl3; forming a first electrode on the first surface of the semiconductor substrate; and forming a second electrode on the micro wire, wherein the efficiency of the solar cells is 10-13%, the efficiency being the ratio of output to incident light energy per unit area.

公开(公告)号：US20170084765A1

公开(公告)日：2017-03-23

申请号：US15368024

申请日：2016-12-02

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Chae Hwan Jeong ,  Jong Hwan Lee ,  Chang Heon Kim ,  Ho Sung Kim

IPC: H01L31/0352 ,  H01L31/0236 ,  H01L31/18 ,  H01L31/0224

CPC classification number: H01L31/035227 ,  H01L31/022425 ,  H01L31/02363 ,  H01L31/035281 ,  H01L31/03529 ,  H01L31/068 ,  H01L31/18 ,  H01L31/1804 ,  Y02E10/50 ,  Y02E10/547 ,  Y02P70/521

Abstract: One embodiment of the present invention relates to a method for manufacturing solar cells having a nano-micro composite structure on a silicon substrate and solar cells manufactured thereby. The technical problem to be solved is to provide a method for manufacturing solar cells and solar cells manufactured thereby, the method being capable of forming micro wires in various sizes according to the lithographic design of a photoresist and forming nano wires, which have various sizes and aspect ratios, by adjusting the concentration of a wet etching solution and immersion time. To this end, the present invention provides a method for manufacturing solar cells and solar cells manufactured thereby, the method comprising the steps of: preparing a first conductive semiconductor substrate having a first surface and a second surface; patterning a photoresist on the second surface of the first conductive semiconductor substrate such that the plane form of the photoresist becomes a form in which multiple horizontal lines and multiple vertical lines intersect each other; electrolessly etching the semiconductor substrate so as to form a micro wire having a width of 1-3 μm and a height of 3-5 μm in a region corresponding to the photoresist and to form multiple nano wires having a width of 1-100 nm and a height of 1-3 μm in a region not corresponding to the photoresist; doping the micro wire and nano wires with a second conductive impurity by using POCl3; forming a first electrode on the first surface of the semiconductor substrate; and forming a second electrode on the micro wire, wherein the efficiency of the solar cells is 10-13%, the efficiency being the ratio of output to incident light energy per unit area.

公开(公告)号：US09478993B2

公开(公告)日：2016-10-25

申请号：US14353279

申请日：2012-10-19

Applicant: Korea Institute of Industrial Technology

Inventor： Ho Sung Kim ,  Ju Hee Kang ,  Ik Hyun Oh ,  Seong Jae Boo ,  Duck Rye Chang ,  Tae Won Kim ,  Sung Hee Park ,  Kyeong Wan Kim

IPC: H02J7/00 ,  H01M4/505 ,  H01M4/525 ,  C01D15/02 ,  H01M4/04 ,  H01M10/052

CPC classification number: H02J7/00 ,  C01D15/02 ,  H01M4/0402 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

Abstract: The present invention relates to the manufacture of a high capacity electrode by synthesizing an excellent Li2MnO3-based composite material Li(LixNiyCozMnwO2) to improve the characteristics of an inactive Li2MnO3 material with a specific capacity of about 460 mAh/g. Here, a manufacturing method of a cathode material for a lithium secondary battery uses a Li2MnO3-based composite material Li(LixNiyCozMnwO2) by reacting a starting material wherein a nickel nitrate solution, a manganese nitrate solution and a cobalt nitrate solution are mixed, with a complex agent by co-precipitation.

Abstract translation: 本发明涉及通过合成优异的Li 2 MnO 3基复合材料Li（Li x Ni y Co z Mn n O 2 O 2）来制造高容量电极，以改善比电容为约460mAh / g的无活性Li 2 MnO 3材料的特性。 这里，锂二次电池用正极材料的制造方法使用混合有硝酸镍溶液，硝酸锰溶液和硝酸钴溶液的原料与Li2MnO3系复合材料Li（Li x Ni y Co z Mn n O 2 O 2） 复合剂通过共沉淀。

公开(公告)号：US20150380720A1

公开(公告)日：2015-12-31

申请号：US14766874

申请日：2013-08-20

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Ho Sung Kim ,  Sun Woo Yang ,  Kyeong Wan Kim ,  Chae Hwan Jeong ,  Tae Won Kim ,  Duck Rye Chang ,  Min Young Kim

IPC: H01M4/04 ,  H01M4/505 ,  H01M10/44 ,  H01M4/485 ,  C01G53/00 ,  H01M4/1391 ,  H01M4/131 ,  H01M4/525

CPC classification number: H01M4/0471 ,  C01G53/50 ,  C01P2002/72 ,  C01P2006/40 ,  H01M2/1653 ,  H01M4/0404 ,  H01M4/0435 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/382 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0427 ,  H01M10/052 ,  H01M10/44 ,  H01M2004/027 ,  Y02T10/7011

Abstract: This disclosure synthesizes an anodic composite material Li(LixNiyCozMnwO2+α) of Li2MnO3 series whose theoretical capacity is a level of about 460 mAh/g, and to produce an electrode of a high capacity using the synthesized anodic composite material. Also provided is a method for charging and discharging the electrode. Here, the method for producing an anodic composite material for a lithium secondary battery includes the steps of: mixing a nickel nitrate solution, a manganese nitrate solution, and a cobalt nitrate solution to produce a starting material solution; and mixing the starting material solution with a complexing agent so as to produce an anodic composite material Li(LixNiyCozMnwO2+α) of Li2MnO3 series by means of coprecipitation.

Abstract translation: 本公开内容合成了理论容量为约460mAh / g的Li2MnO3系列的阳极复合材料Li（LixNiyCozMnwO2 +α），并使用合成的阳极复合材料制造高容量的电极。 还提供了一种用于充电和放电电极的方法。 这里，用于制造锂二次电池用阳极复合材料的方法包括以下步骤：将硝酸镍溶液，硝酸锰溶液和硝酸钴溶液混合以制备原料溶液; 并将原料溶液与络合剂混合，通过共沉淀法制备Li2MnO3系列的阳极复合材料Li（Li x Ni y Co z Mn O 2 +α）。

公开(公告)号：US20150280048A1

公开(公告)日：2015-10-01

申请号：US14437087

申请日：2012-12-18

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Chae Hwan Jeong ,  Sun Hwa Lee ,  Sang Ryu ,  Ho Sung Kim ,  Seong Jae Boo

IPC: H01L31/18

CPC classification number: H01L31/182 ,  C23C14/5806 ,  H01L31/028 ,  H01L31/068 ,  H01L31/1872 ,  H05K999/99 ,  Y02E10/546 ,  Y02E10/547 ,  Y02P70/521

Abstract: One embodiment of the present invention relates to a method of manufacturing polycrystalline silicon thin-film solar cell by a method of crystallizing a large-area amorphous silicon thin film using a linear electron beam, and the technical problem to be solved is to crystallize an amorphous silicon thin film, which is formed on a low-priced substrate, by means of an electron beam so as for same to easily be of high quality by having high crystallization yield and to be processed at a low temperature. To this end, one embodiment of the present invention provides a method of manufacturing polycrystalline silicon thin-film solar cell by means of a method for crystallizing a large-area amorphous silicon thin film using a linear electron beam, the method comprising: a substrate preparation step for preparing a substrate; a type 1+ amorphous silicon layer deposition step for forming a type 1+ amorphous silicon layer on the substrate; a type 1 amorphous silicon layer deposition step for forming a type 1 amorphous silicon layer on the type 1+ amorphous silicon layer; an absorption layer formation step for forming an absorption layer by radiating a linear electron beam to the type 1 amorphous silicon layer and thus crystallizing the type 1 amorphous layer and the type 1+ amorphous silicon layer; a type 2 amorphous silicon layer deposition step for forming a type 2 amorphous silicon layer on the absorption layer; and an emitter layer formation step for forming an emitter layer by radiating a linear electron beam to the type 2 amorphous silicon layer and thus crystallizing the type 2 amorphous silicon layer, wherein the linear electron beam is radiated from above type 1 and type 2 amorphous silicon layers in a linear scanning manner in which to reciprocate in a predetermined area.

Abstract translation: 本发明的一个实施方案涉及通过使用线性电子束使大面积非晶硅薄膜结晶的方法制造多晶硅薄膜太阳能电池的方法，并且要解决的技术问题是使无定形 硅薄膜，其通过电子束形成在低价基板上，以便通过具有高结晶产率容易地获得高质量并在低温下进行处理。 为此，本发明的一个实施例提供一种利用线性电子束使大面积非晶硅薄膜结晶的方法制造多晶硅薄膜太阳能电池的方法，该方法包括： 制备底物的步骤; 1类非晶硅层沉积步骤，用于在衬底上形成1型非晶硅层; 1型非晶硅层沉积步骤，用于在1 +非晶硅层上形成1型非晶硅层; 吸收层形成步骤，用于通过将线性电子束照射到1型非晶硅层并因此使1型非晶层和1型非晶硅层结晶而形成吸收层; 用于在吸收层上形成2型非晶硅层的2型非晶硅层沉积步骤; 以及发射极层形成步骤，用于通过将线性电子束照射到2型非晶硅层并因此使2型非晶硅层结晶而形成发射极层，其中线性电子束从上述类型1和2型非晶硅 层，其以预定区域往复运动的线性扫描方式。

公开(公告)号：US11177502B2

公开(公告)日：2021-11-16

申请号：US16249687

申请日：2019-01-16

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Ho Sung Kim ,  Tae Won Kim ,  Duck Rye Chang ,  Jong Ho Lee ,  Kyeong Wan Kim ,  Min Young Kim

IPC: H01M10/0562 ,  H01M10/0525 ,  C04B35/486 ,  C04B35/626 ,  C04B35/50 ,  C04B35/64

Abstract: The method for manufacturing a solid electrolyte using an LLZ material for a lithium-ion battery comprises the steps of: providing a starting material in which lanthanum nitrate [La(NO3)3.6H2O] and zirconium nitrate [ZrO(NO3)2.6H2O] are mixed at a mole ratio of 3:2; forming an aqueous solution by dissolving the starting material; forming a precipitate by putting ammonia, which is a complex agent, and sodium hydroxide, which adjusts the pH of a reactor, into the aqueous solution, mixing the same, and then co-precipitating the mixture; forming a primary precursor powder by cleaning, drying and pulverizing the precipitate; forming a secondary precursor powder by mixing lithium powder [LiOH.H2O] with the primary precursor powder and ball-milling the mixture so as to solidify the lithium; and forming a solid electrolyte powder by heat-treating the secondary precursor powder.

公开(公告)号：US10886560B2

公开(公告)日：2021-01-05

申请号：US16072571

申请日：2016-11-15

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Ho Sung Kim ,  Min-Young Kim ,  Seung Hoon Yang ,  Da-Hye Kim ,  Kyeong Joon Kim ,  Seung Woo Choi ,  Jinsub Lim ,  Duck Rye Chang

IPC: H01M10/0562 ,  H01M10/052 ,  H01M4/62 ,  H01M10/058 ,  H01M4/505 ,  H01M4/525

Abstract: The present invention relates to an all-solid-state lithium secondary battery and a method of manufacturing the same. The all-solid-state lithium secondary battery includes a cathode, an anode, and a composite solid electrolyte layer between the cathode and the anode, wherein first and second LLZOs contained respectively in the cathode and the composite solid electrolyte layer are each independently aluminum-doped or undoped LLZO, and the battery of the invention can exhibit improved discharge capacity and cycle characteristics because both the cathode and the composite solid electrolyte layer contain a conductive polymer, a lithium salt and an inorganic ceramic solid electrolyte. The method of the invention enables the all-solid-state lithium secondary battery to be manufactured in a non-sintering manner, thus reducing manufacturing costs and controlling interfacial reactions between active materials, between solid electrolyte particles, and between an electrolyte and an electrode, thereby further reducing the internal resistance of the battery.