公开(公告)号：US09061894B2

公开(公告)日：2015-06-23

申请号：US14009502

申请日：2011-04-02

申请人： Lei Jiang ,  Bin Su ,  Shutao Wang ,  Jie Ma ,  Yanlin Song

发明人： Lei Jiang ,  Bin Su ,  Shutao Wang ,  Jie Ma ,  Yanlin Song

IPC分类号： B05D5/12 ,  B81C1/00 ,  H01L29/12 ,  B82Y10/00 ,  B82Y40/00 ,  H01L29/417 ,  H01L29/66 ,  H01L29/06 ,  H01L29/16 ,  H01L29/41 ,  B05D1/18 ,  C23C18/04 ,  C23C18/18 ,  B05D1/02 ,  C23C18/31 ,  B82Y30/00

CPC分类号： B81C1/00341 ,  B05D1/02 ,  B05D1/18 ,  B05D5/12 ,  B81B2203/0361 ,  B81C1/00206 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C23C18/04 ,  C23C18/18 ,  C23C18/31 ,  H01L29/0649 ,  H01L29/0673 ,  H01L29/125 ,  H01L29/16 ,  H01L29/413 ,  H01L29/41725 ,  H01L29/66439

摘要： Provided is a method of forming large-area directionally aligned nanowires on a silicon wafer surface with hydrophobic silicon pillars so as to form microelectrode-pair arrays, which belongs to the field of electronic circuit. The method includes grafting fluoroalkylsilane on the surface of a silicon wafer with hydrophilic silicon pillar arrays; increasing the contact angle between the surface of the hydrophilic silicon pillar arrays and water from 10° to 150° above and obtaining the silicon wafer with hydrophobic silicon pillar arrays; driving water solution containing materials used for forming nanowires to flow across the surface with the hydrophobic silicon pillar arrays uniformly, so that directionally aligned nanowires are formed on the tops of each two adjacent silicon pillars in the hydrophobic silicon pillar arrays; each of the nanowires connects the two adjacent silicon pillars together so as to form a microelectrode-pair, and a plurality of microelectrode-pairs constitute the microelectrode-pair arrays.

摘要翻译： 提供了一种在具有疏水硅柱的硅晶片表面上形成大面积定向排列的纳米线的方法，以形成属于电子电路领域的微电极对阵列。 该方法包括用亲水硅柱阵列在硅晶片的表面上接枝氟代烷基硅烷; 增加亲水硅柱阵列的表面与上述10°至150°之间的水的接触角，并获得具有疏水硅柱阵列的硅晶片; 含有用于形成纳米线的材料的驱动水溶液均匀地与疏水硅柱阵列一起流过表面，从而在疏水性硅柱阵列中的每两个相邻的硅柱的顶部上形成定向排列的纳米线; 每个纳米线将两个相邻的硅柱连接在一起以形成微电极对，并且多个微电极对构成微电极对阵列。

公开(公告)号：US20140120271A1

公开(公告)日：2014-05-01

申请号：US14009502

申请日：2011-04-02

申请人： Lei Jiang ,  Bin Su ,  Shutao Wang ,  Jie Ma ,  Yanlin Song

发明人： Lei Jiang ,  Bin Su ,  Shutao Wang ,  Jie Ma ,  Yanlin Song

IPC分类号： B81C1/00

CPC分类号： B81C1/00341 ,  B05D1/02 ,  B05D1/18 ,  B05D5/12 ,  B81B2203/0361 ,  B81C1/00206 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C23C18/04 ,  C23C18/18 ,  C23C18/31 ,  H01L29/0649 ,  H01L29/0673 ,  H01L29/125 ,  H01L29/16 ,  H01L29/413 ,  H01L29/41725 ,  H01L29/66439

摘要： Provided is a method of forming large-area directionally aligned nanowires on a silicon wafer surface with hydrophobic silicon pillars so as to form microelectrode-pair arrays, which belongs to the field of electronic circuit. The method includes grafting fluoroalkylsilane on the surface of a silicon wafer with hydrophilic silicon pillar arrays; increasing the contact angle between the surface of the hydrophilic silicon pillar arrays and water from 10° to 150° above and obtaining the silicon wafer with hydrophobic silicon pillar arrays; driving water solution containing materials used for forming nanowires to flow across the surface with the hydrophobic silicon pillar arrays uniformly, so that directionally aligned nanowires are formed on the tops of each two adjacent silicon pillars in the hydrophobic silicon pillar arrays; each of the nanowires connects the two adjacent silicon pillars together so as to form a microelectrode-pair, and a plurality of microelectrode-pairs constitute the microelectrode-pair arrays.

摘要翻译： 提供了一种在具有疏水硅柱的硅晶片表面上形成大面积定向排列的纳米线的方法，以形成属于电子电路领域的微电极对阵列。 该方法包括用亲水硅柱阵列在硅晶片的表面上接枝氟代烷基硅烷; 增加亲水硅柱阵列的表面与上述10°至150°之间的水的接触角，并获得具有疏水硅柱阵列的硅晶片; 含有用于形成纳米线的材料的驱动水溶液均匀地与疏水硅柱阵列一起流过表面，从而在疏水性硅柱阵列中的每两个相邻的硅柱的顶部上形成定向排列的纳米线; 每个纳米线将两个相邻的硅柱连接在一起以形成微电极对，并且多个微电极对构成微电极对阵列。

公开(公告)号：US09493672B2

公开(公告)日：2016-11-15

申请号：US14232610

申请日：2012-07-12

申请人： Yanlin Song ,  Ming Yang ,  Haihua Zhou ,  Lianming Yang ,  Gang Li

发明人： Yanlin Song ,  Ming Yang ,  Haihua Zhou ,  Lianming Yang ,  Gang Li

IPC分类号： C09D161/06 ,  B05D5/02 ,  C09D105/00 ,  C09D161/24 ,  C09D163/00 ,  C09D175/04 ,  C09D7/12 ,  C09D133/10 ,  C09D167/06 ,  C09D133/02 ,  C09D131/04 ,  C09D167/00 ,  B05D3/02 ,  B05D1/28 ,  B05D1/00 ,  C08K3/22 ,  C08K3/36 ,  C08K5/05 ,  C08K5/06 ,  C08K5/101

CPC分类号： C09D161/06 ,  B05D1/005 ,  B05D1/28 ,  B05D3/0254 ,  B05D5/02 ,  C08K3/22 ,  C08K3/36 ,  C08K5/05 ,  C08K5/06 ,  C08K5/101 ,  C08K2003/2213 ,  C08K2003/2227 ,  C08K2003/2241 ,  C08K2003/2296 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D105/00 ,  C09D131/04 ,  C09D133/02 ,  C09D133/10 ,  C09D161/24 ,  C09D163/00 ,  C09D167/00 ,  C09D167/06 ,  C09D175/04 ,  C09D129/14

摘要： A coating material for an aluminum substrate for inkjet computer-to-plate and preparation method and use of same. The composition of the coating material is: high polymer 5-40 wt %; nano-sized and/or micro-sized oxide particles 5-30 wt %; organic solvent constituting the remainder. The high polymer is at least one selected from the group consisting of MMA-BMA-MA terpolymer resin, phenolic resin, epoxy resin, polyurethane, polyester, urea-formaldehyde resin, polyvinyl formal, polyvinyl butyral and gum arabic. The preparation method for obtaining the coating material is to mix the ingredients together and stir at room temperature. A spin coating method or a roll coating method is used to coat the coating material onto a clean aluminum substrate having not undergone electrolytic graining and anodic oxidation treatment, and then the substrate is baked, resulting in the required roughness.

摘要翻译： 喷墨印刷电路板用铝基材用涂料及其制备方法和用途。 涂料的组成为：5-40重量％的高聚物; 5-30重量％的纳米尺寸和/或微尺寸氧化物颗粒; 构成其余部分的有机溶剂。 高聚物是选自MMA-BMA-MA三元共聚树脂，酚醛树脂，环氧树脂，聚氨酯，聚酯，脲 - 甲醛树脂，聚乙烯醇缩甲醛，聚乙烯醇缩丁醛和阿拉伯树胶中的至少一种。 获得涂料的制备方法是将成分混合在一起并在室温下搅拌。 使用旋涂法或辊涂法将涂料涂覆在没有进行电解砂化和阳极氧化处理的清洁铝基板上，然后烘烤基板，导致所需的粗糙度。

公开(公告)号：US20130131219A1

公开(公告)日：2013-05-23

申请号：US13814178

申请日：2010-10-25

申请人： Huiling Li ,  Mingming Qin ,  Yanlin Song

发明人： Huiling Li ,  Mingming Qin ,  Yanlin Song

IPC分类号： C09D11/00

CPC分类号： C09D11/30 ,  C09D11/10 ,  C09D11/38

摘要： Disclosed are a kind of ink used for ink-jet computer-to-plate (CTP) technology and the preparation method thereof. The ink comprises, in mass percent, 5% to 20% of cosslinkable resin, 5% to 25% of light solvent, and 55% to 90% of deionized water. The preparation method includes: mixing the components with stirring at room temperature; multistage filtering for removing insoluble substance and impurity in mixed solution after the crosslinkable resin being completely dissolved in the solvent; and thus to obtain the ink. An image with high resolution can be formed upon printing the ink on a treated aluminum plate and thermocuring. The aluminum plate can be printed directly by a printer, which reduces post treatment.

摘要翻译： 公开了一种用于喷墨计算机对板（CTP）技术的油墨及其制备方法。 该油墨以质量％计含有5％至20％的可切屑树脂，5％至25％的轻质溶剂和55％至90％的去离子水。 制备方法包括：在室温下搅拌混合组分; 在可交联树脂完全溶解在溶剂中后，用于除去混合溶液中的不溶物和杂质的多级过滤; 从而获得油墨。 在经处理​​的铝板上印刷油墨并进行热固化时，可以形成高分辨率的图像。 铝板可以直接由打印机打印，这样可以减少后处理。

公开(公告)号：US20120021129A1

公开(公告)日：2012-01-26

申请号：US13124658

申请日：2009-08-28

申请人： Haihua Zhou ,  Yanlin Song

发明人： Haihua Zhou ,  Yanlin Song

IPC分类号： B05D3/12 ,  B05D5/00 ,  C23C28/04 ,  B05D3/02

CPC分类号： B41N3/036 ,  B05D3/002 ,  B05D3/102 ,  B05D3/12 ,  B05D5/08 ,  B41N3/04

摘要： A method for preparing a metal substrate for inkjet CTP, comprising: treating a metal substrate by anodizing or non-anodizing (such as sandpaper burnishing, sand blasting, polishing, or brushing), and then applying a hydrophilic polymer paint on the surface of the metal substrate. Due to the existence of nano-size or micron-size oxide particles in the hydrophilic polymer paint, the metal substrate has high specific surface energy, while the metal substrate has a certain roughness, therefore the metal substrate has ink absorbency and good abrasive resistance. The metal substrate can reduce the spread of ink droplets and produces print image having better resolution and definition. The non-anodizing method can avoid environmental pollution which is caused by waste acid and waste alkali discharge of anodizing method.

摘要翻译： 一种制备用于喷墨CTP的金属基材的方法，包括：通过阳极氧化或非阳极氧化（例如砂纸抛光，喷砂，抛光或刷涂）处理金属基材，然后在亲水性聚合物涂料的表面上 金属基板。 由于在亲水性聚合物涂料中存在纳米尺寸或微米级氧化物颗粒，金属基材具有高的比表面积，而金属基材具有一定的粗糙度，因此金属基材具有油墨吸收性和良好的耐磨性。 金属基底可以减少墨滴的扩散，并产生具有更好分辨率和清晰度的印刷图像。 非阳极氧化方法可以避免由阳极氧化方法的废酸和废碱排放引起的环境污染。

公开(公告)号：US09127177B2

公开(公告)日：2015-09-08

申请号：US14343613

申请日：2012-09-07

申请人： Wei Wu ,  Haihua Zhou ,  Yanlin Song

发明人： Wei Wu ,  Haihua Zhou ,  Yanlin Song

IPC分类号： C09D11/02 ,  C09D11/03 ,  C09D11/328 ,  C09D11/10 ,  C09D11/30

CPC分类号： C09D11/03 ,  C09D11/10 ,  C09D11/30 ,  C09D11/32 ,  C09D11/328 ,  C09D11/38

摘要： A water-based ink for use in a computer-to-plate inkjet printing and a preparation method therefor. A polymer of 5 to 40 wt %, an additive of 0.01 to 10 wt %, a dye or pigment of 0.01 to 10 wt %, an organic solvent of 1 to 30 wt %, an anti-foaming agent of 0 to 5 wt %, and deionized water are stirred and mixed at room temperature. When the polymer is dissolved, the mixed solution is filtered. The filtrate is the water-based ink. The water-based ink is sprayed via a computer-to-plate machine onto a surface of a metal substrate (which may be an aluminum plate, a zinc plate, or a copper plate) to form a graphic region. A printing plate allowing for computer-to-plate printing is acquired after solidification. The printing plate acquired is allowed to achieve a halftone dot reproduction rate between 2 and 99% and a recognition rate of 175 lpi.

摘要翻译： 一种用于计算机对板式喷墨印刷的水性油墨及其制备方法。 5〜40重量％的聚合物，0.01-10重量％的添加剂，0.01至10重量％的染料或颜料，1至30重量％的有机溶剂，0至5重量％的消泡剂， ，去离子水在室温下搅拌混合。 当聚合物溶解时，过滤混合溶液。 滤液是水性油墨。 将水性油墨经由计算机对印版机喷涂到金属基板（可以是铝板，锌板，铜板）的表面上，形成图形区域。 在凝固后获得允许计算机对板印刷的印版。 获得的印版允许实现2至99％的半色调点再现速率和175 lpi的识别率。

公开(公告)号：US20140296382A1

公开(公告)日：2014-10-02

申请号：US14123508

申请日：2012-06-01

申请人： Haihua Zhou ,  Minxuan Kuang ,  Yanlin Song

发明人： Haihua Zhou ,  Minxuan Kuang ,  Yanlin Song

IPC分类号： C09D11/00

CPC分类号： C09D11/328 ,  C09D11/106

摘要： An ink used for direct inkjet printing to plate based on nanometer material and a method for preparing same. Of the baseline total amount of the ink, 5 to 30 wt % is of film-forming resin, 0.01 to 5 wt % is of nanometer or micrometer dye, 30 to 60 wt % is of organic solvent, 0.01 to 5 wt % is of humectant, and water provides the balance; these ingredients are stirred and mixed at room temperature, and after the film-forming resin is completely dissolved, impurities and/or insoluble substances in the present invention are removed by means of multi-level filtering, and the obtained filtrate is the present ink. The ink in the present invention is sprayed on a metal base material surface by an inkjet printer o form a printing pattern which, after curing, can be directly printed on the machine, thus reducing chemical pollution and post-processing processes, while a press run of the printing plate can be up to 100,000 copies at a resolution of up to 175 lpi.

摘要翻译： 用于直接喷墨印刷以基于纳米材料制版的油墨及其制备方法。 在油墨的基准总量中，5〜30重量％为成膜树脂，0.01〜5重量％为纳米或微米染料，30〜60重量％为有机溶剂，0.01〜5重量％为 保湿剂和水提供平衡; 将这些成分在室温下搅拌混合，在成膜树脂完全溶解后，通过多层过滤除去本发明的杂质和/或不溶性物质，得到的滤液为本发明的油墨。 通过喷墨打印机将本发明的油墨喷射在金属基材表面上，形成印刷图案，其在固化后可以直接印刷在机器上，从而减少化学污染和后处理过程，同时按压运行 的印版最高可达100,000张，分辨率高达175 lpi。

公开(公告)号：US09034430B2

公开(公告)日：2015-05-19

申请号：US13124658

申请日：2009-08-28

申请人： Haihua Zhou ,  Yanlin Song

发明人： Haihua Zhou ,  Yanlin Song

IPC分类号： B05D3/12 ,  B41N3/03 ,  B05D5/08 ,  B05D3/10 ,  B05D3/00 ,  B41N3/04

CPC分类号： B41N3/036 ,  B05D3/002 ,  B05D3/102 ,  B05D3/12 ,  B05D5/08 ,  B41N3/04

摘要： A method for preparing a metal substrate for inkjet CTP, comprising: treating a metal substrate by anodizing or non-anodizing (such as sandpaper burnishing, sand blasting, polishing, or brushing), and then applying a hydrophilic polymer paint on the surface of the metal substrate. Due to the existence of nano-size or micron-size oxide particles in the hydrophilic polymer paint, the metal substrate has high specific surface energy, while the metal substrate has a certain roughness, therefore the metal substrate has ink absorbency and good abrasive resistance. The metal substrate can reduce the spread of ink droplets and produces print image having better resolution and definition. The non-anodizing method can avoid environmental pollution which is caused by waste acid and waste alkali discharge of anodizing method.

摘要翻译： 一种制备用于喷墨CTP的金属基材的方法，包括：通过阳极氧化或非阳极氧化（例如砂纸抛光，喷砂，抛光或刷涂）处理金属基材，然后在亲水性聚合物涂料的表面上 金属基板。 由于在亲水性聚合物涂料中存在纳米尺寸或微米级氧化物颗粒，金属基材具有高的比表面积，而金属基材具有一定的粗糙度，因此金属基材具有油墨吸收性和良好的耐磨性。 金属基底可以减少墨滴的扩散，并产生具有更好分辨率和清晰度的印刷图像。 非阳极氧化方法可以避免由阳极氧化方法的废酸和废碱排放引起的环境污染。

公开(公告)号：US20130160666A1

公开(公告)日：2013-06-27

申请号：US13806700

申请日：2010-04-27

申请人： Haihua Zhou ,  Yanlin Song

发明人： Haihua Zhou ,  Yanlin Song

IPC分类号： C09D11/10 ,  B41C1/10

CPC分类号： B41C1/1066 ,  B41M5/0047 ,  B41M5/0058 ,  B41N1/003

摘要： A plate for inkjet computer-to-plate and an inkjet printing method are disclosed. The plate is obtained by coating adhesive on the surface of metallic base followed by coating ink repulsive liquid, and a polymer film can be further covered on the obtained plate as protective layer. The adhesive improves the adhesion force between the metallic base and the ink repulsive layer, and the obtained ink repulsive layer is not sticky to the printing ink during printing. Therefore, without undergoing the treatments of electrolytic graining and anodizing, the plate of the present invention can achieve excellent printing durability and high resolution, thereby avoiding serious environmental pollution of the waste acid solution and waste base solution produced in the process of electrolytic graining and anodizing.

摘要翻译： 公开了一种用于喷墨计算机板和喷墨打印方法的板。 通过在金属基材的表面上涂布粘合剂，然后涂布油墨排斥液而获得该板，并且可以在获得的板上进一步覆盖聚合物膜作为保护层。 粘合剂改善了金属基底和油墨排斥层之间的粘合力，并且所得到的油墨排斥层在印刷过程中不会粘附到印刷油墨上。 因此，在不进行电解粗面化和阳极氧化处理的情况下，本发明的板可以获得优异的印刷耐久性和高分辨率，从而避免在电解砂化和阳极氧化过程中产生的废酸溶液和废碱溶液的严重环境污染 。

公开(公告)号：US08372484B2

公开(公告)日：2013-02-12

申请号：US12864607

申请日：2009-01-21

申请人： Min He ,  Yanlin Song ,  Biqian Liu

发明人： Min He ,  Yanlin Song ,  Biqian Liu

IPC分类号： B05D3/02

CPC分类号： C09D133/066 ,  B05D5/04 ,  B05D5/08 ,  B05D2202/25 ,  C08L23/02 ,  C08L23/10 ,  C08L33/066 ,  C08L33/08 ,  C08L33/12 ,  C08L33/16 ,  C08L2205/03 ,  C09D5/00 ,  C09D133/08 ,  C09D133/12 ,  C09D133/16 ,  F25D23/065 ,  Y02P20/124 ,  C08L2666/06 ,  C08L2666/04

摘要： The present invention provides an anti-frost coating, which forms a coat having a hydrophilic and hydrophobic composite structure after being applied on a substrate, and contains a hydrophobic polymer and a hydrophilic polymer. The application method of the anti-frost coating comprises: dissolving the hydrophilic polymer and the hydrophobic polymer in a solvent to form a homogeneous solution, coating the solution on a substrate to form a film, drying and curing to form an anti-frost coat with a hydrophilic and super-hydrophobic composite structure including a super-hydrophobic surface layer and a hydrophilic inner layer. Water drips can roll off easily and the dust and impurities deposited on the surface can be easily removed. The anti-frost effect is desirable.

摘要翻译： 本发明提供一种防霜涂层，其在涂布在基材上后形成具有亲水和疏水复合结构的涂层，并且含有疏水性聚合物和亲水性聚合物。 防霜涂层的应用方法包括：将亲水性聚合物和疏水性聚合物溶解在溶剂中以形成均匀溶液，将溶液涂布在基材上以形成膜，干燥和固化以形成具有 包含超疏水表面层和亲水性内层的亲水和超疏水复合结构。 水滴可能容易脱落，沉积在表面上的灰尘和杂质可以很容易地去除。 防霜效果是可取的。