摘要:
The invention relates to a process for the preparation of thermoplastic molding materials comprising A) from 39 to 99% by weight of at least one thermoplastic polymer, B) from 1 to 60% by weight of a flameproofing component comprising B1) an expandable graphite, and C) from 0 to 60% by weight of further additives, the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight, by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction, wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises substantially no shearing elements, and thermoplastic molding materials which can be prepared by these processes, the use of said thermoplastic molding materials for the production of fibers, films, moldings and foams, and these fibers, films, moldings and foams themselves.
摘要:
The invention relates to a process for the preparation of thermoplastic molding materials comprising A) from 39 to 99% by weight of at least one thermoplastic polymer, B) from 1 to 60% by weight of a flameproofing component comprising B1) an expandable graphite, and C) from 0 to 60% by weight of further additives, the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight, by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction, wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises substantially no shearing elements, and thermoplastic molding materials which can be prepared by these processes, the use of said thermoplastic molding materials for the production of fibers, films, moldings and foams, and these fibers, films, moldings and foams themselves.
摘要:
Use of thermoplastic molding compositions comprising, as essential components, A) a polyester, B) from 20 to 200 mmol/kg of polyester A) of at least one compound of the general formula (I) where respectively independently at any position -A1- is —NR—, —O—, —S—, —CH=A4- where R is H or C1-6-alkyl, A4 is N or CH A2 is COOX or OX, where X is Li, Na, K, Rb, Cs, Mg/2, Ca/2, Sr/2, Ba/2, Al/3 A3 is C1-6-alkyl, C6-12-aryl, O7-13-alkaryl, C7-13-aralkyl, O—C1-6-alkyl, O—C6-12-aryl, O—C7-13-alkaryl, O—C7-13-aralkyl, COOX′, OX′, SX′, SO3X′, where X′ is H or X, S—C1-6-alkyl, S—C6-12-aryl, NR2, halogen, NO2, n is an integer from 1 to 4, and m is an integer from 0 to 4−n, where m=1, if A3=NO2, with the proviso that the number of mmol is based on the group(s) COOX and OX and SX′ where X′═X, to the extent that these are present in the compound of the general formula (I), and also moreover C) from 0 to 230% by weight of further added substances, based on the weight of component A), for producing laser-transparent moldings of any type.
摘要:
Sheet-like moldings or foils with anisotropic coefficients of thermal expansion are produced from extrudable thermoplastic polymer molding compositions by filling the thermoplastic polymer molding compositions with lamellar phyllosilicates whose diameter is in the range from 10 to 1000 nm and whose aspect ratio is in the range from 1:5 to 1:10 000 and extruding the filled thermoplastic polymer molding compositions, and then monoaxially or biaxially orienting the extrudate to give sheet-like moldings or foils.
摘要:
Thermoplastic molding composition comprising components A, B, C and D and, if appropriate, E, F, G and H, A) from 1 to 97.5% by weight of at least one aromatic polycarbonate A, B) from 1 to 97.5% by weight of at least one graft polymer B made from b1) from 40 to 80% by weight of a graft base made from an elastomeric polymer B1, b2) from 20 to 60% by weight of a graft B2 made from b21) from 60 to 95% by weight of styrene or of substituted styrenes B21 and b22) from 5 to 40% by weight of at least one unsaturated nitrile B22, C) from 1 to 97.5% by weight of at least one thermoplastic copolymer C made from c1) from 60 to 85% by weight of styrene or of substituted styrenes C1 or mixtures thereof and c2) from 15 to 40% by weight of at least one unsaturated nitrile C2, D) from 0.5 to 50% by weight of at least one copolymer D, obtainable via reaction of d1) from 5 to 95% by weight of at least one thermoplastic methacrylate polymer D1 containing at least one type of functional groups selected from epoxy, carboxy, hydroxy, anhydride and oxazoline, with d2) from 5 to 95% by weight of at least one thermoplastic polyester D2, E) from 0 to 40% by weight of at least one filler E, F) from 0 to 2% by weight of at least one organic acid F, G) from 0 to 25% by weight of at least one halogen-free phosphorus compound G, H) from 0 to 45% by weight of other additives H.
摘要:
Flame-retardant thermoplastic molding materials containing A) at least one polyphenylene ether, B) at least one vinylaromatic polymer, and C) at least one flameproofing agent furthermore comprise D) as an antidrip agent, a high molecular weight polymer based on acrylamide having a viscosity of more than about 1.5 mpas, measured in 0.1% strength aqueous solution at 25° C., and are used for the production of fibers, films and moldings.
摘要:
Flame-retardant thermoplastic molding materials contain A) from 5 to 97.7% by weight of a polyphenylene ether, B) from 1 to 93.7% by weight of vinylaromatic polymers, C) from 0 to 50% by weight of impact modifiers, D) from 0.3 to 20% by weight of sheet silicates which contain one or more nitrogen-containing compounds in amounts of from 0.1 to 50% by weight, based on the sheet silicates, E) from 1 to 20% by weight of a flameproofing agent and F) from 0 to 60% by weight of further additives.
摘要:
A curable impact modified epoxy resin mixture suitable for producing high performance composites is composed ofA. an aromatic epoxy compound,B. an amine type curing agent,C. from 10 to 40% by weight of an aromatic thermoplastic oligomer which contains reactive groups, preferably a polyether sulfone, andD. from 0.1 to 10% by weight of a high molecular weight emulsifier, preferably a phenoxy resin, an epoxy resin or a thermoplastic copolymer, which is compatible not only with the epoxy compound A but also with oligomer C.
摘要:
Thermoplastic molding materials based on styrene polymers modified to be impact resistant with EPDM rubbers and polyphenylene ethers wherein the particles of the flexible components of the impact resistant styrene polymer have an average particle diameter range of 0.3 to 0.7 microns.
摘要:
The invention relates to a blow molding having capacity of at least 250 ml, its shell being composed of polystyrene and being produced via injection stretch blow molding.The invention moreover relates to the process for production of this blow molding and to the use of the blow moldings.