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1.发明授权Method for intercalating organic-swelled layered metal chalcogenide with polymer chalcogenide by treatment with polymeric chalcogenide precursor in inert atmosphere 失效通过在惰性气氛中用聚合硫族化物前体处理来将有机溶胀的层状金属硫族化物与聚合物硫族化物嵌入的方法
公开(公告)号：US4929587A
公开(公告)日：1990-05-29
申请号：US314611
申请日：1989-02-23
IPC分类号： B01J20/10 , B01J21/06 , B01J29/04 , C01B13/14 , C01B33/32 , C01B33/38 , C01B33/44 , C01G23/00
CPC分类号： B01J29/049 , B01J21/063 , C01B13/145 , C01G23/003 , C01P2002/72 , C01P2006/10 , C01P2006/12
摘要： Organic-swelled layered metal chalcogenide is intercalated with polymeric chalcogenide by contacting with a hydrolyzable polymeric chalcogenide precursor under an inert atmosphere, e.g., nitrogen to minimize formation of extralaminar polymeric chalcogenide. The chalcogenide precursor is then hydrolyzed.
摘要翻译： 有机溶胀的层状金属硫族化物通过在惰性气氛例如氮气下与可水解的聚合硫族化物前体接触来插入聚合物硫族化物，以最小化外部层状聚合硫族化物的形成。 然后硫化物前体被水解。
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2.发明授权
公开(公告)号：US4980333A
公开(公告)日：1990-12-25
申请号：US375650
申请日：1989-07-05
IPC分类号： B01J21/08 , B01J29/04 , C01B13/14 , C01B17/20 , C01B17/42 , C01B19/00 , C01G23/00 , C07C2/08 , C07C2/10
CPC分类号： B01J29/049 , C01B13/145 , C01B17/20 , C01B17/42 , C01B19/007 , C01G23/003 , C07C2/08 , C07C2/10 , C01P2002/02 , C01P2002/22 , C01P2002/70 , C01P2002/72 , C01P2002/74 , C01P2002/78 , C01P2006/12 , C01P2006/42 , C01P2006/80 , C07C2521/06 , C07C2521/08 , C07C2521/12 , Y10S502/525
摘要： Perovskite related materials of high thermal stability and surface area which contain interspathic polymeric chalcogenides such as polymeric silica are prepared by ion exchanging a layered metal oxide, such as layered titanium oxide, with organic cation, to spread the layers apart. A compound such as tetraethylorthosilicate, capable of forming a polymeric oxide, is thereafter introduced between the layers. The resulting product is treated to form polymeric oxide, e.g. by hydrolysis, to produce the layered oxide material. The resulting product may be employed as catalyst material in the conversion of organic compounds.
摘要翻译： 通过将层状金属氧化物（例如层状氧化钛）与有机阳离子交换来分层，制备含有聚合硫化物如聚合二氧化硅的高热稳定性和表面积的钙钛矿相关材料。 然后在层之间引入能够形成聚合氧化物的化合物如原硅酸四乙酯。 将所得产物处理形成聚合物氧化物，例如 通过水解制备层状氧化物材料。 所得产物可用作有机化合物转化中的催化剂材料。
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3.发明授权
公开(公告)号：US4859648A
公开(公告)日：1989-08-22
申请号：US879787
申请日：1986-06-27
申请人： Michael E. Landis , Brent A. Aufdembrink , Pochen Chu , Ivy D. Johnson , Garry W. Kirker , Nancy M. Page , Mae K. Rubin
发明人： Michael E. Landis , Brent A. Aufdembrink , Pochen Chu , Ivy D. Johnson , Garry W. Kirker , Nancy M. Page , Mae K. Rubin
IPC分类号： B01J21/16 , A47G9/00 , B01J20/06 , B01J20/10 , B01J20/18 , B01J27/04 , B01J29/03 , B01J29/04 , B01J35/02 , B68G7/00 , C01B13/14 , C01B17/20 , C01B17/42 , C01B19/00 , C01B33/20 , C01B33/26 , C01B33/36 , C01B33/40 , C01B33/44 , C01B37/00 , C01B37/02 , C01B39/00 , C01B39/04 , C01B39/06 , C01B39/26 , C01G1/00 , C01G23/00 , C01G33/00 , C07B61/00 , C07C1/00 , C07C2/02 , C07C2/08 , C07C2/10 , C07C11/00 , C07C67/00 , C10G11/02 , C10G17/00 , C10G45/04 , C10G47/04 , C10G47/06
CPC分类号： B01J29/049 , B82Y30/00 , C01B13/145 , C01B17/20 , C01B17/42 , C01B19/007 , C01G23/003 , C07C2/08 , C07C2/10 , C10G45/04 , C01P2002/02 , C01P2002/22 , C01P2002/70 , C01P2002/72 , C01P2002/74 , C01P2002/78 , C01P2006/12 , C01P2006/42 , C01P2006/80 , C07C2521/06 , C07C2521/08 , C07C2521/12
摘要： Layered chalcogenide materials of high thermal stability and surface area which contain interspathic polymeric chalcogenides such as polymeric silica are prepared by ion exchanging a layered metal oxide, such as layered titanium oxide, with organic cation, to spread the layers apart. A compound such as tetraethylorthosilicate, capable of forming a polymeric oxide, is thereafter introduced between the layers. The resulting product is treated to form polymeric oxide, e.g. by hydrolysis, to produce the layered oxide material. The resulting product may be employed as catalyst material in the conversion of organic compounds.
摘要翻译： 通过将层状金属氧化物（例如层状氧化钛）与有机阳离子交换来分层，制备含有聚合硫化物如聚合二氧化硅的高热稳定性和表面积的分层硫属化物材料。 然后在层之间引入能够形成聚合氧化物的化合物如原硅酸四乙酯。 将所得产物处理形成聚合物氧化物，例如 通过水解制备层状氧化物材料。 所得产物可用作有机化合物转化中的催化剂材料。
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公开(公告)号：US4912277A
公开(公告)日：1990-03-27
申请号：US358105
申请日：1989-05-30
IPC分类号： B01J29/04 , C07C2/66 , C07C15/02 , C10M105/06
CPC分类号： B01J29/049 , C07C2/66 , C10M105/06 , C07C2521/06 , C07C2523/04 , C10M2203/06
摘要： Relatively long chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively long chain alkylating agent under alkylation reaction conditions in the pressure of a layered material as an alkylation catalyst. The layered material contains titanate in the layers and oxide pillars separating the layers. The layers also contain vacancies and/or metals incorporated therein.
摘要翻译： 通过在作为烷基化催化剂的层状材料的压力下的烷基化反应条件下用相对长链烷基化剂烷基化可烷基化芳族化合物来制备相对长链烷基芳族化合物。 层状材料在层中含有钛酸盐和分离层的氧化物柱。 这些层还含有掺入其中的空位和/或金属。
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公开(公告)号：US4895638A
公开(公告)日：1990-01-23
申请号：US339284
申请日：1989-04-17
摘要： A process for the catalytic cracking of heavy petroleum fractions into lower hydrocarbons, such as fuel products. The process comprises contacting the petroleum fractions at an elevated temperature with a cracking catalyst comprising (a) a layered metal oxide of the titanometallate type intercalated with an interspathic polymeric chalcogenide, e.g., polymeric silica and, optionally (b) a porous crystalline silicate component such as a large pore zeolite material.
摘要翻译： 将重质石油馏分催化裂化成低级烃，如燃料产品的方法。 该方法包括在升高的温度下使石油馏分与裂解催化剂接触，所述裂化催化剂包含（a）层状金属氧化物，金属螯合物层状金属氧化物，其插入有间位聚合硫属化物，例如聚合二氧化硅，和任选地（b）多孔结晶硅酸盐组分， 作为大孔沸石材料。
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公开(公告)号：US5137707A
公开(公告)日：1992-08-11
申请号：US780190
申请日：1991-10-22
CPC分类号： B01J29/049 , B01J20/12
摘要： There is provided a method for the removal of residual organic swelling agent from pillared layered materials by treating such materials with acid.
摘要翻译： 提供了通过用酸处理这种材料来从柱状分层材料中除去残留的有机溶胀剂的方法。
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7.发明授权Aromatization process and catalyst utilizing a mixture of shape-selective porous crystalline silicate zeolite and pillared layered metal oxide 失效使用形状选择性多孔结晶硅酸盐沸石和柱状层状金属氧化物的混合物的芳构化方法和催化剂
公开(公告)号：US4933310A
公开(公告)日：1990-06-12
申请号：US314606
申请日：1989-02-23
CPC分类号： C10G35/095 , B01J29/049 , B01J29/40 , B01J29/405 , B01J29/44 , B01J29/80 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70
摘要： A catalyst composition suitable for use in aromatization of non-aromatic hydrocarbons comprises a shape-selective crystalline silicate such as ZSM-5 and a titanometallate-type layered metal oxide comprising a layered metal oxide and pillars of an oxide of at least one element selected from Groups IB, IIB, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIIA and VIIIA of the Periodic Table of the Elements separating the layers of the metal oxide where each layer of the metal oxide has the general formula[M.sub.x .quadrature..sub.y Z.sub.2-(x+y) O.sub.4 ].sup.q-wherein M is at least one metal of valence n wherein n is an integer between 0 and 7, .quadrature.represents a vacancy site, Z is a tetravalent metal, and whereinq=4y-x(n-4)O
摘要翻译： 适用于非芳族烃芳构化的催化剂组合物包括形状选择性结晶硅酸盐，例如ZSM-5和金属金属盐型层状金属氧化物，其包含层状金属氧化物和选自以下的至少一种元素的氧化物柱 分离金属氧化物层的元素周期表的IB，IIB，IIIA，IIIB，IVA，IVB，VA，VB，VIA，VIIA和VIIIA，其中每层金属氧化物具有通式[Mx＆ y Z2-（x + y）O4] q-其中M是价数n的至少一种金属，其中n是0和7之间的整数，并且表示空位，Z是四价金属，并且其中q = 4y- x（n-4）O
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公开(公告)号：US20090126602A1
公开(公告)日：2009-05-21
申请号：US12281931
申请日：2007-03-07
CPC分类号： C09B67/0063 , C09B67/0073 , C09B67/0084 , C09B67/0097 , F42B6/10 , F42B8/14 , Y10T428/13 , Y10T428/2984
摘要： Disclosed are improved colorant compositions that are suitable for encapsulation in an impact-rupturable casing that is adapted for intact projectile motion and rupture upon contact with a target surface. In many embodiments, the colorant compositions comprise (a) a carrier comprising: (i) a metathesized unsaturated polyol ester; and (ii) a polyol ester; and (b) a colorant. The colorant compositions are useful in paint balls for use in conjunction with projectile devices, such as paint ball markers.
摘要翻译： 公开了适于封装在可冲击破裂套管中的改进的着色剂组合物，其适用于在与目标表面接触时完好的弹丸运动和破裂。 在许多实施方案中，着色剂组合物包含（a）载体，其包含：（i）复分解的不饱和多元醇酯; 和（ii）多元醇酯; 和（b）着色剂。 着色剂组合物可用于与抛射装置如油漆球标记物结合使用的油漆球中。
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公开(公告)号：US5258114A
公开(公告)日：1993-11-02
申请号：US735227
申请日：1991-07-24
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： B01J29/005 , B01D53/8628 , B01J20/16 , B01J20/18 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42 , B01J29/084 , B01J29/405 , B01J29/65 , B01J29/7026 , B01J29/703 , B01J29/7034 , B01J29/7038
摘要： A process and catalyst for catalytic cracking comprising a non-layered, ultra-large pore crystalline material. The crystalline material preferably has a benzene adsorption capacity greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C. Preferred materials have a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units. Preferred cracking catalysts comprise ultra-large pore materials having pore openings formed by at least 20 tetrahedrally coordinated members, most preferably with 36 or 42 tetahedrally coordinated members.
摘要翻译： 一种用于催化裂化的方法和催化剂，包括非层状的超大孔结晶材料。 结晶材料优选在50托和25℃下具有大于约15克苯/ 100克的苯吸附能力。优选的材料具有六角形电子衍射图，其可以以大于约18埃单位的d100值进行索引，并且 具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。 优选的裂化催化剂包括具有由至少20个四面体配位的构件形成的孔隙的超大孔材料，最优选地具有36或42个四面体配位的构件。
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公开(公告)号：US4902392A
公开(公告)日：1990-02-20
申请号：US139545
申请日：1987-12-30
摘要： A catalytic hydrocracking process for use in refining various petroleum based feedstocks to lighter hydrocarbons. The hydrocracking process for treatment of petroleum fractions utilizes a catalyst comprising (a) a layered metal oxide of the titanometallate type intercalated with an interspathic polymeric chalcogenide, e.g., polymeric silica, (b) a transition hydrogenation metal selected from Group IVA, VIA, and VIIIA of the Periodic Table such as platinum and the like, and optionally, (c) a conventional cracking component, e.g., a large pore crystalline silicate component.
摘要翻译： 用于将各种石油基原料精炼成轻质烃的催化加氢裂化方法。 用于处理石油馏分的加氢裂化方法使用催化剂，其包含（a）层状金属螯合物层状金属氧化物，其中嵌入有层状聚合硫族化物，例如聚合二氧化硅，（b）选自IVA族，VIA族和 周期表的VIIIA，例如铂等，和任选地，（c）常规的裂化组分，例如大孔结晶硅酸盐组分。
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