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公开(公告)号：US09315430B2
公开(公告)日：2016-04-19
申请号：US13658851
申请日：2012-10-24
IPC分类号： C07C4/04 , C07C4/02 , C07C2/02 , C07C11/00 , F23L15/02 , B01J19/02 , B01J19/24 , B01J4/00 , B01J8/04 , C10G9/18 , C10G9/26 , B01J12/00
CPC分类号： C10G9/18 , B01J4/004 , B01J8/0423 , B01J8/0438 , B01J8/0442 , B01J8/0453 , B01J8/0457 , B01J19/02 , B01J19/2485 , B01J2208/00106 , B01J2208/00309 , B01J2208/00327 , B01J2208/00495 , B01J2208/0053 , B01J2208/00911 , B01J2219/0004 , B01J2219/00117 , B01J2219/00121 , B01J2219/00139 , B01J2219/00155 , B01J2219/00159 , B01J2219/0281 , B01J2219/182 , B01J2219/185 , B01J2219/1923 , B01J2219/194 , B01J2219/1943 , B01J2219/1947 , C07C4/04 , C10G9/26 , F23L15/02 , Y02E20/348
摘要： The present disclosure relates to reactor components and their use, e.g., in regenerative reactors. A process and apparatus for utilizing different wetted areas along the flow path of a fluid in a pyrolysis reactor, e.g., a thermally regenerating reactor, such as a regenerative, reverse-flow reactor, is described.
摘要翻译： 本公开涉及反应器组件及其在再生反应器中的用途。 描述了在热解反应器（例如再生反应器，例如再生逆流反应器）中沿着流体的流动路径利用不同润湿区域的方法和装置。
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公开(公告)号：US20130150644A1
公开(公告)日：2013-06-13
申请号：US13658851
申请日：2012-10-24
IPC分类号： C07C4/04
CPC分类号： C10G9/18 , B01J4/004 , B01J8/0423 , B01J8/0438 , B01J8/0442 , B01J8/0453 , B01J8/0457 , B01J19/02 , B01J19/2485 , B01J2208/00106 , B01J2208/00309 , B01J2208/00327 , B01J2208/00495 , B01J2208/0053 , B01J2208/00911 , B01J2219/0004 , B01J2219/00117 , B01J2219/00121 , B01J2219/00139 , B01J2219/00155 , B01J2219/00159 , B01J2219/0281 , B01J2219/182 , B01J2219/185 , B01J2219/1923 , B01J2219/194 , B01J2219/1943 , B01J2219/1947 , C07C4/04 , C10G9/26 , F23L15/02 , Y02E20/348
摘要： The present disclosure relates to reactor components and their use, e.g., in regenerative reactors. A process and apparatus for utilizing different wetted areas along the flow path of a fluid in a pyrolysis reactor, e.g., a thermally regenerating reactor, such as a regenerative, reverse-flow reactor, is described.
摘要翻译： 本公开涉及反应器组件及其在再生反应器中的用途。 描述了在热解反应器（例如再生反应器，例如再生逆流反应器）中沿着流体的流动路径利用不同润湿区域的方法和装置。
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3.发明申请Method and Apparatus for Managing Hydrogen Content Through The Conversion of Hydrocarbons Into Olefins 有权通过将碳氢化合物转化成烯烃来控制氢含量的方法和装置公开(公告)号：US20140163287A1
公开(公告)日：2014-06-12
申请号：US13994461
申请日：2011-12-20
IPC分类号： C07C4/04
摘要： An apparatus and method are provided for processing hydrocarbon feeds. The method enhances the conversion of hydrocarbon feeds into conversion products, such as ethylene and propylene. In particular, the present techniques combine a first hydrocarbon feed with a second hydrocarbon feed and a hydrogen (H2) containing stream to manage the hydrogen content of the feed provided to a pyrolysis reactor. The mixture is then exposed to high-severity operating conditions in a pyrolysis reactor and further processing into desired olefins.
摘要翻译： 提供了一种用于处理烃进料的装置和方法。 该方法增强了烃进料转化成转化产物，如乙烯和丙烯。 特别地，本技术结合了第一烃进料与第二烃进料和含氢（H 2）的流，以控制提供给热解反应器的进料的氢含量。 然后将混合物在热解反应器中暴露于高苛刻度的操作条件，并进一步加工成所需的烯烃。
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公开(公告)号：US20140296597A1
公开(公告)日：2014-10-02
申请号：US13993515
申请日：2011-12-20
CPC分类号： C07C5/09 , B01J19/0053 , C10G9/00 , C10G9/002 , C10G9/007 , C10G9/18 , C10G9/20 , C10G9/38 , C10G47/00 , C07C11/04
摘要： An apparatus and method are provided for processing hydrocarbon feeds. The method enhances the conversion of hydrocarbon feeds into conversion products, such as ethylene. In particular, the present techniques utilize a high-severity thermal pyrolysis reactor that exposes a feed at a peak pyrolysis gas temperature ≧1540° C. to produce a reactor product comprising ethylene and acetylene and has a C3+ to acetylene weight ratio ≦0.5. Then, the method separates a product comprising tars and/or solids from at least a portion of the reactor product and converts at least a portion of the remaining reactor product into a conversion product, such as ethylene.
摘要翻译： 提供了一种用于处理烃进料的装置和方法。 该方法增强了烃进料转化为转化产物如乙烯。 特别地，本技术利用高严重性的热解热解反应器，其在峰值热解气体温度≥1540℃下暴露进料，以产生包含乙烯和乙炔的反应器产物，并且具有C3 +与乙炔重量比＆nlE; 0.5。 然后，该方法将含有焦油和/或固体的产物与反应器产物的至少一部分分离，并将至少一部分剩余的反应器产物转化为转化产物如乙烯。
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公开(公告)号：US09676681B2
公开(公告)日：2017-06-13
申请号：US13994461
申请日：2011-12-20
IPC分类号： C07C4/04
摘要： An apparatus and method are provided for processing hydrocarbon feeds. The method enhances the conversion of hydrocarbon feeds into conversion products, such as ethylene and propylene. In particular, the present techniques combine a first hydrocarbon feed with a second hydrocarbon feed and a hydrogen (H2) containing stream to manage the hydrogen content of the feed provided to a pyrolysis reactor. The mixture is then exposed to high-severity operating conditions in a pyrolysis reactor and further processing into desired olefins.
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公开(公告)号：US20140303418A1
公开(公告)日：2014-10-09
申请号：US13994433
申请日：2011-12-20
CPC分类号： C07C2/78 , C07C2/06 , C07C4/06 , C07C5/09 , C07C7/00 , C07C7/14858 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C10G50/00 , C10G2300/1025 , C10G2300/202 , C10G2300/207 , C10G2400/20 , C10G2400/22 , C10G2400/24 , Y02P30/40 , C07C11/24 , C07C11/04
摘要： The invention relates to processes for converting a mixture of hydrocarbon and sulfur-containing molecules such as mercaptan into products comprising acetylene, ethylene, and hydrogen sulfide, to processes utilizing the acetylene and ethylene resulting from the conversion, and to equipment useful for such processes.
摘要翻译： 本发明涉及将烃和含硫分子如硫醇的混合物转化成包含乙炔，乙烯和硫化氢的产物的方法，以利用由转化产生的乙炔和乙烯的方法，以及可用于这些方法的设备。
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公开(公告)号：US09708232B2
公开(公告)日：2017-07-18
申请号：US13993515
申请日：2011-12-20
CPC分类号： C07C5/09 , B01J19/0053 , C10G9/00 , C10G9/002 , C10G9/007 , C10G9/18 , C10G9/20 , C10G9/38 , C10G47/00 , C07C11/04
摘要： An apparatus and method are provided for processing hydrocarbon feeds. The method enhances the conversion of hydrocarbon feeds into conversion products, such as ethylene. In particular, the present techniques utilize a high-severity thermal pyrolysis reactor that exposes a feed at a peak pyrolysis gas temperature ≧1540° C. to produce a reactor product comprising ethylene and acetylene and has a C3+ to acetylene weight ratio ≦0.5. Then, the method separates a product comprising tars and/or solids from at least a portion of the reactor product and converts at least a portion of the remaining reactor product into a conversion product, such as ethylene.
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公开(公告)号：US09512048B2
公开(公告)日：2016-12-06
申请号：US14117374
申请日：2012-05-31
CPC分类号： C07C2/78 , C07C2/76 , C07C5/09 , C07C7/005 , C07C7/148 , C07C2529/068 , C08F110/02 , C10G50/00 , C07C11/24 , C07C11/04
摘要： The invention relates to processes for converting a mixture of hydrocarbon and sulfur-containing molecules such as mercaptan into products comprising acetylene, ethylene, and hydrogen sulfide, to processes utilizing the acetylene and ethylene resulting from the conversion, and to equipment useful for such processes.
摘要翻译： 本发明涉及将烃和含硫分子如硫醇的混合物转化成包含乙炔，乙烯和硫化氢的产物的方法，以利用由转化产生的乙炔和乙烯的方法，以及可用于这些方法的设备。
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公开(公告)号：US09663419B2
公开(公告)日：2017-05-30
申请号：US13994433
申请日：2011-12-20
CPC分类号： C07C2/78 , C07C2/06 , C07C4/06 , C07C5/09 , C07C7/00 , C07C7/14858 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C10G50/00 , C10G2300/1025 , C10G2300/202 , C10G2300/207 , C10G2400/20 , C10G2400/22 , C10G2400/24 , Y02P30/40 , C07C11/24 , C07C11/04
摘要： The invention relates to processes for converting a mixture of hydrocarbon and sulfur-containing molecules such as mercaptans into products comprising acetylene, ethylene, and hydrogen sulfide, to processes utilizing the acetylene and ethylene resulting from the conversion, and to equipment useful for such processes.
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公开(公告)号：US20100288617A1
公开(公告)日：2010-11-18
申请号：US12576002
申请日：2009-10-08
IPC分类号： C10B57/16 , C04B35/01 , B01J8/00 , B01J19/00 , C10B23/00 , C10G9/00 , C10B47/00 , C10B1/00 , C07C4/04 , C07C4/06
CPC分类号： C04B35/488 , B01J4/002 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J19/02 , B01J19/2485 , B01J2208/00115 , B01J2208/00309 , B01J2208/00504 , B01J2208/0084 , B01J2208/00849 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/0263 , C04B35/486 , C04B35/505 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/528 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/5481 , C04B2235/6021 , C04B2235/658 , C04B2235/6584 , C04B2235/72 , C04B2235/762 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , C04B2235/9669 , C04B2235/9684 , C10G1/02 , C10G9/00 , C10G9/005 , C10G9/18 , C10G9/26 , C10G75/00 , Y02P20/582
摘要： In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and that remains in oxide form when exposed to a gas having a carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.
摘要翻译： 在一个方面，本发明包括用于热解烃原料的反应器装置，该装置包括：反应器组件，其包含氧化物形式的耐火材料，耐火材料的熔点至少为2060℃，并保留在氧化物 当暴露于碳分压为10-22巴，氧气分压为10-10巴的气体时，在1200℃的温度下形成。在一些实施方案中，反应器包括再生热解反应器装置，在其它实施方案中 它包括逆流再生反应器装置。 在其他方面，本发明包括使用热解反应器系统热解烃原料的方法，该方法包括在加热区域中提供用于热解烃原料的热解反应器系统，包括氧化物形式的耐火材料的装置，耐火材料 材料具有至少2060℃的熔点，并且当暴露于碳分压为10-22巴，氧分压为10-10巴的气体时，在1200℃的温度下保持为氧化物形式 C。
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