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公开(公告)号:US20100288617A1
公开(公告)日:2010-11-18
申请号:US12576002
申请日:2009-10-08
IPC分类号: C10B57/16 , C04B35/01 , B01J8/00 , B01J19/00 , C10B23/00 , C10G9/00 , C10B47/00 , C10B1/00 , C07C4/04 , C07C4/06
CPC分类号: C04B35/488 , B01J4/002 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J19/02 , B01J19/2485 , B01J2208/00115 , B01J2208/00309 , B01J2208/00504 , B01J2208/0084 , B01J2208/00849 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/0263 , C04B35/486 , C04B35/505 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/528 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/5481 , C04B2235/6021 , C04B2235/658 , C04B2235/6584 , C04B2235/72 , C04B2235/762 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , C04B2235/9669 , C04B2235/9684 , C10G1/02 , C10G9/00 , C10G9/005 , C10G9/18 , C10G9/26 , C10G75/00 , Y02P20/582
摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and that remains in oxide form when exposed to a gas having a carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.
摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,该装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点至少为2060℃,并保留在氧化物 当暴露于碳分压为10-22巴,氧气分压为10-10巴的气体时,在1200℃的温度下形成。在一些实施方案中,反应器包括再生热解反应器装置,在其它实施方案中 它包括逆流再生反应器装置。 在其他方面,本发明包括使用热解反应器系统热解烃原料的方法,该方法包括在加热区域中提供用于热解烃原料的热解反应器系统,包括氧化物形式的耐火材料的装置,耐火材料 材料具有至少2060℃的熔点,并且当暴露于碳分压为10-22巴,氧分压为10-10巴的气体时,在1200℃的温度下保持为氧化物形式 C。
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公开(公告)号:US08932534B2
公开(公告)日:2015-01-13
申请号:US12623046
申请日:2009-11-20
CPC分类号: C10G9/203 , C10G9/16 , C10G2300/4075
摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, said apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of no less than 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar and oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.; wherein said refractory material has no less than 4 vol % formed porosity, measured at 20° C., based upon the bulk volume of said refractory material. In another embodiment, the refractory material has total porosity in the range of from 4 to 60 vol %.
摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,所述装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点不低于2060℃,并保持在 在1200℃的温度下暴露于碳分压为10-22巴,氧气分压为10-10巴的气体时,氧化物形式。 其中所述耐火材料具有基于所述耐火材料的体积体积在20℃下测量的不少于4体积%的孔隙率。 在另一个实施方案中,耐火材料具有4至60体积%的总孔隙率。
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公开(公告)号:US08821806B2
公开(公告)日:2014-09-02
申请号:US12772757
申请日:2010-05-03
CPC分类号: C04B35/488 , B01J4/002 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J19/02 , B01J19/2485 , B01J2208/00115 , B01J2208/00309 , B01J2208/00504 , B01J2208/0084 , B01J2208/00849 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/0263 , C04B35/486 , C04B35/505 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/528 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/5481 , C04B2235/6021 , C04B2235/658 , C04B2235/6584 , C04B2235/72 , C04B2235/762 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , C04B2235/9669 , C04B2235/9684 , C10G1/02 , C10G9/00 , C10G9/005 , C10G9/18 , C10G9/26 , C10G75/00 , Y02P20/582
摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having an oxygen partial pressure of 10−15 bar, a carbon partial pressure above the carbon partial pressure of the zirconium carbide and zirconium oxide phase transition at the same temperature, and at temperatures below the temperature of the zirconium triple point at the oxygen partial pressure of 10−15 bar; and ii) when exposed to a gas having an oxygen partial pressure of 10−15 bar and at temperatures above the zirconium triple point at the oxygen partial pressure of 10−15 bar. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising the above refractory material.
摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,该装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点至少为2060℃,并保留在氧化物 当暴露于氧分压为10-15巴的气体,碳分压高于碳化锆的碳分压和相同温度下的氧化锆相变时,以及低于锆三元组温度的温度 点氧分压为10-15巴; 和ii)当暴露于氧分压为10-15巴的气体和在10-15巴的氧分压下在高于锆三重点的温度下。 在一些实施方案中,反应器包括再生热解反应器装置,并且在其它实施方案中,其包括逆流再生反应器装置。 在其它方面,本发明包括使用热解反应器系统热解烃原料的方法,该方法包括在加热区域中提供用于热解烃原料的热解反应器系统,该装置包括上述耐火材料。
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公开(公告)号:US20100292523A1
公开(公告)日:2010-11-18
申请号:US12772757
申请日:2010-05-03
CPC分类号: C04B35/488 , B01J4/002 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J19/02 , B01J19/2485 , B01J2208/00115 , B01J2208/00309 , B01J2208/00504 , B01J2208/0084 , B01J2208/00849 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/0263 , C04B35/486 , C04B35/505 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/528 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/5481 , C04B2235/6021 , C04B2235/658 , C04B2235/6584 , C04B2235/72 , C04B2235/762 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , C04B2235/9669 , C04B2235/9684 , C10G1/02 , C10G9/00 , C10G9/005 , C10G9/18 , C10G9/26 , C10G75/00 , Y02P20/582
摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having an oxygen partial pressure of 10−15 bar, a carbon partial pressure above the carbon partial pressure of the zirconium carbide and zirconium oxide phase transition at the same temperature, and at temperatures below the temperature of the zirconium triple point at the oxygen partial pressure of 10−15 bar; and ii) when exposed to a gas having an oxygen partial pressure of 10−15 bar and at temperatures above the zirconium triple point at the oxygen partial pressure of 10−15 bar. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising the above refractory material.
摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,该装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点至少为2060℃,并保留在氧化物 当暴露于氧分压为10-15巴的气体,碳分压高于碳化锆的碳分压和相同温度下的氧化锆相变时,以及低于锆三元组温度的温度 点氧分压为10-15巴; 和ii)当暴露于氧分压为10-15巴的气体和在10-15巴的氧分压下在高于锆三重点的温度下。 在一些实施方案中,反应器包括再生热解反应器装置,并且在其它实施方案中,其包括逆流再生反应器装置。 在其它方面,本发明包括使用热解反应器系统热解烃原料的方法,该方法包括在加热区域中提供用于热解烃原料的热解反应器系统,该装置包括上述耐火材料。
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公开(公告)号:US08450552B2
公开(公告)日:2013-05-28
申请号:US12576002
申请日:2009-10-08
CPC分类号: C04B35/488 , B01J4/002 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J19/02 , B01J19/2485 , B01J2208/00115 , B01J2208/00309 , B01J2208/00504 , B01J2208/0084 , B01J2208/00849 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/0263 , C04B35/486 , C04B35/505 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/528 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/5481 , C04B2235/6021 , C04B2235/658 , C04B2235/6584 , C04B2235/72 , C04B2235/762 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , C04B2235/9669 , C04B2235/9684 , C10G1/02 , C10G9/00 , C10G9/005 , C10G9/18 , C10G9/26 , C10G75/00 , Y02P20/582
摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and that remains in oxide form when exposed to a gas having a carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.
摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,该装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点至少为2060℃,并保留在氧化物 当暴露于碳分压为10-22巴,氧气分压为10-10巴的气体时,在1200℃的温度下形成。在一些实施方案中,反应器包括再生热解反应器装置,在其它实施方案中 它包括逆流再生反应器装置。 在其他方面,本发明包括使用热解反应器系统热解烃原料的方法,该方法包括在加热区域中提供用于热解烃原料的热解反应器系统,包括氧化物形式的耐火材料的装置,耐火材料 材料具有至少2060℃的熔点,并且当暴露于碳分压为10-22巴,氧分压为10-10巴的气体时,在1200℃的温度下保持为氧化物形式 C。
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公开(公告)号:US20110120853A1
公开(公告)日:2011-05-26
申请号:US12623046
申请日:2009-11-20
CPC分类号: C10G9/203 , C10G9/16 , C10G2300/4075
摘要: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, said apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of no less than 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar and oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.; wherein said refractory material has no less than 4 vol % formed porosity, measured at 20° C., based upon the bulk volume of said refractory material. In another embodiment, the refractory material has total porosity in the range of from 4 to 60 vol %.
摘要翻译: 在一个方面,本发明包括用于热解烃原料的反应器装置,所述装置包括:反应器组件,其包含氧化物形式的耐火材料,耐火材料的熔点不低于2060℃,并保持在 在1200℃的温度下暴露于碳分压为10-22巴,氧气分压为10-10巴的气体时,氧化物形式。 其中所述耐火材料具有基于所述耐火材料的体积体积在20℃下测量的不少于4体积%的孔隙率。 在另一个实施方案中,耐火材料具有4至60体积%的总孔隙率。
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公开(公告)号:US07335295B2
公开(公告)日:2008-02-26
申请号:US10862849
申请日:2004-06-07
申请人: Jannetje Maatje van den Berge , Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Michael C. Bradford
发明人: Jannetje Maatje van den Berge , Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Michael C. Bradford
IPC分类号: C10G35/04
CPC分类号: B01J35/023 , B01J29/40 , B01J29/70 , B01J29/80 , B01J37/0246 , B01J2229/12 , B01J2229/26 , B01J2229/42 , B01J2229/62 , C07C2/864 , C07C5/2708 , C07C6/123 , C07C2529/40 , C07C2529/70 , C07C2529/87 , C10G3/45 , C10G3/47 , C10G3/49 , C10G11/05 , C10G35/065 , C10G35/095 , C10G45/64 , C10G2300/1044 , C10G2300/4018 , C10G2300/708 , C10G2400/20 , Y02P20/52 , Y02P30/20 , C07C15/08
摘要: There is provided a coated zeolite catalyst in which the accessibility of the acid sites on the external surfaces of the zeolite is controlled and a process for converting hydrocarbons utilizing the coated zeolite catalyst. The zeolite catalyst comprises core crystals of a first zeolite and a discontinuous layer of smaller size second crystals of a second zeolite which cover at least a portion of the external surface of the first crystals The coated zeolite catalyst finds particular application in hydrocarbon conversion processes where catalyst activity in combination with zeolite structure are important for reaction selectivity, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.
摘要翻译: 提供了一种涂层沸石催化剂,其中控制沸石外表面上的酸性位点的可及性以及利用涂覆的沸石催化剂转化烃的方法。 沸石催化剂包括第一沸石的核心晶体和覆盖第一晶体的至少部分外表面的第二沸石的较小尺寸的第二晶体的不连续层。涂覆的沸石催化剂在烃转化过程中特别适用于其中催化剂 结合沸石结构的活性对于反应选择性是重要的,例如催化裂化,烷基化,甲苯不成比例,异构化和烷基转移反应。
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公开(公告)号:US06645370B2
公开(公告)日:2003-11-11
申请号:US10315353
申请日:2002-12-10
IPC分类号: C10G1105
CPC分类号: C01B39/026 , B01J29/40 , B01J37/0009 , B01J2229/42 , Y10S423/22
摘要: This invention relates to a process for producing zeolite-bound high silica zeolites and the use of the zeolite-bound high silica zeolite produced by the process for hydrocarbon conversion. The process is carried out by forming an extrudable paste comprising a mixture of high silica zeolite in the hydrogen form, water, silica, and optionally an extrusion aid, extruding the extrudable paste to form silica-bound high silica zeolite extrudates, and then converting the silica of the binder to a zeolite binder. The zeolite-bound high silica zeolite produced by the process comprises high silica zeolite crystals that are bound together by zeolite binder crystals. The zeolite-bound high silica zeolite finds particular application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions.
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公开(公告)号:US06627577B2
公开(公告)日:2003-09-30
申请号:US10161121
申请日:2002-05-31
IPC分类号: B01J2718
CPC分类号: C10G49/08 , B01J29/005 , B01J29/84 , B01J29/85 , B01J2229/26 , B01J2229/42 , C10G3/48 , C10G3/49 , C10G3/50 , C10G11/05 , C10G35/095 , C10G2300/1037 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P30/20
摘要: There is provided catalysts and conversion processes for converting hydrocarbons using the catalysts. The catalysts comprises a first alumino-phosphospho-molecular sieves and a binder comprising a second alumino-phopho-molecular sieves. Exemplary conversion processes include the conversion of oxygenates to olefins, dewaxing, reforming, dealkylation, dehydrogenation, transalkylation, alkylation, and isomerization.
摘要翻译: 提供了使用催化剂转化烃的催化剂和转化方法。 催化剂包括第一铝磷磷分子筛和包含第二铝 - 磷光分子筛的粘合剂。 示例性的转化方法包括将含氧化合物转化为烯烃,脱蜡,重整,脱烷基化,脱氢,烷基转移,烷基化和异构化。
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公开(公告)号:US20100282641A1
公开(公告)日:2010-11-11
申请号:US12766372
申请日:2010-04-23
IPC分类号: C10G17/00
CPC分类号: C10G29/16 , C10G25/003 , C10G25/03 , C10G53/02 , C10G53/08 , C10G67/06 , C10G67/14 , C10G69/12 , C10G2300/4018 , C10G2300/4056 , C10G2300/701
摘要: A process for reducing the Bromine Index of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock with a catalyst at conversion conditions, wherein the catalyst includes at least one molecular sieve and at least one clay, and wherein said catalyst is sufficient to reduce more than 50% of the Bromine Index of a hydrocarbon feedstock.
摘要翻译: 一种用于降低烃原料的溴指数的方法,该方法包括在转化条件下使烃原料与催化剂接触的步骤,其中催化剂包括至少一种分子筛和至少一种粘土,并且其中所述催化剂是足够的 以减少烃原料的溴指数的50%以上。
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