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公开(公告)号:US20110250122A1
公开(公告)日:2011-10-13
申请号:US13128226
申请日:2009-11-03
IPC分类号: C01B31/20 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/52 , B01J23/50 , B01J23/72 , B01J23/755 , B01J23/75 , B01J23/745 , B01J21/08 , B01J21/04 , B01J21/06 , B01J23/20 , B01J35/08 , B01J35/06 , B01J37/025 , B01J37/08 , B01J37/14 , C07C5/03 , B01J35/10 , B82Y30/00
CPC分类号: B01J35/0013 , B01J21/08 , B01J23/38 , B01J23/40 , B01J23/42 , B01J23/74 , B01J23/75 , B01J29/0308 , B01J29/0325 , B01J35/002 , B01J2229/66 , C01B3/26 , C01B3/40 , C01B3/583 , C01B2203/0261 , C01B2203/0277 , C01B2203/044 , C01B2203/047 , C01B2203/1017 , C01B2203/107 , C07C5/03 , C07C2521/08 , C07C2523/42 , Y02P20/52 , C07C9/06
摘要: The present invention provides a core-shell nanoparticle that includes a metal-oxide shell and a nanoparticle. Pores extend from an outer surface to an inner surface of the shell. The inner surface of the shell forms a void, which is filled by the nanoparticle. The pores allow gas to transfer from outside the shell to a surface of the nanoparticle. The present invention also provides a method of making a core-shell nanoparticle includes forming a metal-oxide shell on a colloidal nanoparticle, which forms a precursor core-shell nanoparticle. A capping agent is removed from the precursor core-shell nanoparticle, which produces the core-shell nanoparticle. The present invention also provides a method of using a nanocatalyst of the present invention includes providing the nanocatalyst, which is the core-shell nanoparticle. Reactants are introduced in a vicinity of the nanocatalyst, which produces a reaction that is facilitated or enhanced by the nanocatalyst.
摘要翻译: 本发明提供了包含金属氧化物壳和纳米颗粒的核 - 壳纳米颗粒。 孔从壳体的外表面延伸到内表面。 壳的内表面形成空隙,其由纳米颗粒填充。 孔允许气体从外壳转移到纳米颗粒的表面。 本发明还提供了制备核 - 壳纳米颗粒的方法,包括在形成前体核 - 壳纳米颗粒的胶体纳米颗粒上形成金属氧化物壳。 从前体核 - 壳纳米颗粒中除去封端剂,其产生核 - 壳纳米颗粒。 本发明还提供了使用本发明的纳米催化剂的方法,包括提供作为核 - 壳纳米颗粒的纳米催化剂。 将反应物引入纳米催化剂附近,产生由纳米催化剂促进或增强的反应。
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公开(公告)号:US08859455B2
公开(公告)日:2014-10-14
申请号:US13441240
申请日:2012-04-06
申请人: Peidong Yang , Gabor Somorjai , Yusuke Yamada , Chia-Kuang Tsung , Wenyu Huang
发明人: Peidong Yang , Gabor Somorjai , Yusuke Yamada , Chia-Kuang Tsung , Wenyu Huang
IPC分类号: B01J21/00 , B01J23/00 , B01J23/63 , B01J23/42 , B01J37/02 , C01B3/22 , B01J35/00 , C07C45/49
CPC分类号: B01J23/63 , B01J23/42 , B01J35/0013 , B01J37/0244 , C01B3/22 , C01B2203/0277 , C01B2203/107 , C01B2203/1082 , C01B2203/1223 , C07C45/49 , C07C45/50 , C07C47/02
摘要: The present invention provides a nanocrystal tandem catalyst comprising at least two metal-metal oxide interfaces for the catalysis of sequential reactions. One embodiment utilizes a nanocrystal bilayer structure formed by assembling sub-10 nm platinum and cerium oxide nanocube monolayers on a silica substrate. The two distinct metal-metal oxide interfaces, CeO2—Pt and Pt—SiO2, can be used to catalyze two distinct sequential reactions. The CeO2—Pt interface catalyzed methanol decomposition to produce CO and H2, which were then subsequently used for ethylene hydroformylation catalyzed by the nearby Pt—SiO2 interface. Consequently, propanal was selectively produced on this nanocrystal bilayer tandem catalyst.
摘要翻译: 本发明提供一种纳米晶体串联催化剂,其包括用于催化顺序反应的至少两个金属 - 金属氧化物界面。 一个实施例使用通过在二氧化硅衬底上组装次10nm的铂和氧化铈纳米管单层而形成的纳米晶体双层结构。 两种不同的金属 - 金属氧化物界面CeO2-Pt和Pt-SiO2可用于催化两种不同的顺序反应。 CeO2-Pt界面催化甲醇分解以产生CO和H 2,随后将其用于由附近的Pt-SiO 2界面催化的乙烯加氢甲酰化。 因此,在该纳米晶体双层串联催化剂上选择性地生成丙醛。
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公开(公告)号:US20120302437A1
公开(公告)日:2012-11-29
申请号:US13441240
申请日:2012-04-06
申请人: Peidong Yang , Gabor Somorjai , Yusuke Yamada , Chia-Kuang Tsung , Wenyu Huang
发明人: Peidong Yang , Gabor Somorjai , Yusuke Yamada , Chia-Kuang Tsung , Wenyu Huang
CPC分类号: B01J23/63 , B01J23/42 , B01J35/0013 , B01J37/0244 , C01B3/22 , C01B2203/0277 , C01B2203/107 , C01B2203/1082 , C01B2203/1223 , C07C45/49 , C07C45/50 , C07C47/02
摘要: The present invention provides a nanocrystal tandem catalyst comprising at least two metal-metal oxide interfaces for the catalysis of sequential reactions. One embodiment utilizes a nanocrystal bilayer structure formed by assembling sub-10 nm platinum and cerium oxide nanocube monolayers on a silica substrate. The two distinct metal-metal oxide interfaces, CeO2—Pt and Pt—SiO2, can be used to catalyze two distinct sequential reactions. The CeO2—Pt interface catalyzed methanol decomposition to produce CO and H2, which were then subsequently used for ethylene hydroformylation catalyzed by the nearby Pt—SiO2 interface. Consequently, propanal was selectively produced on this nanocrystal bilayer tandem catalyst.
摘要翻译: 本发明提供一种纳米晶体串联催化剂,其包括用于催化顺序反应的至少两个金属 - 金属氧化物界面。 一个实施例使用通过在二氧化硅衬底上组装次10nm的铂和氧化铈纳米管单层而形成的纳米晶体双层结构。 两种不同的金属 - 金属氧化物界面CeO2-Pt和Pt-SiO2可用于催化两种不同的顺序反应。 CeO2-Pt界面催化甲醇分解以产生CO和H 2,随后将其用于由附近的Pt-SiO 2界面催化的乙烯加氢甲酰化。 因此,在该纳米晶体双层串联催化剂上选择性地生成丙醛。
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公开(公告)号:US11047055B2
公开(公告)日:2021-06-29
申请号:US16025594
申请日:2018-07-02
申请人: Peidong Yang , Qiao Kong , Dohyung Kim , Chong Liu
发明人: Peidong Yang , Qiao Kong , Dohyung Kim , Chong Liu
IPC分类号: C25B11/091 , B05D3/00 , C25B1/55
摘要: This disclosure provides systems, methods, and apparatus related to nanostructures. In one aspect, an array of nanowires is provided. The array of nanowires comprises a plurality of nanowires. End of nanowires of the plurality of nanowires are attached to a substrate. A liquid including a plurality of nanoparticles is deposited on the array of nanowires. The liquid is evaporated from the array of nanowires. Nanoparticles of the plurality of nanoparticles are deposited on the nanowires as a meniscus of the liquid recedes along lengths of the plurality of nanowires.
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公开(公告)号:US10304980B2
公开(公告)日:2019-05-28
申请号:US14692886
申请日:2015-04-22
申请人: Peidong Yang , Chong Liu , Jinyao Tang , Hao Ming Chen , Bin Liu
发明人: Peidong Yang , Chong Liu , Jinyao Tang , Hao Ming Chen , Bin Liu
IPC分类号: H01L31/0352 , C25B1/00 , C25B3/04 , C25B9/18
摘要: This disclosure provides systems, methods, and apparatus related to solar water splitting. In one aspect, a structure includes a plurality of first nanowires, the plurality of first nanowires comprising an n-type semiconductor or a p-type semiconductor. The structure further includes a second nanowire, the second nanowire comprising the n-type semiconductor or the p-type semiconductor, the second nanowire being a different composition than the plurality of first nanowires. The second nanowire includes a first region and a second region, with the first region having a conductive layer disposed thereon, and each of the plurality of first nanowires being disposed on the conductive layer.
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6.
公开(公告)号:US08003497B2
公开(公告)日:2011-08-23
申请号:US11480280
申请日:2006-06-29
申请人: Peidong Yang , Heonjin Choi , Sangkwon Lee , Rongrui He , Yanfeng Zhang , Tevye Kuykendal , Peter Pauzauskie
发明人: Peidong Yang , Heonjin Choi , Sangkwon Lee , Rongrui He , Yanfeng Zhang , Tevye Kuykendal , Peter Pauzauskie
IPC分类号: H01L21/20
CPC分类号: C01B21/0602 , B82Y25/00 , B82Y30/00 , C01B21/0632 , C01P2002/01 , C01P2002/54 , C01P2002/85 , C01P2004/03 , C01P2004/16 , C01P2006/40 , C01P2006/42 , H01L33/18 , Y10S438/931 , Y10S977/762
摘要: A method for is disclosed for fabricating diluted magnetic semiconductor (DMS) nanowires by providing a catalyst-coated substrate and subjecting at least a portion of the substrate to a semiconductor, and dopant via chloride-based vapor transport to synthesize the nanowires. Using this novel chloride-based chemical vapor transport process, single crystalline diluted magnetic semiconductor nanowires Ga1-xMnxN (x=0.07) were synthesized. The nanowires, which have diameters of ˜10 nm to 100 nm and lengths of up to tens of micrometers, show ferromagnetism with Curie temperature above room temperature, and magnetoresistance up to 250 Kelvin.
摘要翻译: 公开了一种用于通过提供催化剂涂覆的基底并使基底的至少一部分经受半导体制造稀磁半导体(DMS)纳米线的方法,以及通过基于氯化物的蒸汽输运的掺杂剂来合成纳米线。 使用这种新型的基于氯化物的化学气相传输方法,合成了单晶稀释磁半导体纳米线Ga1-xMnxN(x = 0.07)。 具有〜10nm至100nm直径和高达几十微米的直径的纳米线显示出高于室温的居里温度的铁磁性,高达250开尔文的磁阻。
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公开(公告)号:US20110114145A1
公开(公告)日:2011-05-19
申请号:US12673366
申请日:2008-08-21
摘要: The invention provides for a nanostructure, or an array of such nanostructures, each comprising a rough surface, and a doped or undoped semiconductor. The nanostructure is an one-dimensional (1-D) nanostructure, such a nanowire, or a two-dimensional (2-D) nanostructure. The nanostructure can be placed between two electrodes and used for thermoelectric power generation or thermoelectric cooling.
摘要翻译: 本发明提供纳米结构或这种纳米结构的阵列,每个包括粗糙表面,以及掺杂或未掺杂的半导体。 纳米结构是一维(1-D)纳米结构,如纳米线或二维(2-D)纳米结构。 纳米结构可以放置在两个电极之间,用于热电发电或热电冷却。
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8.
公开(公告)号:US20090294908A1
公开(公告)日:2009-12-03
申请号:US11480280
申请日:2006-06-29
申请人: Peidong Yang , Heonjin Choi , Sangkwon Lee , Rongrui He , Yanfeng Zheng , Tevye Kuykendal , Peter Pauzauskie
发明人: Peidong Yang , Heonjin Choi , Sangkwon Lee , Rongrui He , Yanfeng Zheng , Tevye Kuykendal , Peter Pauzauskie
CPC分类号: C01B21/0602 , B82Y25/00 , B82Y30/00 , C01B21/0632 , C01P2002/01 , C01P2002/54 , C01P2002/85 , C01P2004/03 , C01P2004/16 , C01P2006/40 , C01P2006/42 , H01L33/18 , Y10S438/931 , Y10S977/762
摘要: A method for is disclosed for fabricating diluted magnetic semiconductor (DMS) nanowires by providing a catalyst-coated substrate and subjecting at least a portion of the substrate to a semiconductor, and dopant via chloride-based vapor transport to synthesize the nanowires. Using this novel chloride-based chemical vapor transport process, single crystalline diluted magnetic semiconductor nanowires Ga1-xMnxN (x=0.07) were synthesized. The nanowires, which have diameters of ˜10 nm to 100 nm and lengths of up to tens of micrometers, show ferromagnetism with Curie temperature above room temperature, and magnetoresistance up to 250 Kelvin.
摘要翻译: 公开了一种用于通过提供催化剂涂覆的基底并使基底的至少一部分经受半导体制造稀磁半导体(DMS)纳米线的方法,以及通过基于氯化物的蒸汽输运的掺杂剂来合成纳米线。 使用这种新型的基于氯化物的化学气相传输方法,合成了单晶稀释磁半导体纳米线Ga1-xMnxN(x = 0.07)。 具有约10nm至100nm直径和高达几十微米的直径的纳米线显示出具有高于室温的居里温度的铁磁性,高达250开尔德的磁致电阻。
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公开(公告)号:US20090293928A1
公开(公告)日:2009-12-03
申请号:US12330114
申请日:2008-12-08
申请人: Wenjie Liang , Allon Hochbaum , Melissa Fardy , Minjuan Zhang , Peidong Yang
发明人: Wenjie Liang , Allon Hochbaum , Melissa Fardy , Minjuan Zhang , Peidong Yang
IPC分类号: H01L35/34
CPC分类号: C01B19/007 , B82Y30/00 , C01G21/00 , C01G21/21 , C01P2004/03 , C01P2004/04 , C01P2004/16 , C01P2004/62 , C01P2004/64 , C01P2004/80 , C01P2006/32 , C01P2006/40
摘要: A process for altering the thermoelectric properties of an electrically conductive material is provided. The process includes providing an electrically conducting material and a substrate. The electrically conducting material is brought into contact with the substrate. A thermal gradient can be applied to the electrically conducting material and a voltage applied to the substrate. In this manner, the electrical conductivity, the thermoelectric power and/or the thermal conductivity of the electrically conductive material can be altered and the figure of merit increased.
摘要翻译: 提供了改变导电材料的热电性能的方法。 该方法包括提供导电材料和基底。 使导电材料与基板接触。 可以对导电材料施加热梯度并施加施加到基板的电压。 以这种方式,可以改变导电材料的导电性,热电功率和/或热导率,并且提高品质因数。
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公开(公告)号:US06882767B2
公开(公告)日:2005-04-19
申请号:US10032698
申请日:2001-12-27
申请人: Peidong Yang , Hannes Kind , Haoquan Yan , Matthew Law , Benjamin Messer
发明人: Peidong Yang , Hannes Kind , Haoquan Yan , Matthew Law , Benjamin Messer
CPC分类号: G11C13/025 , B82Y10/00 , G11C13/04 , G11C2213/16 , Y10S977/932
摘要: A nanowire switching device and method. The device has a nanowire structure comprising an elongated member having a cross-sectional area ranging from about 1 nanometers but less than about 500 nanometers, but can also be at other dimensions, which vary or are substantially constant or any combination of these. The device also has a first terminal coupled to a first portion of the nanowire structure; and a second terminal coupled to a second portion of the nanowire structure. The second portion of the nanowire structure is disposed spatially from the first portion of the nanowire structure. An active surface structure is coupled to the nanowire structure. The active surface structure extends from the first portion to the second portion along the elongated member.
摘要翻译: 纳米线切换装置及方法。 该装置具有纳米线结构,该纳米线结构包括具有约1纳米但小于约500纳米的横截面积的细长构件,但是也可以在其它尺寸上变化或基本上恒定,或者这些的任何组合。 该器件还具有耦合到纳米线结构的第一部分的第一端子; 以及耦合到所述纳米线结构的第二部分的第二端子。 纳米线结构的第二部分从纳米线结构的第一部分空间上放置。 有源表面结构耦合到纳米线结构。 主动表面结构沿着细长构件从第一部分延伸到第二部分。
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