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公开(公告)号：US08147953B2
公开(公告)日：2012-04-03
申请号：US10540377
申请日：2004-01-20
IPC分类号： B32B15/04 , B32B15/06 , B32B15/085 , C23C16/00
CPC分类号： C08J7/047 , B32B25/08 , B32B25/16 , C08J7/123 , C08J2423/00 , Y10T428/24942 , Y10T428/26 , Y10T428/263 , Y10T428/31678 , Y10T428/31692 , Y10T428/31696 , Y10T428/31931
摘要： An object of the invention is to provide a laminate which is good in adhesiveness between a substrate and a thin film laminated thereon by a dry film-forming method such as a chemical vapor growth method or a vacuum evaporation method even if the substrate is a polymer substrate made of a nonpolar polymer; and a process for producing the same. In order to attain the above-mentioned object, the invention provides a laminate comprising a polymer substrate, a primer layer comprising a cyclized rubber which is a conjugated diene polymer cyclized product or a derivative thereof, the layer being formed on the surface of the polymer substrate, and a thin film laminated on the surface of the primer layer by a dry film-forming method; and a process for producing the same.
摘要翻译： 本发明的目的是提供一种层压体，其通过诸如化学气相生长法或真空蒸发法之类的干膜形成方法在基材和其上层压的薄膜之间具有良好的粘附性，即使基材是聚合物 由非极性聚合物制成的基底; 及其制造方法。 为了实现上述目的，本发明提供了一种层压体，其包括聚合物基材，包含作为共轭二烯聚合物环化产物的环化橡胶或其衍生物的底漆层，所述层在聚合物的表面上形成 基板和通过干膜形成方法层压在底漆层的表面上的薄膜; 及其制造方法。
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公开(公告)号：US20060127655A1
公开(公告)日：2006-06-15
申请号：US10540377
申请日：2004-01-20
IPC分类号： B32B7/02
CPC分类号： C08J7/047 , B32B25/08 , B32B25/16 , C08J7/123 , C08J2423/00 , Y10T428/24942 , Y10T428/26 , Y10T428/263 , Y10T428/31678 , Y10T428/31692 , Y10T428/31696 , Y10T428/31931
摘要： An object of the invention is to provide a laminate which is good in adhesiveness between a substrate and a thin film laminated thereon by a dry film-forming method such as a chemical vapor growth method or a vacuum evaporation method even if the substrate is a polymer substrate made of a nonpolar polymer; and a process for producing the same. In order to attain the above-mentioned object, the invention provides a laminate comprising a polymer substrate, a primer layer comprising a cyclized rubber which is a conjugated diene polymer cyclized product or a derivative thereof, the layer being formed on the surface of the polymer substrate, and a thin film laminated on the surface of the primer layer by a dry film-forming method; and a process for producing the same.
摘要翻译： 本发明的目的是提供一种层压体，其通过诸如化学气相生长法或真空蒸发法之类的干膜形成方法在基材和其上层压的薄膜之间具有良好的粘附性，即使基材是聚合物 由非极性聚合物制成的基材; 及其制造方法。 为了实现上述目的，本发明提供了一种层压体，其包括聚合物基材，包含作为共轭二烯聚合物环化产物的环化橡胶或其衍生物的底漆层，所述层在聚合物的表面上形成 基板和通过干膜形成方法层压在底漆层的表面上的薄膜; 及其制造方法。
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公开(公告)号：US08293346B2
公开(公告)日：2012-10-23
申请号：US11886024
申请日：2006-03-17
申请人： Shizuo Kitahara , Yasushi Tanaka
发明人： Shizuo Kitahara , Yasushi Tanaka
CPC分类号： C08L15/00 , A23L3/3436 , B01J20/26 , B01J20/261 , B32B25/08 , B32B25/14 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2274/00 , B32B2439/70 , C08C19/02 , C08C19/08 , C08L2205/02 , Y10T428/1341 , Y10T428/1352 , Y10T428/31931 , C08L2666/08
摘要： The objective of the invention is to provide a gas barrier resin composition that is excellent in oxygen absorbability and further excellent in adhesiveness to olefin resins, a structure comprising the same, and a multi-layer structure comprising the same. The oxygen-absorbing gas barrier resin composition disclosed comprises a cyclized product of a conjugated diene polymer and an ethylene/vinyl alcohol copolymer having a specified oxygen permeation rate. The oxygen-absorbing gas barrier resin composition further comprises an α-olefin resin. The oxygen-absorbing gas barrier structure is obtained by molding the subject oxygen-absorbing gas barrier resin composition. The oxygen-absorbing gas barrier multi-layer structure comprises a layer of the subject oxygen-absorbing gas barrier structure and a sealing material layer.
摘要翻译： 本发明的目的是提供一种阻气性树脂组合物，该阻气性树脂组合物具有优异的氧吸收性，并且对烯烃树脂的粘合性，包含该阻气性树脂组合物的结构，以及包含该阻气性树脂组合物的多层结构。 所公开的氧吸收阻气性树脂组合物包含共轭二烯聚合物和具有规定氧渗透速率的乙烯/乙烯醇共聚物的环化产物。 氧吸收阻气性树脂组合物还包含α-烯烃树脂。 氧吸收阻气性树脂组合物通过成型而得到。 氧吸收气体阻隔层的多层结构包括本发明的氧吸收气体阻隔结构层和密封材料层。
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4.发明申请公开(公告)号：US20080090042A1
公开(公告)日：2008-04-17
申请号：US11794440
申请日：2005-12-22
申请人： Shizuo Kitahara
发明人： Shizuo Kitahara
CPC分类号： B65D81/267 , B32B27/08 , B32B27/18 , C08C19/10 , Y10T428/1379
摘要： [Problem] To provide an oxygen-absorbing multilayer sheet which exhibits high oxygen-absorbability without the addition of a transition metal salt and which does not cause a problem of odors, a packaging material comprising the multilayer sheet, and a packaging container obtained by molding this packaging material. [Means for Dissolution] An oxygen-absorbing multilayer sheet having a thickness of 250 μm or more that comprises a gas barrier material layer, an oxygen absorbent layer and a sealing material layer laminated in this order, wherein an oxygen absorbent constituting the subject oxygen absorbent layer comprises a cyclized product of a conjugated diene polymer. There are also disclosed a packaging material comprising this multilayer film and a packaging container obtained by molding this packaging material.
摘要翻译： [问题]提供一种不加入过渡金属盐显示高吸氧性且不引起气味问题的吸氧性多层片材，包含该多层片材的包装材料和通过成型获得的包装容器 这种包装材料。 [溶解方法]将依次层叠的阻气材料层，氧吸收层和密封材料层的厚度为250μm以上的吸氧性多层片材，其中构成主体氧吸收剂的氧吸收剂 层包含共轭二烯聚合物的环化产物。 还公开了包含这种多层膜的包装材料和通过模制该包装材料获得的包装容器。
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5.发明申请公开(公告)号：US20080014395A1
公开(公告)日：2008-01-17
申请号：US11794154
申请日：2005-12-22
申请人： Shizuo Kitahara
发明人： Shizuo Kitahara
CPC分类号： B32B27/08 , B65D81/267 , C08C19/10 , C08L15/00 , C08L23/06 , C08L23/10 , Y10T428/1376 , C08L2666/08
摘要： [Problem]To provide an oxygen-absorbing multilayer film which exhibits excellent oxygen-absorbability without incorporating a transition metal salt usually added as a catalyst for the purpose of enhancing oxygen-absorbability and which is excellent in physical properties after oxygen absorption, a packaging material comprising this multilayer film, and a packaging container obtained by molding this packaging material. [Dissolution Means]An oxygen-absorbing multilayer film that comprises a gas barrier material layer, an oxygen absorbent layer and a sealing material layer laminated in this order, wherein the subject oxygen absorbent layer comprises less than 50% by weight of a cyclized product of a conjugated diene polymer relative to all the constitutional components of the oxygen absorbent layer. There are also disclosed a packaging material comprising this multilayer film and a packaging container obtained by molding this packaging material.
摘要翻译： 为了提供氧吸收性优异的吸氧性多层膜，不加入通常加入作为催化剂的过渡金属盐，为了提高吸氧性，氧吸收后的物理性能优异，可以使用包装材料 包括该多层膜，以及通过模制该包装材料而获得的包装容器。 [溶解方法]一种吸氧性多层膜，其包含以下顺序层叠的阻气材料层，氧吸收层和密封材料层，其中所述主体氧吸收层包含小于50重量％的环化产物 相对于氧吸收层的所有构成成分的共轭二烯聚合物。 还公开了包含这种多层膜的包装材料和通过模制该包装材料获得的包装容器。
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6.发明授权Modifier for hydrocarbon polymers, hydrocarbon polymer composition and moldings 失效烃聚合物改性剂，烃聚合物组合物和模塑制品公开(公告)号：US07144959B2
公开(公告)日：2006-12-05
申请号：US10509022
申请日：2003-03-25
申请人： Shizuo Kitahara
发明人： Shizuo Kitahara
IPC分类号： C08L33/06
CPC分类号： C08L23/02 , C08C19/10 , C08F8/48 , C08K3/04 , C08K3/06 , C08K3/26 , C08K5/0025 , C08K5/09 , C08K5/40 , C08K5/47 , C08L9/00 , C08L23/00 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L23/18 , C08L91/00 , C08L2312/00 , C08F10/00 , C08L2666/04 , C08L2666/08 , C08L2666/06
摘要： The present invention has a main object to provide a modifier for hydrocarbon polymer that improves a coatability of a surface of a hydrocarbon polymer molding. To attain the object, the present invention provides a modifier for hydrocarbon polymer which contains, as an active component, a modified cyclic structure-containing conjugated diene polymer wherein an amount of an α,β-ethylenically unsaturated carboxylic acid compound bonded by addition is from 0.1 to 20% by weight and a cyclization ratio is from 30 to 95%; and provides a hydrocarbon polymer composition comprising the modifier for hydrocarbon polymer and a hydrocarbon polymer; and provides a molding by molding the hydrocarbon polymer composition.
摘要翻译： 本发明的主要目的是提供改进烃类聚合物成型体的表面的涂布性的烃聚合物改性剂。 为了达到上述目的，本发明提供了一种烃类聚合物改性剂，它含有作为活性组分的含改性环状结构的共轭二烯聚合物，其中通过加成键合的α，β-烯键式不饱和羧酸化合物的量来自 0.1〜20重量％，环化率为30〜95％。 并提供一种烃聚合物组合物，其包含烃聚合物改性剂和烃聚合物; 并通过模制烃聚合物组合物提供模制品。
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7.发明授权Sludge dispersing agent for fuel oil and fuel oil composition containing the same 失效用于燃料油的污泥分散剂和含有它的燃料油组合物
公开(公告)号：US5372614A
公开(公告)日：1994-12-13
申请号：US38977
申请日：1993-03-29
CPC分类号： C10L1/143 , C10L1/221 , C10L1/2383 , C10L1/2437 , C10L1/2641
摘要： A sludge dispersing agent for fuel oils includes a polymer having at least one >C.dbd.N.sup.+
摘要翻译： 用于燃料油的污泥分散剂包括在其分子中具有至少一个> C = N + <键的聚合物和至少一种选自长链烷基磷酸酯和烷基磺基琥珀酸盐及其盐的化合物。
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8.发明授权
公开(公告)号：US5247009A
公开(公告)日：1993-09-21
申请号：US322168
申请日：1989-03-13
申请人： Shizuo Kitahara
发明人： Shizuo Kitahara
CPC分类号： C08L21/00 , B60C1/0016 , C08C19/22 , C08F8/30 , C08L23/16 , B60C1/0008
摘要： A rubber composition comprising a rubbery polymer and a modified liquid polymer. The modified liquid polymer is obtained by reacting a liquid polymer having at least one carbon-carbon double bond in the molecule with an organic compound having the group --CH.dbd.N-- and an organic acid halide having the group --COX where X is halogen, in the presence of a Friedel-Crafts catalyst.
摘要翻译： 包含橡胶状聚合物和改性液体聚合物的橡胶组合物。 改性液体聚合物通过使分子中具有至少一个碳 - 碳双键的液体聚合物与基团-CH = N-的有机化合物和具有基团-COX的有机酰卤反应而获得，其中X为卤素， 在Friedel-Crafts催化剂存在下。
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公开(公告)号：US4654435A
公开(公告)日：1987-03-31
申请号：US563379
申请日：1983-12-20
申请人： Shizuo Kitahara , Yoshitsugu Hirokawa , Haruki Kawada , Toshihiro Fujii , Nagatoshi Sugi , Hiroaki Hasegawa , Akira Yoshioka
发明人： Shizuo Kitahara , Yoshitsugu Hirokawa , Haruki Kawada , Toshihiro Fujii , Nagatoshi Sugi , Hiroaki Hasegawa , Akira Yoshioka
IPC分类号： C07C69/712 , B01J27/00 , B01J31/00 , C07B31/00 , C07B37/02 , C07B61/00 , C07C51/00 , C07C51/347 , C07C59/70 , C07C67/00 , C08F8/00 , C07C69/76
CPC分类号： C07C51/347
摘要： A process for the addition reaction of an unsaturated organic compound, except a rubber, having at least one carbon-carbon double bond in a molecule, which comprises reacting the unsaturated organic compound with an organic compound having a carboxyl group and an aldehyde group in the presence of a Lewis acid.
摘要翻译： 在分子中具有至少一个碳 - 碳双键的橡胶以外的不饱和有机化合物的加成反应的方法，其包括使不饱和有机化合物与具有羧基和醛基的有机化合物在 存在路易斯酸。
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公开(公告)号：US20130030104A1
公开(公告)日：2013-01-31
申请号：US13638478
申请日：2011-03-28
申请人： Takuro Sakurai , Shizuo Kitahara
发明人： Takuro Sakurai , Shizuo Kitahara
IPC分类号： C08K5/09
CPC分类号： C08K5/0016 , C08C19/10 , C08G2261/3327 , C08G2261/46 , C08J5/18 , C08J2367/02 , C08K5/09 , C08L15/00 , C08L65/00 , C08L67/02
摘要： An object of the invention is to provide a resin composition that exhibits sufficient oxygen absorption performance within a relatively short period after being placed in the presence of oxygen, even without including an oxidation catalyst such as a transition metal catalyst, and that furthermore suppresses the generation of malodor associated with oxygen absorption. The object is attained by providing a resin composition comprising an oxygen absorbing resin composition dispersed within a matrix resin, characterized in that the oxygen absorbing resin composition comprises a cyclized product of a conjugated diene polymer and a saturated fatty acid having 18 to 44 carbon atoms.
摘要翻译： 本发明的目的是提供一种树脂组合物，即使在不含有过渡金属催化剂等氧化催化剂的情况下，也可以在放置有氧之后的较短时间内表现出足够的氧吸收性能，并且进一步抑制发生 的恶臭与氧气吸收有关。 本发明的目的是提供一种分散在基体树脂中的含氧吸收性树脂组合物的树脂组合物，其特征在于，所述吸氧树脂组合物含有共轭二烯系聚合物和碳原子数为18〜44的饱和脂肪酸的环化物。
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