摘要:
Described herein are compositions comprising a vinyl acrylic copolymer derived in the presence of maltodextrin. In some examples, the compositions comprise a copolymer derived from: vinyl acetate; an acrylate monomer having a Tg of −30° C. or less; a carboxylic acid, a carboxylic acid anhydride, or a combination thereof; and an organosilane; in the presence of maltodextrin. The copolymer can be provided as an aqueous dispersion. In some examples, the aqueous dispersion can have an overall solids content of from 40% to 75%. Also disclosed herein are carpet tiles having a surface coated with the adhesive formulations disclosed herein. In some examples, the carpet tile with the adhesive formulation applied thereto can pass the British spill test. Also disclosed herein are methods of making the compositions disclosed herein.
摘要:
A normally tacky and pressure-sensitive adhesive which is dispersible in water is obtained a composition comprising an acrylate modified polysaccharide, i.e., a polysaccharide polyacrylate, and a polyhydroxy compound by subjecting the composition to a short heat cycle.
摘要:
An adhesive may be formulated with a functional component that reacts in the presence of ultraviolet light with a neighboring functional component to form a nonreversible bond therebetween. The functional component may include at least one —C═C— functional group that is able to undergo dimerization with a neighboring component. A method for making the adhesive includes covalently bonding the functional component to a support polymer, wherein the functional component may be covalently bonded to the support polymer by a linking molecule. A kit containing the adhesive and an ultraviolet light source is also provided.
摘要:
The invention relates to compositions and articles containing s crosslinked polymer matrix and an immobilized active liquid, as well as methods of making and using the same.
摘要:
The present disclosure discloses a thermosetting starch adhesive for a wood-based panel and a preparation method therefor, and belongs to the technical field of preparation of adhesives. In the present disclosure, starch is used as a main raw material, and after acid hydrolysis thereof, a semi-continuous seed emulsion polymerization method is adopted to improve control of monomer polymerization stability. After grafting is completed, a cross-linking monomer with polymerizable double bonds and condensable methylol functional groups is added for copolymerization. The cross-linking monomer is also added in a semi-continuous manner. After the cross-linking reaction is completed, the reaction mixture is gelatinized and incubated, and finally a thermosetting adhesive which can be used for bonding of hot-pressed wood-based panels is obtained. The adhesive of the present disclosure has the properties of two-step cross-linking and high-temperature rapid cross-linking curing, good film formation, good heat resistance, and strong cohesion. With a hot-pressing process in an appropriate coating manner, appropriate temperature and pressure, the resultant wood-based panels have all their properties superior over those of Class II wood-based panels, and they can be widely used in decoration of hot-pressed woods, and bonding of wood-based panels and plywoods.
摘要:
A multi-functionally modified polymer binder for lithium ion batteries, which is prepared by a free radical graft copolymerization or a Michael addition reaction, with a biomass polymer or a synthetic polymer as a substrate, and a hydrophilic monomer and a lipophilic monomer as functionally modifying monomers. The binder presents a three-dimensional network body with a multi-branch structure, provides more active cites for contacting with the electrode active materials, improves uniformity and flatness in the formation of films from electrode slurry, enhances the binding strength between the electrode active materials, the conductive agents and the current collector, has high elasticity and binding strength, and is applicable in water/organic solvent. Use of the binder in positive electrodes and negative electrodes can facilitate the conduction of electrons/ions during charging and discharging, reduce the electrochemical interface impedance of the electrodes.
摘要:
An aqueous binder for a lithium ion battery, a preparation method and a use thereof. The binder is an inorganic-organic composite emulsion, comprising a dispersing agent, inorganic nanoparticles, (methyl)acrylate monomers, unsaturated carboxylic acid monomers, vinyl hydrocarbon monomers and optionally copolymers of other copolymerizable monomers, wherein the dispersing agent is a water-soluble cellulose grafted amphiphilic copolymer. When the water-soluble cellulose grafted amphiphilic copolymer is used as the dispersing agent, the agglomeration of the nanoparticles when the binder is formed into a film can be avoided, and at the same time, the effects of toughening and improving the binding strength can be achieved. Meanwhile, the water-soluble cellulose has certain strengthening and toughening properties so that the aqueous binder has an excellent anti-tensile performance. The aqueous binder for a lithium ion battery can be used for lithium ion batteries.
摘要:
The present disclosure discloses a thermosetting starch adhesive for a wood-based panel and a preparation method therefor, and belongs to the technical field of preparation of adhesives. In the present disclosure, starch is used as a main raw material, and after acid hydrolysis thereof, a semi-continuous seed emulsion polymerization method is adopted to improve control of monomer polymerization stability. After grafting is completed, a cross-linking monomer with polymerizable double bonds and condensable methylol functional groups is added for copolymerization. The cross-linking monomer is also added in a semi-continuous manner. After the cross-linking reaction is completed, the reaction mixture is gelatinized and incubated, and finally a thermosetting adhesive which can be used for bonding of hot-pressed wood-based panels is obtained. The adhesive of the present disclosure has the properties of two-step cross-linking and high-temperature rapid cross-linking curing, good film formation, good heat resistance, and strong cohesion. With a hot-pressing process in an appropriate coating manner, appropriate temperature and pressure, the resultant wood-based panels have all their properties superior over those of Class II wood-based panels, and they can be widely used in decoration of hot-pressed woods, and bonding of wood-based panels and plywoods.
摘要:
The disclosure relates to a process for preparing an adhesive, a novel adhesive, a novel polymeric material and a process for preparing extremely stable emulsions. The process of the invention comprises subjecting an aqueous mixture of starch or protein, or at least two insoluble substances, and grinding media to an agitation in the presence of a pigment, if desired, and then removing the grinding media therefrom. The treated starch or protein may be further reacted with a polymerizable monomer or preformed polymer to form the novel polymeric material. A superior adhesive, which finds particular application in coating base materials, as paper, is obtained. Stable emulsions formed are particularly useful in pharmaceutical and food applications.
摘要:
A POLYOLEFIN-MODIFIED STARCH WHERE AN OLEFIN IS POLYMERIZED DIRECTLY UPON THE SURFACE OF STARCH TO YIELD A STARCH/POLYOLEFIN COMPOSITE (SPS). SPS IS PREPARED BY POLYMERIZING AN OLEFIN MONOMER ON THE SURFACE OF STARCH UPON WHICH A SUITABLE CATALYST HAS BEEN ADSORBED, PREFERABLY A CATALYST OF THE ZIEGLER-NATTA TYPE, I.E. AN ORGANOMETALLIC TRANSITION METAL CATALYST SYSTEM. THESE SURFACE POLYMERIZED POLYOLEFIN STARCHES (SPS) ARE USEFUL IN A WIDE VARIETY OF APPLICATIONS INCLUDING THEIR USE IN WATER-RESISTANT ADHESIVES AND BINDERS, PAPER SIZES AND COATING, TEXTILE SIZES, PAINT EXTENDERS, AND A WIDE VARIETY OF OTHER USES.