Vinyl acrylic copolymers and methods of making and use thereof

    公开(公告)号:US11427667B2

    公开(公告)日:2022-08-30

    申请号:US16760105

    申请日:2017-10-31

    申请人: BASF SE

    摘要: Described herein are compositions comprising a vinyl acrylic copolymer derived in the presence of maltodextrin. In some examples, the compositions comprise a copolymer derived from: vinyl acetate; an acrylate monomer having a Tg of −30° C. or less; a carboxylic acid, a carboxylic acid anhydride, or a combination thereof; and an organosilane; in the presence of maltodextrin. The copolymer can be provided as an aqueous dispersion. In some examples, the aqueous dispersion can have an overall solids content of from 40% to 75%. Also disclosed herein are carpet tiles having a surface coated with the adhesive formulations disclosed herein. In some examples, the carpet tile with the adhesive formulation applied thereto can pass the British spill test. Also disclosed herein are methods of making the compositions disclosed herein.

    Ultra-violet curable adhesive
    3.
    发明授权
    Ultra-violet curable adhesive 有权
    紫外线固化胶

    公开(公告)号:US09120958B2

    公开(公告)日:2015-09-01

    申请号:US13816988

    申请日:2012-07-31

    申请人: Glen Leon Brizius

    发明人: Glen Leon Brizius

    IPC分类号: C09J151/02 C09J197/00

    摘要: An adhesive may be formulated with a functional component that reacts in the presence of ultraviolet light with a neighboring functional component to form a nonreversible bond therebetween. The functional component may include at least one —C═C— functional group that is able to undergo dimerization with a neighboring component. A method for making the adhesive includes covalently bonding the functional component to a support polymer, wherein the functional component may be covalently bonded to the support polymer by a linking molecule. A kit containing the adhesive and an ultraviolet light source is also provided.

    摘要翻译: 粘合剂可以与在紫外线存在下与相邻功能组分反应以在其间形成不可逆结合的功能组分配制。 功能组分可以包括能够与相邻组分进行二聚化的至少一个-C≡C-官能团。 制备粘合剂的方法包括将功能性组分共价键合到支持聚合物上,其中功能性组分可以通过连接分子共价键合到载体聚合物上。 还提供了包含粘合剂和紫外光源的试剂盒。

    Thermosetting Starch Adhesive For Wood-based Panel and Preparation Method Therefor

    公开(公告)号:US20200239750A1

    公开(公告)日:2020-07-30

    申请号:US16850520

    申请日:2020-04-16

    摘要: The present disclosure discloses a thermosetting starch adhesive for a wood-based panel and a preparation method therefor, and belongs to the technical field of preparation of adhesives. In the present disclosure, starch is used as a main raw material, and after acid hydrolysis thereof, a semi-continuous seed emulsion polymerization method is adopted to improve control of monomer polymerization stability. After grafting is completed, a cross-linking monomer with polymerizable double bonds and condensable methylol functional groups is added for copolymerization. The cross-linking monomer is also added in a semi-continuous manner. After the cross-linking reaction is completed, the reaction mixture is gelatinized and incubated, and finally a thermosetting adhesive which can be used for bonding of hot-pressed wood-based panels is obtained. The adhesive of the present disclosure has the properties of two-step cross-linking and high-temperature rapid cross-linking curing, good film formation, good heat resistance, and strong cohesion. With a hot-pressing process in an appropriate coating manner, appropriate temperature and pressure, the resultant wood-based panels have all their properties superior over those of Class II wood-based panels, and they can be widely used in decoration of hot-pressed woods, and bonding of wood-based panels and plywoods.

    Polyolefin-starch
    10.
    发明授权
    Polyolefin-starch 失效
    POLYOLEFIN-STARCH

    公开(公告)号:US3704271A

    公开(公告)日:1972-11-28

    申请号:US3704271D

    申请日:1970-10-29

    摘要: A POLYOLEFIN-MODIFIED STARCH WHERE AN OLEFIN IS POLYMERIZED DIRECTLY UPON THE SURFACE OF STARCH TO YIELD A STARCH/POLYOLEFIN COMPOSITE (SPS). SPS IS PREPARED BY POLYMERIZING AN OLEFIN MONOMER ON THE SURFACE OF STARCH UPON WHICH A SUITABLE CATALYST HAS BEEN ADSORBED, PREFERABLY A CATALYST OF THE ZIEGLER-NATTA TYPE, I.E. AN ORGANOMETALLIC TRANSITION METAL CATALYST SYSTEM. THESE SURFACE POLYMERIZED POLYOLEFIN STARCHES (SPS) ARE USEFUL IN A WIDE VARIETY OF APPLICATIONS INCLUDING THEIR USE IN WATER-RESISTANT ADHESIVES AND BINDERS, PAPER SIZES AND COATING, TEXTILE SIZES, PAINT EXTENDERS, AND A WIDE VARIETY OF OTHER USES.