公开(公告)号：US20230072588A1

公开(公告)日：2023-03-09

申请号：US17891093

申请日：2022-08-18

申请人： VIRENT, INC. ,  JOHNSON MATTHEY DAVY TECHNOLOGIES LIMITED

发明人： Paul G. Blommel ,  Colin Anson ,  Matt van Straten ,  Edgar Steenwinkel ,  Chris Holland ,  Rauf Gearing ,  Chris Ferguson ,  Rob Wild ,  Ian Campbell

IPC分类号： B01J38/70 ,  B01J23/46 ,  B01J23/96 ,  B01J21/18 ,  C13K1/02

摘要： The present disclosure provides methods for producing a regenerated hydrogenation catalyst from a fouled hydrogenation catalyst having a total surface area and at least one associated impurity. The method can include maintaining contact between the fouled hydrogenation catalyst and a flushing medium that comprises water, oxygen, and an inert or diluent gas at a regeneration temperature and a regeneration pressure sufficient to remove at least a portion of the at least one impurity from the hydrogenation catalyst to produce the regenerated hydrogenation catalyst, where the regenerated hydrogenation catalyst is characterized as retaining at least 70% of the activity of the hydrogenation catalyst.

公开(公告)号：US20220340505A1

公开(公告)日：2022-10-27

申请号：US17860357

申请日：2022-07-08

申请人： Dow Global Technologies LLC

发明人： Matthew T. Pretz ,  Mark W. Stewart ,  Lin Luo ,  Hangyao Wang

IPC分类号： C07C5/333 ,  B01J8/00 ,  B01J8/18 ,  B01J8/24 ,  B01J21/12 ,  B01J23/62 ,  B01J23/96 ,  B01J38/02 ,  B01J38/12

摘要： A method for processing a chemical stream includes contacting a feed stream with a catalyst in a reactor portion of a reactor system that includes a reactor portion and a catalyst processing portion. The catalyst includes platinum, gallium, or both and contacting the feed stream with the catalyst causes a reaction which forms an effluent stream. The method includes separating the effluent stream from the catalyst, passing the catalyst to the catalyst processing portion, and processing the catalyst in the catalyst processing portion. Processing the catalyst includes passing the catalyst to a combustor, combusting a supplemental fuel in the combustor to heat the catalyst, treating the heated catalyst with an oxygen-containing gas to produce a reactivated catalyst, and passing the reactivated catalyst from the catalyst processing portion to the reactor portion. The supplemental fuel may include a molar ratio of hydrogen to other combustible fuels of at least 1:1.

公开(公告)号：US20220135887A1

公开(公告)日：2022-05-05

申请号：US17574439

申请日：2022-01-12

申请人： UOP LLC

发明人： Avram M. Buchbinder ,  John J. Senetar ,  Wei Pan ,  Wolfgang A. Spieker ,  Richard A. Johnson, II

IPC分类号： C10G35/09 ,  B01J23/96 ,  B01J38/02

摘要： A fluidized catalytic reactor system cycles from 0.05-5% of catalyst at a time through a rejuvenation unit to be heated in the presence of oxygen to maintain catalyst activity. The use of the rejuvenation unit that may be 2% of the size of the main catalyst regeneration unit allows for reduction in equipment size and in catalyst inventory. The catalyst that is sent to the rejuvenation unit may be spent catalyst but may be partially or fully regenerated catalyst. The rejuvenation unit may be heated by combusting fuel or by hot flue gas.

公开(公告)号：US10646855B2

公开(公告)日：2020-05-12

申请号：US16177833

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333 ,  B01J23/96 ,  B01J38/02

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US10472304B2

公开(公告)日：2019-11-12

申请号：US15737848

申请日：2016-06-29

申请人： SMH Co., Ltd

发明人： Kongkiat Suriye ,  Amnart Jantharasuk ,  Wuttithep Jareewatchara

IPC分类号： C07C5/333 ,  B01J37/04 ,  B01J23/652 ,  C07C6/10 ,  B01J37/18 ,  B01J38/12 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/36 ,  B01J23/656 ,  B01J23/92 ,  B01J23/96

摘要： The present invention relates to a hydrocarbon conversion catalyst comprising i) a catalyst, in oxidic form, metals M1, M2, M3 and M4, wherein: M1 is selected from Si, Al, Zr, and mixtures thereof; M2 is selected from Pt, Cr, and mixtures thereof; M3 is selected from W, Mo, Re and mixtures thereof; M4 is selected from Sn, K, Y, Yb and mixtures thereof; and ii) a hydrogen scavenger selected from at least one alkali and/or alkaline earth metal derivative, preferably in metallic, hydride, salt, complex or alloy form; as well as a hydrocarbon conversion process utilizing this catalyst.

公开(公告)号：US20190225563A1

公开(公告)日：2019-07-25

申请号：US16255364

申请日：2019-01-23

申请人： Dow Global Technologies LLC

发明人： Matthew T. Pretz

IPC分类号： C07C5/333 ,  B01J23/26 ,  B01J38/02 ,  B01J38/12 ,  B01J38/14 ,  B01J23/62 ,  B01J23/94 ,  B01J35/00 ,  B01J21/04 ,  B01J21/12 ,  B01J23/887 ,  B01J23/92 ,  B01J23/96 ,  B01J35/10 ,  B01J8/00 ,  B01J8/26 ,  B01J8/18 ,  B01J8/12 ,  B01J8/08

CPC分类号： C07C5/3332 ,  B01J8/0025 ,  B01J8/0055 ,  B01J8/087 ,  B01J8/12 ,  B01J8/1836 ,  B01J8/1863 ,  B01J8/26 ,  B01J21/04 ,  B01J21/12 ,  B01J23/26 ,  B01J23/62 ,  B01J23/8871 ,  B01J23/92 ,  B01J23/94 ,  B01J23/96 ,  B01J35/0006 ,  B01J35/1009 ,  B01J35/1014 ,  B01J38/02 ,  B01J38/12 ,  B01J38/14 ,  B01J2208/00176 ,  B01J2208/00362 ,  B01J2208/00769 ,  B01J2219/00024 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/08 ,  C07C2523/42 ,  C07C2523/62 ,  Y02P20/125 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/08

摘要： An integrated process for producing C3-C4 olefins or di-olefins including: contacting a hydrocarbon feed and a catalyst feed in a fluidized dehydrogenation reactor under conditions such that a product mixture is formed and the catalyst is at least partially deactivated; transferring the product mixture and the catalyst from the reactor to a cyclonic separation system under conditions such that the product mixture is converted to form a new product mixture and is separated from the catalyst; transferring at least a portion of the catalyst to a regenerator vessel and heating it in order to combust the coke deposited thereon; subjecting the catalyst to a conditioning step to form an oxygen-containing, at least partially reactivated catalyst; and transferring the partially reactivated catalyst back to the fluidized dehydrogenation reactor.

公开(公告)号：US20180169630A1

公开(公告)日：2018-06-21

申请号：US15847976

申请日：2017-12-20

申请人： UOP LLC

发明人： Wolfgang A. Spieker ,  Adam D. Ballard ,  Gregory J. Gajda ,  J. W. Adriaan Sachtler

IPC分类号： B01J23/96 ,  B01J38/10 ,  B01J38/02 ,  C07C5/333 ,  C07C11/02 ,  C10G45/04 ,  C10G45/14

摘要： A process is presented for the management of sulfur on a catalyst. The catalyst is a dehydrogenation catalyst, and sulfur accumulates during the dehydrogenation process. Sulfur compounds are stripped from the spent catalyst and the catalyst is cooled before the regeneration process. The process includes controlling the amount of sulfur that needs to be removed from the catalyst before regeneration.

公开(公告)号：US09970342B2

公开(公告)日：2018-05-15

申请号：US15547988

申请日：2016-01-29

申请人： HONDA MOTOR CO., LTD. ,  MITSUI MINING & SMELTING CO., LTD.

发明人： Ryosaku Takahara ,  Koichi Inaba ,  Nobuhiro Komatsu ,  Masafumi Sakota ,  Takahiro Kogawa ,  Michitaka Yamaguchi

IPC分类号： F01N3/10 ,  F01N3/08 ,  B01D53/96 ,  B01J23/50 ,  B01J21/04 ,  B01J23/96 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J37/08 ,  B01J38/02 ,  F01N3/023 ,  F01N3/035 ,  B01D53/94

CPC分类号： F01N3/0885 ,  B01D53/94 ,  B01D53/9422 ,  B01D53/96 ,  B01D2255/1023 ,  B01D2255/104 ,  B01D2255/915 ,  B01J21/04 ,  B01J23/44 ,  B01J23/50 ,  B01J23/96 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/0248 ,  B01J37/08 ,  B01J38/02 ,  F01N3/023 ,  F01N3/035 ,  F01N3/08 ,  F01N3/0814 ,  F01N3/0842 ,  F01N3/10 ,  F01N3/24 ,  F01N2370/02 ,  F01N2510/065 ,  F02D41/04 ,  Y02T10/47

摘要： An exhaust gas purification device is equipped with: an NOx purification unit disposed in exhaust gas piping of an engine supporting an NOx storage catalyst (NSC); a catalyzed soot filter (CSF) disposed downstream of the NOx purification unit supporting a particulate combustion catalyst causing captured particulates to combust; and an electronic control unit (ECU) which controls exhaust gas flowing into the NSC to be rich and which, by raising the temperature of the NSC, acts as a regeneration device that causes sulfur components captured in the NSC to be desorbed. The particulate combustion catalyst is provided where Ag and Pd have been alloyed on an Al2O3 carrier; the quantity of Ag supported by the Al2O3 carrier is 1.2-2.5 g/L; the quantity of Pd supported by the Al2O3 carrier is 0.7 g/L or less; and the ratio Ag/Pd of the Ag support quantity to the Pd support quantity is 1.7-8.3.

公开(公告)号：US09944578B2

公开(公告)日：2018-04-17

申请号：US15329392

申请日：2015-07-27

申请人： MEXICHEM AMANCO HOLDING S.A. DE C.V.

发明人： Andrew Paul Sharratt ,  Claire Nicola Rees ,  Maxine Doran

IPC分类号： C07C17/25 ,  B01J23/755 ,  B01J23/92 ,  B01J23/96 ,  B01J23/90 ,  B01J23/94 ,  B01J21/20

CPC分类号： C07C17/25 ,  B01J21/20 ,  B01J23/755 ,  B01J23/90 ,  B01J23/92 ,  B01J23/94 ,  B01J23/96 ,  C07C21/18

摘要： The present invention provides a process for the preparation of a (hydro)(chloro)fluoroalkene by contacting a reagent stream comprising a hydrochlorofluoroalkane with a catalyst in a reactor to dehydrochlorinate at least a portion of the hydrochlorofluoroalkane to produce a product stream comprising the (hydro)(chloro)fluoroalkene and hydrogen chloride (NCI), wherein the catalyst is selected from the group consisting of metal oxide catalysts, metal halide catalysts, zero-valent metal catalysts, carbon-based catalysts and mixtures thereof, and wherein (i) the catalyst is chlorinated prior to contacting it with the reagent stream comprising the hydrochlorofluoroalkane; and/or (ii) the contacting step is carried out in the presence of a HCI co-feed.

公开(公告)号：US09884314B2

公开(公告)日：2018-02-06

申请号：US14420677

申请日：2013-07-31

申请人： Dow Global Technologies LLC

发明人： Lin Luo ,  Brien A. Stears

IPC分类号： B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/54 ,  B01J23/56 ,  B01J23/58 ,  B01J23/62 ,  B01J23/63 ,  B01J23/64 ,  B01J23/76 ,  B01J23/78 ,  B01J23/825 ,  B01J23/83 ,  B01J23/84 ,  B01J23/86 ,  B01J23/89 ,  B01J38/02 ,  B01J38/12 ,  B01J38/18 ,  B01J38/38 ,  B01J23/96 ,  B01J23/648 ,  B01J23/652 ,  C07C5/333

CPC分类号： B01J23/96 ,  B01J23/648 ,  B01J23/6482 ,  B01J23/652 ,  B01J23/6522 ,  B01J23/8906 ,  B01J23/8993 ,  B01J38/02 ,  B01J38/12 ,  B01J38/18 ,  B01J38/38 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/652 ,  C07C2523/745 ,  C07C2523/89 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

摘要： A catalyst comprising a Group IIIA metal, a Group VIII noble metal, and an optional promoter metal, on a support selected from silica, alumina, silica-alumina compositions, rare earth modified alumina, and combinations thereof, doped with iron, a Group VIB metal, a Group VB metal, or a combination thereof, offers decreased reactivation time under air soak in comparison with otherwise identical catalysts. Reducing reactivation time may, in turn, reduce costs, both in inventory and capital.