PROCESS FOR PREPARING 2-ALKYL-3-AROYL-5-NITRO-BENZOFURANS
    2.
    发明申请
    PROCESS FOR PREPARING 2-ALKYL-3-AROYL-5-NITRO-BENZOFURANS 审中-公开
    制备2-烷基-3-硝基-5-硝基苯并呋喃的方法

    公开(公告)号:WO2010040261A1

    公开(公告)日:2010-04-15

    申请号:PCT/CN2008/072644

    申请日:2008-10-10

    Abstract: The present invention relates to a process for the preparation of a compound of formula (I), wherein R 1 is selected from C 1-6 -alkyl, C 3-6 -cycloalkyl and aralkyl, and wherein R 2 at each occurrence independently is halogen or C 1-6 -alkyl, and m is an integer from 0 to 4, Q is selected from halogen, -NO 2 and -NR 3 R 4 , wherein R 3 and R 4 are independently selected from hydrogen, C 1-6 -alkyl, C 3-6 -cycloalkyl, aryl, aralkyl, mesyl and tosyl, or wherein R 3 and R 4 together form a C 4-6 -alkylene group, Y at each occurrence is hydrogen or a hydroxy protection group W that can be hydrolytically cleaved under acidic conditions, and n is an integer from 1 to 3, and n is an integer from 1 to 3, with the proviso that n and m together are not greater than 5.

    Abstract translation: 本发明涉及制备式(I)化合物的方法,其中R 1选自C 1-6 - 烷基,C 3-6 - 环烷基和芳烷基,并且其中R 2在每次出现时独立地为卤素或C1- 并且m是0至4的整数,Q选自卤素,-NO 2和-NR 3 R 4,其中R 3和R 4独立地选自氢,C 1-6 - 烷基,C 3-6 - 环烷基,芳基, 芳烷基,甲磺酰基和甲苯磺酰基,或其中R3和R4一起形成C4-6亚烷基,Y在每次出现时为氢或可在酸性条件下水解切割的羟基保护基W,n为1〜 3,n为1〜3的整数,条件是n和m不大于5。

    ESTER COMPOUNDS, INTERMEDIATES FOR THE ESTER COMPOUNDS AND PESTICIDAL METHODS
    5.
    发明申请
    ESTER COMPOUNDS, INTERMEDIATES FOR THE ESTER COMPOUNDS AND PESTICIDAL METHODS 审中-公开
    酯化合物,酯化合物的中间体和杀虫剂方法

    公开(公告)号:WO01042196A1

    公开(公告)日:2001-06-14

    申请号:PCT/JP2000/008308

    申请日:2000-11-24

    Abstract: The present invention provides an ester compound encompassed by formula (I) wherein R represents a hydrogen atom, a C1 to C5 alkyl group which may be substituted with at least one halogen atom, a C4 to C5 cycloalkyl group which may be substituted with at least one halogen atom, a C3 to C5 alkenyl group which may be substituted with at least one halogen atom, a C3 to C5 alkynyl group which may be substituted with at least one halogen atom, a (C3 to C5 cycloalkyl)methyl group which may be substituted with at least one halogen atom or a C2 to C5 (alkoxyalkyl) group which may be substituted with at least one halogen atom. Further, the present invention provides an aldehyde compound encompassed by formula (II) Furthermore, the present invention provides pesticidal methods.

    Abstract translation: 本发明提供式(I)所包含的酯化合物,其中R 1表示氢原子,可被至少一个卤素原子取代的C 1至C 5烷基,可被取代的C 4至C 5环烷基 与至少一个卤素原子,可被至少一个卤素原子取代的C 3至C 5烯基,可被至少一个卤素原子取代的C 3至C 5炔基,(C 3至C 5环烷基)甲基 其可以被至少一个卤素原子或可以被至少一个卤素原子取代的C 2至C 5(烷氧基烷基)基团取代。 此外,本发明提供由式(II)包含的醛化合物。此外,本发明提供杀虫方法。

    MICROBICIDES
    7.
    发明申请
    MICROBICIDES 审中-公开
    杀菌剂

    公开(公告)号:WO1996010556A1

    公开(公告)日:1996-04-11

    申请号:PCT/EP1995003683

    申请日:1995-09-19

    Inventor: CIBA-GEIGY AG

    CPC classification number: A01N37/38 A01N37/50 C07C69/736 C07C251/52 C07C255/61

    Abstract: Compounds of formula (I) and possible isomers and isomeric mixtures thereof, wherein: a) X is CH2F or CHF2; Y is CH and Z is OMe, or b) X is CH2F or CHF2; Y is a nitrogen atom and Z is OMe or NHCH3, and wherein also m is 0, 1, 2, 3, 4 or 5 and U represents identical or different substituents selected from halogen, cyano, nitro, C1-C12alkyl, C3-C8cycloalkyl, C3-C6alkenyl, C3-C6alkenyloxyiminomethyl, C1-C4alkoxy, C1-C4alkoxyiminomethyl, C1-C2haloalkyl, C1-C2haloalkoxy, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy and unsubstituted or substituted benzyl or represents substituents at two adjacent positions of the phenyl ring of formula (I) that define a fused hydrocarbon bridge so as to form a larger hydrocarbon ring having up to 14 carbon atoms, are suitable for controlling and preventing microorganisms, insects and Acarina on plants. They can be used in the form of commercially customary formulated compositions.

    Abstract translation: 式(I)化合物及其可能的异构体和异构体混合物,其中:a)X是CH 2 F或CHF 2; Y是CH,Z是OMe,或b)X是CH 2 F或CHF 2; Y是氮原子,Z是OMe或NHCH 3,其中m是0,1,2,3,4或5,U代表相同或不同的选自卤素,氰基,硝基,C 1 -C 12烷基,C 3 -C 8环烷基 C 3 -C 6烯基氧基亚氨基甲基,C 1 -C 4烷氧基,C 1 -C 4烷氧基亚氨基甲基,C 1 -C 2卤代烷基,C 1 -C 2卤代烷氧基,未取代或取代的苯基,未取代或取代的苯氧基和未取代或取代的苄基或在苯环的两个相邻位置 定义稠合烃桥以形成具有至多14个碳原子的较大烃环的式(I)的化合物适用于控制和防止植物上的微生物,昆虫和蜱螨属。 它们可以以商业习惯配制的组合物的形式使用。

    CYCLOHEXENONE DERIVATES USED AS HERBICIDES
    8.
    发明申请
    CYCLOHEXENONE DERIVATES USED AS HERBICIDES 审中-公开
    环己酮衍生物用作除草剂

    公开(公告)号:WO1993008153A1

    公开(公告)日:1993-04-29

    申请号:PCT/EP1992002226

    申请日:1992-09-26

    Abstract: Cyclohexenone derivates have the formula (I), in which R1 stands for alkyl, alkenyl, alkinyl, cycloalkyl, aloxyalkyl, alkylthioalkyl, possibly substituted phenyl, possibly substituted benzyl, possibly substituted 5-/6-membered heteroaryl; W stands for 0, =N-OR2 or =N-R3; R2 stands for possibly substituted alkyl, alkenyl or alkinyl residue, possibly substituted 3- to 6-membered alkyl chain or 4- to 6-membered alkenyl or alkinyl chain, a chain link in each of the chains being substituted by -0-, -S-, -S0-, -S0¿2?- or -N(R?8)-; R8¿ stands for H, alkyl, alkenyl, alkinyl, alkylcarbonyl, benzoyl; R3 stands for H, alkyl hydroxyakyl, alkoxyalkyl or alkylthioalkyl, possibly substituted phenyl, possibly substituted benzyl; X, Y stand for -OR?4 or -NR5 R6; R4¿ stands for H, alkyl, akenyl, alkinyl, alkoxyalkyl, alkylthioalkyl; R5 stands for H, alkyl, alkenyl, alkinyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl and R6 stands for H, alkyl, alkenyl, alkinyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl, alkylcarbonyl, possibly substituted benzoyl or R5-R6 form together with the shared N atom a 5-/6-membered heterocycle that may contain -O-, -S- or -N(R7)- as ring element; R7 stands for H, alkyl, alkenyl, alkinyl, alkylcarbonyl, benzoyl. Also disclosed are the agriculturally useful salts and esters of C¿1?-C10-carboxylic acids and anorganic acids of the compounds having the formula (I). These cyclohexenone derivates (I) are useful as herbicides and plant growth regulators.

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