公开(公告)号：US20050033009A1

公开(公告)日：2005-02-10

申请号：US10942262

申请日：2004-09-16

Applicant: Alan Schrock ,  Ralph Priester ,  Wayne Willkom ,  Robert O'Neill ,  Martin Cornell ,  Christopher Christenson

Inventor： Alan Schrock ,  Ralph Priester ,  Wayne Willkom ,  Robert O'Neill ,  Martin Cornell ,  Christopher Christenson

IPC: B60C17/00 ,  B29C45/00 ,  B29C67/24 ,  B29K75/00 ,  B60C17/06 ,  C08G18/10 ,  C08G18/48 ,  C08G18/66

CPC classification number: C08G18/6651 ,  B29C67/246 ,  B29K2075/00 ,  B60C17/06 ,  C08G18/10 ,  C08G18/4841 ,  C08G18/4866 ,  C08G2120/00 ,  C08G2380/00 ,  Y10T152/10054 ,  Y10T152/10522 ,  Y10T152/10738 ,  C08G18/6685

Abstract: A polyurethane-polymer composition suitable for preparing a lightweight tire support includes at least one isocyanate, at least one polyol, and at least one chain extender. A polyurethane-polymer composition can also include an additive such as a catalyst, a filler, a surfactant, a colorant, and a mold-release agent. A lightweight tire support can be prepared from a polyurethane-polymer composition by, for example, reaction injection molding. Such a tire support desirably has temperature stability and load-bearing capability.

Abstract translation: 适用于制备轻质轮胎支承体的聚氨酯 - 聚合物组合物包括至少一种异氰酸酯，至少一种多元醇和至少一种扩链剂。 聚氨酯 - 聚合物组合物还可以包括添加剂如催化剂，填料，表面活性剂，着色剂和脱模剂。 可以通过例如反应注射成型由聚氨酯 - 聚合物组合物制备轻质轮胎支撑体。 这样的轮胎支撑件期望地具有温度稳定性和承载能力。

公开(公告)号：US20060193802A1

公开(公告)日：2006-08-31

申请号：US10551854

申请日：2004-04-22

Applicant: Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

Inventor： Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

IPC: C07C29/14

CPC classification number: C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

Abstract: An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxmethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foams.

Abstract translation: 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或脂肪酸酯的混合物，所述羟甲基取代的脂肪酸或脂肪酸酯具有以下重量组成：大于约10至小于约95％的一元醇{单（羟甲基，大于 约1至小于约65％的二醇{二（羟甲基，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯;优选大于约3至小于约35％ 饱和物;优选小于约10％的不饱和度。醇组合物可以转化为用于制备聚氨酯板坯柔性泡沫的低聚多元醇。

公开(公告)号：US20060276609A1

公开(公告)日：2006-12-07

申请号：US10553767

申请日：2004-04-21

Applicant: Zenon Lysenko ,  Alan Schrock ,  David Babb ,  Aaron Sanders

Inventor： Zenon Lysenko ,  Alan Schrock ,  David Babb ,  Aaron Sanders

IPC: C08G18/00

CPC classification number: C08G18/36 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4288 ,  C08G18/4804 ,  C08G18/4841 ,  C08G18/4891 ,  C08G18/6696 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

Abstract: Polyols useful in the manufacture of polyurethanes are disclosed. The polyols are prepared by reacting a vegetable oil based (hydroxymethyl containing) monomer with a polyol, polyamine or aminoalcohol under vacuum.

Abstract translation: 公开了可用于制造聚氨酯的多元醇。 通过在真空下使基于植物油的（含羟甲基）单体与多元醇，多胺或氨基醇反应来制备多元醇。

公开(公告)号：US4642329A

公开(公告)日：1987-02-10

申请号：US770913

申请日：1985-08-30

Applicant: Robert A. Kirchhoff ,  Alan Schrock ,  Jo A. Gilpin

Inventor： Robert A. Kirchhoff ,  Alan Schrock ,  Jo A. Gilpin

IPC: C08F12/32 ,  C07C13/44 ,  C07C63/49 ,  C07C63/72 ,  C08F12/00 ,  C08F32/08 ,  C08G61/00 ,  C08G61/02 ,  C08G61/06 ,  C08F32/00

CPC classification number: C07C13/44 ,  C07C63/49 ,  C07C63/72 ,  C08F32/08 ,  C08G61/00 ,  C08G61/02

Abstract: Reactive polymeric compositions are prepared by subjecting arylcyclobutene monomeric compositions to polymerization conditions to provide a partially polymerized composition; and removing the partially polymerized composition from said conditions. The partially polymerized composition can be subsequently subjected to polymerization and curing conditions to provide a cured polymeric composition.

Abstract translation: 通过使芳基环丁烯单体组合物经受聚合条件以提供部分聚合的组合物来制备反应性聚合物组合物; 并从所述条件除去部分聚合的组合物。 随后将部分聚合的组合物进行聚合和固化条件以提供固化的聚合物组合物。

公开(公告)号：US20050154221A1

公开(公告)日：2005-07-14

申请号：US10508805

申请日：2003-04-17

Applicant: Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

Inventor： Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

IPC: B01J31/24 ,  C07B61/00 ,  C07C6/04 ,  C07C11/02 ,  C07C67/333 ,  C07C67/347 ,  C07C67/475 ,  C07C67/56 ,  C07C69/533 ,  C07C69/58 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  C07D303/42 ,  C07C51/43

CPC classification number: C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

Abstract: Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,Ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,Ω-hydroxy acid or α,Ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,Ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,Ω-amino acid or α,Ω-amino ester, which may be (trans)esterified to form an α,Ωpolyester polyamine.

Abstract translation: 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原反应加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。