公开(公告)号：US20060193802A1

公开(公告)日：2006-08-31

申请号：US10551854

申请日：2004-04-22

申请人： Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

发明人： Zenon Lysenko ,  Donald Morrison ,  David Babb ,  Donald Bunning ,  Christopher Derstine ,  James Gilchrist ,  H. Ray Jouett ,  Jeffrey Kanel ,  Kurt Olson ,  Wei-Jun Peng ,  Joe Philips ,  Brian Roesch ,  Aaron Sanders ,  Alan Schrock ,  Pulikkottil Thomas

IPC分类号： C07C29/14

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxmethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foams.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或脂肪酸酯的混合物，所述羟甲基取代的脂肪酸或脂肪酸酯具有以下重量组成：大于约10至小于约95％的一元醇{单（羟甲基，大于 约1至小于约65％的二醇{二（羟甲基，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯;优选大于约3至小于约35％ 饱和物;优选小于约10％的不饱和度。醇组合物可以转化为用于制备聚氨酯板坯柔性泡沫的低聚多元醇。

公开(公告)号：US20060276609A1

公开(公告)日：2006-12-07

申请号：US10553767

申请日：2004-04-21

申请人： Zenon Lysenko ,  Alan Schrock ,  David Babb ,  Aaron Sanders

发明人： Zenon Lysenko ,  Alan Schrock ,  David Babb ,  Aaron Sanders

IPC分类号： C08G18/00

CPC分类号： C08G18/36 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4288 ,  C08G18/4804 ,  C08G18/4841 ,  C08G18/4891 ,  C08G18/6696 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

摘要： Polyols useful in the manufacture of polyurethanes are disclosed. The polyols are prepared by reacting a vegetable oil based (hydroxymethyl containing) monomer with a polyol, polyamine or aminoalcohol under vacuum.

摘要翻译： 公开了可用于制造聚氨酯的多元醇。 通过在真空下使基于植物油的（含羟甲基）单体与多元醇，多胺或氨基醇反应来制备多元醇。

公开(公告)号：US20050154221A1

公开(公告)日：2005-07-14

申请号：US10508805

申请日：2003-04-17

申请人： Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

发明人： Zenon Lysenko ,  Bob Maughon ,  Josef Bicerano ,  Kenneth Burdett ,  Christopher Christenson ,  Clark Cummins ,  Marvin Dettloff ,  Alan Schrock ,  P. J. Thomas ,  Richard Varjian ,  Jerry White ,  John Maher

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C6/04 ,  C07C11/02 ,  C07C67/333 ,  C07C67/347 ,  C07C67/475 ,  C07C67/56 ,  C07C69/533 ,  C07C69/58 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  C07D303/42 ,  C07C51/43

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,Ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,Ω-hydroxy acid or α,Ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,Ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,Ω-amino acid or α,Ω-amino ester, which may be (trans)esterified to form an α,Ωpolyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原反应加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US08133930B2

公开(公告)日：2012-03-13

申请号：US10554633

申请日：2004-04-23

申请人： Eugene Paul Wiltz, Jr. ,  Zenon Lysenko ,  Fabio Aguirre ,  Aaron Sanders ,  John Tsavalas ,  David A. Babb ,  Alan K Schrock

发明人： Eugene Paul Wiltz, Jr. ,  Zenon Lysenko ,  Fabio Aguirre ,  Aaron Sanders ,  John Tsavalas ,  David A. Babb ,  Alan K Schrock

IPC分类号： C08G18/28

CPC分类号： C08G18/4288 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4244 ,  C08G18/632 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： Flexible polyurethane foams are prepared by reacting a polyisocyanate with a high equivalent weight polyol. At least a portion of the high equivalent weight polyol is a polyester containing hydroxymethyl groups. The polyester is prepared in a multi-step process from animal or vegetable fats, by recovering the constitutent fatty acids, hydroformylating carbon-carbon double bonds in the fatty acids and reducing to form hydroxymethyl groups, and then forming a polyester by reaction with an initiator compound.

摘要翻译： 柔性聚氨酯泡沫通过使多异氰酸酯与高当量多元醇反应制备。 高当量多元醇的至少一部分是含有羟甲基的聚酯。 通过回收组分脂肪酸，在脂肪酸中加氢甲酰化碳 - 碳双键并还原形成羟甲基，然后通过与引发剂反应形成聚酯，从动物或植物脂肪的多步法制备聚酯 复合。

公开(公告)号：US07960444B2

公开(公告)日：2011-06-14

申请号：US10553767

申请日：2004-04-21

申请人： Zenon Lysenko ,  Alan K. Schrock ,  David A. Babb ,  Aaron Sanders ,  John Tsavalas ,  H. Ray Jouett ,  Larry Chambers ,  Charles Keillor ,  James H. Gilchrist

发明人： Zenon Lysenko ,  Alan K. Schrock ,  David A. Babb ,  Aaron Sanders ,  John Tsavalas ,  H. Ray Jouett ,  Larry Chambers ,  Charles Keillor ,  James H. Gilchrist

IPC分类号： C08G18/00 ,  C08G18/04 ,  C07C57/02

CPC分类号： C08G18/36 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4288 ,  C08G18/4804 ,  C08G18/4841 ,  C08G18/4891 ,  C08G18/6696 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

摘要： Polyols useful in the manufacture of polyurethanes are disclosed. The polyols are prepared by reacting a vegetable oil based (hydroxymethyl containing) monomer with a polyol, polyamine or aminoalcohol under vacuum.

摘要翻译： 公开了可用于制造聚氨酯的多元醇。 通过在真空下使基于植物油的（含羟甲基）单体与多元醇，多胺或氨基醇反应来制备多元醇。

公开(公告)号：US20100266799A1

公开(公告)日：2010-10-21

申请号：US12668500

申请日：2008-07-09

申请人： William A. Koonce ,  Dwight D. Latham ,  Randall C. Jenkines ,  Debkumar Bhattacharjee ,  Zenon Lysenko ,  Hongyu Chen ,  Mark F. Sonnenschein ,  Klaus Schiller ,  Cora Leibig ,  Alan K. Schrock

发明人： William A. Koonce ,  Dwight D. Latham ,  Randall C. Jenkines ,  Debkumar Bhattacharjee ,  Zenon Lysenko ,  Hongyu Chen ,  Mark F. Sonnenschein ,  Klaus Schiller ,  Cora Leibig ,  Alan K. Schrock

IPC分类号： C08G18/10 ,  C08G18/34 ,  B32B1/08

CPC分类号： C08G18/4288 ,  C08G18/0885 ,  C08G18/10 ,  C08G18/4018 ,  C08G18/4833 ,  C08G18/4841 ,  C08G2101/0008 ,  C08J9/30 ,  C08J2375/04 ,  Y10T428/139 ,  C08G18/3275 ,  C08G18/3206 ,  C08G18/40

摘要： A prepolymer or elastomer is the reaction product of reactants (a) at least one polyester polyol or fatty acid derived polyol which is the reaction product of at least one initiator and a mixture of fatty acids or derivatives of fatty acids comprising at least about 45 weight percent monounsaturated fatty acids or derivatives thereof, (b) optionally, at least one polyol which is different from the polyol of (a); and (c) at least one isocyanate compound (herein after isocyanate) having an average of at least about 1.8 isocyanate groups per molecule. A process comprises admixing reactants (a) at least one polyol composition comprising the fatty acid derived polyol which is the reaction product of at least one initiator and a mixture of fatty acids or derivatives of fatty acids comprising at least about any of 45 weight percent monounsaturated fatty acids or derivatives thereof; and (b) at least one isocyanate having an average functionality of at least about 1.8 under reaction conditions to form a reaction product which is an elastomer or prepolymer is formed therefrom. An article, coating or thermoplastic polyurethane comprises the elastomer is formed from the prepolymer of or using the process of the invention.

摘要翻译： 预聚物或弹性体是反应物（a）至少一种聚酯多元醇或脂肪酸衍生多元醇的反应产物，其是至少一种引发剂与脂肪酸或包含至少约45重量％的脂肪酸​​的衍生物的混合物的反应产物 百分比的单不饱和脂肪酸或其衍生物，（b）任选的至少一种不同于（a）的多元醇的多元醇; 和（c）每分子平均具有至少约1.8个异氰酸酯基团的至少一种异氰酸酯化合物（本文中为异氰酸酯）。 一种方法包括混合反应物（a）至少一种多元醇组合物，其包含脂肪酸衍生的多元醇，其是至少一种引发剂的反应产物和脂肪酸或脂肪酸的混合物的混合物，其至少包含约45重量％的单不饱和物 脂肪酸或其衍生物; 和（b）在反应条件下至少一种具有至少约1.8的平均官能度的异氰酸酯形成由弹性体或预聚物形成的反应产物。 一种制品，涂层或热塑性聚氨酯包括弹性体由本发明的预聚物或使用本发明的方法形成。

公开(公告)号：US07745652B2

公开(公告)日：2010-06-29

申请号：US12328868

申请日：2008-12-05

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

IPC分类号： C07C51/43

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US20080023884A1

公开(公告)日：2008-01-31

申请号：US11879120

申请日：2007-07-16

申请人： Wayde Konze ,  David Bank ,  Martin Cornell ,  Zenon Lysenko ,  Francis Timmers

发明人： Wayde Konze ,  David Bank ,  Martin Cornell ,  Zenon Lysenko ,  Francis Timmers

IPC分类号： B29C45/03 ,  C08G61/08

CPC分类号： C08G61/08 ,  C08F6/006

摘要： Crosslinked polydicyclopentadiene polymer and copolymer are made by first forming a thermoplastic polymeric intermediate in a ring-opening metathesis polymerization (ROMP), and then crosslinking the intermediate in a melt-processing or solution processing step. The formation of the intermediate permits facile removal of residual monomer, which leads to a reduction in odor and improvement in physical properties. Crosslinking can be achieved using various crosslinking strategies, including further ROMP reactions, addition polymerization of residual double bonds, addition of a crosslinking agent or introduction of functional groups.

摘要翻译： 交联的聚二聚环戊二烯聚合物和共聚物通过首先在开环易位聚合（ROMP）中形成热塑性聚合物中间体，然后在熔融加工或溶液处理步骤中交联中间体来制备。 中间体的形成允许容易地去除残留的单体，这导致气味的降低和物理性能的改善。 可以使用各种交联策略实现交联，包括进一步的ROMP反应，残余双键的加成聚合，加入交联剂或引入官能团。

公开(公告)号：US06288188B1

公开(公告)日：2001-09-11

申请号：US09281838

申请日：1999-03-31

申请人： James P. Godschalx ,  Duane R. Romer ,  Zenon Lysenko ,  Michael E. Mills

发明人： James P. Godschalx ,  Duane R. Romer ,  Zenon Lysenko ,  Michael E. Mills

IPC分类号： C08F3800

CPC分类号： C08G61/10 ,  C08G2261/312

摘要： An oligomer, uncured polymer or cured polymer comprising the reaction product of one or more polyfunctional compounds containing two or more cyclopentadienone groups and at least one polyfunctional compound containing two or more aromatic acetylene groups wherein at least some of the polyfunctional compounds contain three or more reactive groups. Such oligomers and uncured polymers may be cured to form cured polymers which are useful as dielectrics in the microelectronics industry, especially for dielectrics in integrated circuits.

摘要翻译： 包含含有两个或多个环戊二烯酮基团的一种或多种多官能化合物与至少一种含有两个或多个芳族乙炔基团的多官能化合物的反应产物的低聚物，未固化聚合物或固化聚合物，其中至少一些多官能化合物含有三个或更多个反应性 团体 这种低聚物和未固化的聚合物可以固化以形成固化聚合物，其可用作微电子工业中的电介质，特别是用于集成电路中的电介质。

公开(公告)号：US5736748A

公开(公告)日：1998-04-07

申请号：US677749

申请日：1996-07-10

申请人： Zenon Lysenko ,  Ritchie A. Wessling

发明人： Zenon Lysenko ,  Ritchie A. Wessling

IPC分类号： C08G65/32 ,  C08G18/48 ,  C08G18/50 ,  C08G63/668 ,  C08G63/685 ,  C08G65/333 ,  C09K3/08

CPC分类号： C08G18/5057 ,  C08G18/4866 ,  C08G63/668 ,  C08G63/6854 ,  C08G65/33365 ,  C08G65/33396

摘要： The unsaturation of a hydroxyl-containing compound can be reduced by reaction with a nitrile oxide compound such as tetramethyl terephthalonitrile, N,N'-dioxide. The reaction of a nitrile oxide with terminal unsaturation associated with the preparation of a polyol from propylene oxide reduces the monol content of the polyol composition.

摘要翻译： 含羟基化合物的不饱和度可以通过与腈化合物如四甲基对苯二腈，N，N'-二氧化物的反应来还原。 与由环氧丙烷制备多元醇相关的腈氧化物与末端不饱和键的反应降低了多元醇组合物的单醇含量。