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    Process for preparing 1-aminoanthraquinone having high purity
    1.
    发明授权
    Process for preparing 1-aminoanthraquinone having high purity 失效
    制备纯度高的1-氨基蒽醌的方法

    公开(公告)号：US4054586A

    公开(公告)日：1977-10-18

    申请号：US641284

    申请日：1975-12-16

    申请人： Yutaka Hirai ,  Katsuharu Miyata ,  Tagui Osawa

    发明人： Yutaka Hirai ,  Katsuharu Miyata ,  Tagui Osawa

    IPC分类号： C07C225/34 ,  C09B1/16

    CPC分类号： C07C225/34

    摘要： A process for preparing 1-aminoanthraquinone having high purity, which comprises either1. hydrogenating 1-nitroanthraquinone in an aqueous medium in the presence of a base using a hydrogenating catalyst, and then oxidizing the hydrogenation product, or2. hydrogenating crude 1-nitroanthraquinone containing dinitroanthraquinones as impurities or crude 1-aminoanthraquinone containing diaminoanthraquinones as impurities in an aqueous medium in the presence of a base using a hydrogenating catalyst, stopping the hydrogenation at a time when the 1-nitroanthraquinone or 1-aminoanthraquinone has been substantially reduced to 1-aminoanthrahydroquinone but the dinitroanthraquinones or diaminoanthraquinones remain substantially unreduced to diaminoanthrahydroquinones, removing water-insoluble materials from the reaction mixture, and then oxidizing the remaining water-soluble residue.

    摘要翻译： 一种制备高纯度的1-氨基蒽醌的方法，其包括1.在使用氢化催化剂的碱存在下在水性介质中氢化1-硝基四氢呋喃，然后氧化氢化产物，或2.加氢原料1-硝基四氢呋喃 含有四氢喹啉酮作为防腐剂或将含有二氨基四氢呋喃的1-氨基四氢喹啉酮作为使用氢化催化剂的基质存在下的水性介质中的污染物，当1-硝基四氢呋喃或1-氨基四氢呋喃大量降低至1- 氨基四氢喹啉酮，但是四氢呋喃或二氨基四氢呋喃基本上不依赖于二氨基四氢呋喃，从反应混合物中除去水不溶物，然后氧化剩余的水溶性残留物。

    Process for preparing aromatic urethanes
    3.
    发明授权
    Process for preparing aromatic urethanes 失效
    制备芳香族聚氨酯的方法

    公开(公告)号：US4170708A

    公开(公告)日：1979-10-09

    申请号：US664995

    申请日：1976-03-08

    申请人： Yutaka Hirai ,  Katsuharu Miyata ,  Seiji Hasegawa

    发明人： Yutaka Hirai ,  Katsuharu Miyata ,  Seiji Hasegawa

    IPC分类号： C07B61/00 ,  B01J27/00 ,  B01J27/02 ,  B01J27/24 ,  B01J31/00 ,  C07C20060101 ,  C07C67/00 ,  C07C239/00 ,  C07C269/00 ,  C07C125/06

    CPC分类号： C07C271/06

    摘要： Aromatic urethanes are produced by interacting an aromatic nitro compound, an organic compound containing hydroxyl groups and carbon monoxide in the presence of a catalyst composed of elemental selenium or a selenium compound and of a promoter composed of a bicyclic amidine together with a phenolic compound or a carboxylic acid. The interaction proceeds smoothly with the aid of a small amount of the promoter, attended with secondary production of amino compounds only in small amounts. For instance, 2,4-diethyldicarbamatetoluene is obtained at a yield of 87% by interacting 2,4-dinitrotoluene, ethanol and carbon monoxide in the presence of a catalytic system composed of metallic selenium, 1,8-diazabicyclo(5,4,0)-undecene-7 and acetic acid.

    摘要翻译： 芳族聚氨酯通过在由元素硒或硒化合物组成的催化剂和由双环脒组成的助催化剂与酚类化合物或酚类化合物的存在下，使芳族硝基化合物，含有羟基的有机化合物和一氧化碳相互作用来制备， 羧酸。 借助于少量促进剂，相互作用顺利进行，少量次要生产氨基化合物。 例如，通过在由金属硒，1,8-二氮杂双环（5,4），三氟甲磺酸（1,1-二甲基乙基）丙烷等组成的催化体系的存在下，使2,4-二硝基甲苯，乙醇和一氧化碳相互作用，以87％的收率得到2,4-二乙基氨基甲酸甲酯， 0） - 十一碳烯-7和乙酸。

    Process for preparing aromatic urethanes
    4.
    发明授权
    Process for preparing aromatic urethanes 失效
    制备芳香族聚氨酯的方法

    公开(公告)号：US4080365A

    公开(公告)日：1978-03-21

    申请号：US687933

    申请日：1976-05-19

    申请人： Yutaka Hirai ,  Katsuharu Miyata ,  Seiji Hasegawa

    发明人： Yutaka Hirai ,  Katsuharu Miyata ,  Seiji Hasegawa

    IPC分类号： C07D279/18 ,  B01J27/00 ,  B01J27/02 ,  B01J31/00 ,  B01J31/04 ,  C07B61/00 ,  C07C20060101 ,  C07C67/00 ,  C07C239/00 ,  C07C269/00 ,  C07D239/42 ,  C07D285/20 ,  C07C125/06

    CPC分类号： C07C271/06

    摘要： Aromatic urethanes can be produced in exceedingly improved yield when an aromatic nitro compound, an organic compound containing hydroxyl groups, and carbon monoxide are reacted in the presence of a catalyst composed of metallic (elemental) selenium or a selenium compound and a base serving as promoter, to which reaction system an aromatic amino compound and/or an aromatic urea compound which will be secondarily produced by the reaction has been previously added in order to suppress side reactions. For instance, when nitrobenzene, methanol and carbon monoxide are interacted in the presence of metallic selenium and triethylenediamine, the conversion of nitrobenzene is 68% and the percentage of formed methyl N-phenylcarbamate to the interacted nitrobenzene is 80%, whereas when the reaction is effected under the same reaction conditions indicated above with addition to the reaction system of aniline in an amount of about 15 wt. % of the nitrobenzene, the conversion of nitrobenzene and the percentage of formed methyl N-phenylcarbamate reach 100% and 98%, respectively.

    摘要翻译： 当芳族硝基化合物，含羟基的有机化合物和一氧化碳在由金属（元素）硒或硒化合物组成的催化剂和作为助催化剂的碱的存在下反应时，可以以极高的产率生产芳香族聚氨酯。 为了抑制副反应，预先加入将通过反应二次生成的芳香族氨基化合物和/或芳香族脲化合物的反应体系。 例如，当硝基苯，甲醇和一氧化碳在金属硒和三亚乙基二胺的存在下相互作用时，硝基苯的转化率为68％，形成的N-苯基氨基甲酸甲酯与相互作用的硝基苯的百分比为80％，而当反应为 在与上述相同的反应条件下加入约15重量％的苯胺的反应体系进行。 硝基苯的百分比，硝基苯的转化率和形成的N-苯基氨基甲酸甲酯的百分比分别达到100％和98％。

    Process for producing an aromatic urethane from nitro compounds, hydroxyl compounds and carbon monoxide using metal-Lewis acid-ammonia catalyst systems
    5.
    发明授权
    Process for producing an aromatic urethane from nitro compounds, hydroxyl compounds and carbon monoxide using metal-Lewis acid-ammonia catalyst systems 失效
    使用金属 - 路易斯酸 - 氨催化剂体系从硝基化合物，羟基化合物和一氧化碳制备芳族氨基甲酸酯的方法

    公开(公告)号：US4134880A

    公开(公告)日：1979-01-16

    申请号：US870890

    申请日：1978-01-19

    申请人： Katsuharu Miyata ,  Yutaka Hirai ,  Hiroshi Yoshida

    发明人： Katsuharu Miyata ,  Yutaka Hirai ,  Hiroshi Yoshida

    IPC分类号： C07C271/06 ,  C08L79/00

    CPC分类号： C07C271/06

    摘要： An aromatic urethane of high quality and excellent heat stability can be produced in high yield by reacting an aromatic nitro compound, a hydroxyl group-containing organic compound and carbon monoxide in the presence of a catalytic system composed of (1) palladium, ruthenium, rhodium or a compound thereof, (2) a Lewis acid, and (3) ammonia. The use of such catalytic system can suppress undesirable side reactions to a satisfactory extent and ensures the reaction to proceed without causing any corrosion of a stainless steel reactor. If necessary, water may be added to the reaction system to increase the reaction velocity, by which the unit cost of the catalyst can be reduced.

    摘要翻译： 在由（1）钯，钌，铑组成的催化体系存在下，通过使芳族硝基化合物，含羟基的有机化合物和一氧化碳反应，可以高收率地制备高质量和优异的热稳定性的芳族聚氨酯 或其化合物，（2）路易斯酸和（3）氨。 使用这样的催化体系可以将不期望的副反应抑制到令人满意的程度，并确保反应进行而不会引起不锈钢反应器的任何腐蚀。 如果需要，可以向反应体系中加入水以提高反应速度，由此可以降低催化剂的单位成本。

    Method for the preparation of a halogenated aromatic amine
    6.
    发明授权
    Method for the preparation of a halogenated aromatic amine 失效
    卤代芳香胺的制备方法

    公开(公告)号：US4070401A

    公开(公告)日：1978-01-24

    申请号：US331834

    申请日：1973-02-12

    申请人： Yutaka Hirai ,  Katsuharu Miyata

    发明人： Yutaka Hirai ,  Katsuharu Miyata

    IPC分类号： C07C20060101 ,  C07C85/11

    摘要： A method for the preparation of a halogenated aromatic amine, wherein a halogenated aromatic nitro compound is hydrogenated in liquid phase in the presence of a platinum-base catalyst to obtain a corresponding halogenated aromatic amine, the hydrogenation being carried out in the presence of an alkylmonoamine, an alicyclic amine or a polyalkylenepolyamine. The presence of the amine well suppresses a dehalogenation reaction which would otherwise be involved, so that not only a high purity halogenated aromatic amine is obtained, but also corrosion of a reactor is prevented.

    摘要翻译： 一种制备卤代芳族胺的方法，其中卤化芳族硝基化合物在铂碱催化剂存在下在液相中氢化得到相应的卤代芳族胺，氢化在烷基一胺存在下进行 ，脂环族胺或聚亚烷基多胺。 胺阱的存在抑制了否则将涉及的脱卤反应，因此不仅可以获得高纯度的卤代芳族胺，而且可以防止反应器的腐蚀。

    Process for preparing aromatic urethanes
    7.
    发明授权
    Process for preparing aromatic urethanes 失效
    制备芳香族聚氨酯的方法

    公开(公告)号：US4178455A

    公开(公告)日：1979-12-11

    申请号：US925543

    申请日：1978-07-17

    申请人： Yutaka Hirai ,  Katsuharu Miyata ,  Makoto Aiga ,  Seiji Hasegawa

    发明人： Yutaka Hirai ,  Katsuharu Miyata ,  Makoto Aiga ,  Seiji Hasegawa

    IPC分类号： C07C271/06 ,  C07C125/04

    CPC分类号： C07C271/06

    摘要： In a process for preparing an aromatic urethane which comprises reacting an aromatic nitro compound, an organic compound containing at least one hydroxyl group, and carbon monoxide at elevated temperature and pressure in the presence of a catalytic system composed of a catalyst consisting of a platinum metal, a platinum metal compound, and/or a platinum metal compound-containing compound and a promoter consisting of a Lewis acid and/or a Lewis acid-containing compound, an organic primary amino compound, a urea compound, a biuret compound, an allophanate compound, or a mixture thereof is added to the reaction system whereby the reaction rate is increased and the yield of the desired product is enhanced. For example, 2,4-diethylcarbamatetoluene can be prepared in quantitatively high yield by reacting 2,4-dinitrotoluene, ethanol, carbon monoxide, and a small amount of aminonitrotoluene at elevated temperature and pressure in the presence of palladium chloride and ferrous chloride-pyridine complex.

    摘要翻译： 在制备芳族氨基甲酸酯的方法中，包括使芳族硝基化合物，含有至少一个羟基的有机化合物和一氧化碳在升高的温度和压力下，在由铂金属 ，铂金属化合物和/或含铂金属化合物的化合物和由路易斯酸和/或路易斯酸化合物，有机伯氨基化合物，脲化合物，缩二脲化合物，脲基甲酸酯组成的促进剂 化合物或其混合物加入到反应体系中，由此提高反应速率并提高所需产物的产率。 例如，2,4-二乙基氨基甲酸甲酯可以通过在升高的温度和压力下，在氯化钯和氯化亚铁 - 吡啶存在下，使2,4-二硝基甲苯，乙醇，一氧化碳和少量的氨基硝基甲苯反应，以定量高的产率制备 复杂。

    Light emitting device
    10.
    发明授权
    Light emitting device 失效
    发光装置

    公开(公告)号：US4920387A

    公开(公告)日：1990-04-24

    申请号：US406182

    申请日：1989-09-13

    申请人： Katsuji Takasu ,  Masafumi Sano ,  Hisanori Tsuda ,  Yutaka Hirai

    发明人： Katsuji Takasu ,  Masafumi Sano ,  Hisanori Tsuda ,  Yutaka Hirai

    IPC分类号： H01L33/00 ,  H01L33/06 ,  H01L33/18

    CPC分类号： H01L33/18 ,  B82Y20/00 ,  H01L33/0012 ,  H01L33/0058 ,  H01L33/06 ,  H05B33/145

    摘要： A light emitting device includes a luminescent layer having at least two layers comprising non-single crystalline silicon containing hydrogen atoms laminated and having a homo-junction, and at least a pair of electrodes connected electrically to the luminescent layer, the non-single crystalline silicon layer having an optical band gap of 2.0 eV or higher and a localized level density at mid-gap of 10.sup.16 cm.sup.-3.eV.sup.-1 or less.

    摘要翻译： 发光器件包括发光层，其具有至少两层，包含层叠并具有均聚点的氢原子的非单晶硅，以及至少一对与发光层电连接的电极，非单晶硅 具有2.0eV以上的光学带隙和1016cm -3eV-1以下的中间间隙的局部水平密度的层。